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Edexcel IAL Chemistry A2 18.6 phenol bromination and ring activation

Edexcel IAL Chemistry A2 18.6 phenol bromination and ring activation
Pearson Edexcel IAL Chemistry syllabusChemistry YCH11First assessment 2019

Use the oxygen lone pair: it overlaps with the ring π system, raises electron density and allows phenol to react with bromine water under milder conditions.

How this is tested

  • Write the bromine water equation forming 2,4,6-tribromophenol and HBr.
  • Explain phenol activation by oxygen lone-pair delocalisation into the ring.
  • Compare phenol and benzene bromination conditions, products and reactivity.