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CAIE AS Chemistry 16 Hydroxy Compounds

Practise alcohol preparation, classification, reactions, oxidation products, iodoform testing and relative acidity, selecting reagents and conditions for each transformation.

Syllabus
2028–2030
Course
Chemistry 9701
Level
AS

16. Hydroxy compounds question 1

[Maximum number: 1]

Allyl chloride is an important chemical used in the manufacture of plastics, pharmaceuticals and pesticides.

allyl chloride

allyl chloride

A series of reactions starting from allyl chloride is shown.

Figure for Question 16. Hydroxy compounds question 1 — CAIE A-Level Chemistry AS

Suggest a reagent that can be used in reaction 1.

16. Hydroxy compounds question 2

[Maximum number: 2]

Fig. 4.1 shows how propane, C3H8\mathrm{C}_{3} \mathrm{H}_{8}, can be converted to propanoic acid, CH3CH2COOH\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{COOH}.

Fig. 4.1

Fig. 4.1

Question (a)

(a)

Reaction 3 takes place when CH3CH2CH2OH\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH} is heated under reflux with acidified potassium dichromate(VI) solution.

[ 2 ]

Question (i)

(i)

State the colour change that takes place in the reaction mixture.

[ 1 ]

Question (ii)

(ii)

Construct an equation to represent reaction 3. Use [O] to represent an atom of oxygen from the oxidising agent.

[ 1 ]

16. Hydroxy compounds question 3

[Maximum number: 1]

Compound V is a liquid.
V contains 77.2 % carbon, 11.4 % hydrogen and 11.4 % oxygen by mass.
V has a relative molecular mass of 280 .

W, X and Y have the same molecular formula, C5H10O\mathrm{C}_{5} \mathrm{H}_{10} \mathrm{O}.

W, X and Y are added separately to different reagents. Observations for these reactions are described in Table 4.1.

Table 4.1

Table 4.1

State the formula of the yellow precipitate produced when X is added to alkaline I2(aq)\mathrm{I}_{2}(\mathrm{aq}).

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