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CAIE AS Chemistry 6 Electrochemistry

Practise oxidation numbers, electron-transfer equations and identification of oxidising or reducing agents, using redox changes to construct and interpret balanced reactions.

Syllabus
2028–2030
Course
Chemistry 9701
Level
AS

6. Electrochemistry question 1

[Maximum number: 2]

Nitrogen and phosphorus are elements in Group 15 of the Periodic Table.

Question (a)

(a)

A common test for nitrates is the reaction with NaOH and Al . Equation 1 shows the reaction.

 equation 13NO3+8Al+5OH+18H2O3NH3+8[Al(OH)4]\text { equation } 1 \quad 3 \mathrm{NO}_{3}^{-}+8 \mathrm{Al}+5 \mathrm{OH}^{-}+18 \mathrm{H}_{2} \mathrm{O} \rightarrow 3 \mathrm{NH}_{3}+8\left[\mathrm{Al}(\mathrm{OH})_{4}\right]^{-}
[ 2 ]

Question (i)

(i)

Deduce the oxidation state of nitrogen in NO3\mathrm{NO}_{3}^{-}.

[ 1 ]

Question (ii)

(ii)

Identify the species that is oxidised in equation 1.

[ 1 ]

6. Electrochemistry question 2

[Maximum number: 1]

Chlorine is a reactive element. It forms many compounds.

Bleach is used as a cleaning product to kill bacteria. It is made by adding compounds like sodium chlorate(I), NaClO, to water.

Sodium chlorate(I), NaClO, reacts with hydrogen peroxide to produce sodium chloride, water and oxygen gas.

Construct an equation for this reaction.

6. Electrochemistry question 3

[Maximum number: 1]

The Group 17 elements are oxidising agents.

Explain how the Group 17 elements act as oxidising agents.

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