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CAIE A-Level Chemistry 1.4.3 Ionisation-Energy Trends

Practise explaining general changes across periods and down groups while accounting for sub-shell and pairing anomalies.

Syllabus
2028–2030
Course
Chemistry 9701
Level
AS

Exam points

  • explain the general increase across a period by increasing nuclear charge with similar shielding and shell distance
  • explain the general decrease down a group by greater distance and shielding despite higher nuclear charge
  • explain small anomalies using entry into a higher-energy p sub-shell or repulsion between paired electrons

1.4.3—The trends in ionisation energies across question 1

[Maximum number: 4]

The Periodic Table is arranged such that the properties of the elements show a number of trends.

Question (a)

(a)

A plot of the first ionisation energies for the first 18 elements is shown.

Figure for Question (a) — CAIE A-Level Chemistry AS
[ 4 ]

Question (i)

(i)

Explain why the values show a general increase from atomic number 11 to 18 .

[ 2 ]

Question (ii)

(ii)

Suggest an explanation for the trend in the first ionisation energies of the elements with atomic numbers 2, 10 and 18.

[ 2 ]
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