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A-Level CAIE Chemistry AS1.2 IsotopesQuestion Bank

[Maximum number: 1]

Atoms with nuclei containing an odd number of protons tend to have fewer isotopes than those with an even number of protons.

(a)

Potassium also has two stable isotopes. Both isotopes have the same chemical properties.

[ 1 ]
(i)

Explain why both isotopes of potassium have the same chemical properties.

[ 1 ]
(a)
(i)

The mass spectrum of a halogenoalkane containing one chlorine atom or bromine atom will show an additional peak at M+2.

State the isotopes of chlorine and bromine responsible for M+2 peaks.
chlorine bromine

[ 1 ]
[Maximum number: 4]

The element magnesium, Mg, proton number 12, is a metal which is used in many alloys which are strong and light.

Magnesium has several naturally occurring isotopes.

(a)

What is meant by the term isotope?

[ 2 ]
(b)

Complete the table below for two of the isotopes of magnesium.

Table

A sample of magnesium had the following isotopic composition:
24Mg,78.60%;25Mg,10.11%;26Mg,11.29%{ }^{24} \mathrm{Mg}, 78.60 \% ;{ }^{25} \mathrm{Mg}, 10.11 \% ;{ }^{26} \mathrm{Mg}, 11.29 \%.

[ 2 ]
[Maximum number: 2]

Sulfur, S, and polonium, Po, are both elements in Group VI of the Periodic Table.

Sulfur has three isotopes.

(a)

Explain the meaning of the term isotope.

[ 2 ]
(a)

The relative atomic mass of an element can be determined using data from its mass spectrum.

The mass spectrum of element X is shown, with the percentage abundance of each isotope labelled.

Question image
[ 3 ]
(i)

Define the terms relative atomic mass and isotope.
relative atomic mass
isotope

[ 3 ]
[Maximum number: 3]

The model of the nuclear atom was first proposed by Ernest Rutherford. He developed this model on the basis of results obtained from an experiment using gold metal foil.

(a)

A sample of gold found in the earth consists of only one isotope.

[ 3 ]
(i)

Explain what is meant by the term isotopes.

[ 2 ]
(ii)

A different sample of gold contains more than one isotope.

Suggest why this different sample of gold has the same chemical properties as the sample found in the earth.

[ 1 ]
(a)

A sample contains three different types of atom: 1840Ar,1940 K{ }_{18}^{40} \mathrm{Ar},{ }_{19}^{40} \mathrm{~K} and 2040Ca{ }_{20}^{40} \mathrm{Ca}.

[ 2 ]
(i)

State fully, in terms of the numbers of subatomic particles, what these three atoms have in common.

[ 1 ]
(ii)

State fully, in terms of the numbers of all subatomic particles, how these three atoms differ from each other.

[ 1 ]
[Maximum number: 1]

Gallium is a metal in Group 13 of the Periodic Table.

(a)

There are two stable isotopes of gallium, 69Ga{ }^{69} \mathrm{Ga} and 71Ga{ }^{71} \mathrm{Ga}.

[ 1 ]
(i)

State, with reference to subatomic particles, how the isotopes 69Ga{ }^{69} \mathrm{Ga} and 71Ga{ }^{71} \mathrm{Ga} differ from each other.

[ 1 ]
[Maximum number: 1]

Atoms contain the subatomic particles electrons, protons and neutrons. Protons and electrons were discovered by observations of their behaviours in electric fields.

(a)

Hydron is a general term used to represent the ions 11H+,12H+{ }_{1}^{1} \mathrm{H}^{+},{ }_{1}^{2} \mathrm{H}^{+}and 13H+{ }_{1}^{3} \mathrm{H}^{+}.

State, in terms of subatomic particles in the nucleus, what is the same about each of these ions and what is different.
same
different

[ 1 ]
[Maximum number: 3]

Calcium, magnesium and radium are Group 2 elements. Radium follows the same trends as the other members of Group 2.

(a)
(i)

1225Mg{ }_{12}^{25} \mathrm{Mg} is an isotope of magnesium.

Determine the number of protons and neutrons in an atom of 1225Mg{ }_{12}^{25} \mathrm{Mg}.
number of protons
number of neutrons

[ 1 ]
(b)

A sample of magnesium contains three isotopes, 25Mg,26Mg{ }^{25} \mathrm{Mg},{ }^{26} \mathrm{Mg} and X.

The percentage abundance of the three isotopes is shown in Table 1.1.

Table 1.1

Table 1.1

[ 2 ]
(i)

State one similarity and one difference in the properties of these isotopes of magnesium. Explain your answer.

[ 2 ]
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