Edexcel IAL Chemistry A2 18.3 benzene resistance to bromination
Edexcel IAL Chemistry A2 18.3 benzene resistance to bromination

Pearson Edexcel IAL Chemistry syllabusChemistry YCH11First assessment 2019
The direct evidence asks for comparison: benzene needs a catalyst and undergoes substitution, unlike alkenes where localised π electrons support addition.
How this is tested
- Compare benzene substitution with cyclohexene addition when reacting with bromine.
- Explain benzene’s lower bromination reactivity through delocalised π electrons.
- Contrast benzene and phenol bromination conditions when the comparison is requested.