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A-Level CAIE Chemistry AS1.3 Electrons, energy levels and atomic orbitalsQuestion Bank

[Maximum number: 1]

Which pair of formulae is correct?

A

Ag2CO3\mathrm{Ag}_{2} \mathrm{CO}_{3} and (NH4)3NO3\left(\mathrm{NH}_{4}\right)_{3} \mathrm{NO}_{3}

B

K2HCO3\mathrm{K}_{2} \mathrm{HCO}_{3} and Zn3(PO4)2\mathrm{Zn}_{3}\left(\mathrm{PO}_{4}\right)_{2}

C

AgHCO3\mathrm{AgHCO}_{3} and K3PO4\mathrm{K}_{3} \mathrm{PO}_{4}

D

ZnCO3\mathrm{ZnCO}_{3} and (NH4)2PO4\left(\mathrm{NH}_{4}\right)_{2} \mathrm{PO}_{4}

[Maximum number: 1]

Which atom has exactly three unpaired electrons in the ground state?

A

an isolated gaseous aluminium atom

B

an isolated gaseous carbon atom

C

an isolated gaseous chromium atom

D

an isolated gaseous phosphorus atom

[Maximum number: 1]

Which atom has its outermost electron in an orbital of the shape shown, with principal quantum number 3 ?

Question image
A

sodium

B

chlorine

C

calcium

D

bromine

[Maximum number: 1]

This question refers to isolated gaseous atoms.
In which atom are all electrons paired?

A

Ba

B

Br

C

S

D

Si

[Maximum number: 1]

Which ion has the same electronic configuration as Cl\mathrm{Cl}^{-}?

A

F\mathrm{F}^{-}

B

P+\mathrm{P}^{+}

C

Sc3+\mathrm{Sc}^{3+}

D

Si4+\mathrm{Si}^{4+}

[Maximum number: 1]

Use of the Data Booklet is relevant to this question.
Atoms of element X have six unpaired electrons.
What could be element X ?

A

carbon

B

chromium

C

iron

D

selenium

[Maximum number: 1]

A simple ion X+X^{+}contains eight protons.
What is the electronic configuration of X+\mathrm{X}^{+}?

A

1s22s12p61 s^{2} \quad 2 s^{1} \quad 2 p^{6}

B

1s22s22p3\begin{array}{rrr}1 s^{2} & 2 s^{2} & 2 p^{3}\end{array}

C

1s22s22p51 s^{2} \quad 2 s^{2} \quad 2 p^{5}

D

1s22s22p7\begin{array}{rrr}1 s^{2} & 2 s^{2} & 2 p^{7}\end{array}

[Maximum number: 3]

The elements phosphorus, sulfur and chlorine are in Period 3 of the Periodic Table.

Table 1.1 shows some properties of the elements P to Cl .
The first ionisation energy of S is not shown.

Table 1.1

Table 1.1

(a)
(i)

Complete Table 1.1 to show the number of electrons in the 3 p subshell and the total number of unpaired electrons in an atom of P, S and C 1 .

[ 2 ]
(b)

P3,S2\mathrm{P}^{3-}, \mathrm{S}^{2-} and Cl\mathrm{Cl}^{-}have the same number of electrons.

[ 1 ]
(i)

Give the full electronic configuration of P3\mathrm{P}^{3-}.

[ 1 ]
[Maximum number: 2]

The elements silicon, phosphorus and sulfur are in Period 3 of the Periodic Table.

(a)

Table 1.1 shows some properties of the elements Si to S .

The first ionisation energy of P is not shown.

Table 1.1

Table 1.1

[ 2 ]
(i)

Complete Table 1.1 to show the total number of s and p electrons in an atom of Si, P and S .

[ 2 ]
[Maximum number: 1]

Copper is used in electrical equipment. It has a melting point of 1085C1085^{\circ} \mathrm{C}.

(a)

When KI(aq) is added to CuSO4(aq)\mathrm{CuSO}_{4}(\mathrm{aq}) the blue-coloured solution turns brown and a white precipitate of CuI(s) is seen.

The reaction between copper ions and iodide forms only two products.

[ 1 ]
(i)

State the full electronic configuration of Cu2+\mathrm{Cu}^{2+}.

[ 1 ]
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