CAIE A-Level Chemistry AS 8 Reaction Kinetics Questions

Practise measuring reaction rates and explaining how collision frequency, activation energy and catalysts affect them, then interpret experimental data and reaction pathway…

Syllabus
2028–2030
Course
Chemistry 9701
Level
AS

Question 1

[Maximum number: 1]

A student carries out four experiments to investigate the rate of reaction between 3.0 g of calcium carbonate and hydrochloric acid.

CaCO3( s)+2HCl(aq)CaCl2(aq)+CO2( g)+H2O(l)\mathrm{CaCO}_{3}(\mathrm{~s})+2 \mathrm{HCl}(\mathrm{aq}) \rightarrow \mathrm{CaCl}_{2}(\mathrm{aq})+\mathrm{CO}_{2}(\mathrm{~g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l})

experiment 1CaCO31 \quad \mathrm{CaCO}_{3} powder +2.0moldm3HCl+2.0 \mathrm{moldm}^{-3} \mathrm{HCl} at 35C35^{\circ} \mathrm{C}
experiment 2CaCO32 \mathrm{CaCO}_{3} powder +2.0moldm3HCl+2.0 \mathrm{moldm}^{-3} \mathrm{HCl} at 35C35^{\circ} \mathrm{C}
experiment 3 large chips of CaCO3+1.0moldm3HCl\mathrm{CaCO}_{3}+1.0 \mathrm{moldm}^{-3} \mathrm{HCl} at room temperature
experiment 4 large chips of CaCO3+1.0moldm3HCl\mathrm{CaCO}_{3}+1.0 \mathrm{moldm}^{-3} \mathrm{HCl} at 35C35^{\circ} \mathrm{C}

The student collects the CO2( g)\mathrm{CO}_{2}(\mathrm{~g}) and times how long it takes to produce the same volume of gas for each experiment.

What could be the correct times for the four experiments?

experiment 1 /s

experiment 2 /s

experiment 3 /s

experiment 4 /s

5

10

30

95

5

10

95

30

5

30

95

10

95

30

10

5

Question 2

[Maximum number: 1]

For a certain endothermic reaction, the activation energy is numerically equal to twice the enthalpy change of reaction.

Which reaction pathway diagram is correct for this reaction?

A
Figure for Question 2 — CAIE A-Level Chemistry AS — Option A
B
Figure for Question 2 — CAIE A-Level Chemistry AS — Option B
C
Figure for Question 2 — CAIE A-Level Chemistry AS — Option C
D
Figure for Question 2 — CAIE A-Level Chemistry AS — Option D

Question 3

[Maximum number: 1]

The Boltzmann distribution for the hydrogenation of an alkene at a particular temperature in the absence of a catalyst is shown.

Figure for Question 3 — CAIE A-Level Chemistry AS

Which row correctly describes the effects of adding a nickel catalyst to the reaction vessel?

the shape of the Boltzmann distribution

activation energy, EaE_{a}

changes

decreases

changes

increases

does not change

decreases

does not change

increases

Question 4

[Maximum number: 1]

The decomposition of hydrogen peroxide in the presence of MnO2\mathrm{MnO}_{2} produces water and oxygen gas.

The volume of gas collected when 0.2 g of MnO2\mathrm{MnO}_{2} is added to two different hydrogen peroxide solutions at 20C20^{\circ} \mathrm{C} is shown on the graph as curves X and Y .

Figure for Question 4 — CAIE A-Level Chemistry AS

Which row shows the conditions that will result in curves X and Y ?

volume of H2O2/cm3\mathrm{H}_{2} \mathrm{O}_{2} / \mathrm{cm}^{3}

concentration of H2O2/moldm3\mathrm{H}_{2} \mathrm{O}_{2} / \mathrm{moldm}^{-3}

form of MnO2\mathrm{MnO}_{2}

volume of H2O2/cm3\mathrm{H}_{2} \mathrm{O}_{2} / \mathrm{cm}^{3}

concentration of H2O2/moldm3\mathrm{H}_{2} \mathrm{O}_{2} / \mathrm{moldm}^{-3}

form of MnO2\mathrm{MnO}_{2}

50

0.1

lumps

50

0.2

powder

25

0.2

powder

25

0.1

lumps

50

0.1

lumps

20

0.2

powder

20

0.2

powder

40

0.1

lumps

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