CAIE A-Level Chemistry 9 Period 3 Chemical Periodicity
Practise interpreting Period 3 trends in physical properties and explaining them through structure and bonding.
- Syllabus
- 2028–2030
- Course
- Chemistry 9701
- Level
- AS
Practise interpreting Period 3 trends in physical properties and explaining them through structure and bonding.
Table 1 gives physical data for some of the Period 3 elements.

Table 1
Complete the row in the table labelled 'maximum oxidation number'.
(+) 1 & (+) 2 & (+) 3 & (+) 4 & (+) 5 & (+) 6
Use the axes to sketch a graph that shows the trend in melting points of the elements with atomic numbers 11 to 17.

Correct sketch of the trend in melting points is shown in the attached official markscheme figure.

Dmitri Mendeleev published the first Periodic Table in 1869.
Mendeleev used his knowledge of chemical periodicity to propose the properties of gallium, 31Ga, a Group 13 element.
Table 2 gives some chemical and physical data of elements in Group 13.

Table 2
Complete the table by predicting values for the missing data.
M1 density of 13Al : value within range 2.5−5.0( g cm−3)
M2 cationic radius of 31Ga : value within range 0.055−0.075( nm)
M3 boiling point of 49In : value within range 1500-2300 (K)
Indium and aluminium are elements in Group 13 of the Periodic Table.
Indium has very similar chemical properties to aluminium.
- Indium reacts vigorously with hydrochloric acid to form a colourless gas and a salt in solution.
- Indium oxide, In2O3, is amphoteric.
- Gaseous indium bromide has the formula In2Br6. This molecule contains coordinate bonds.
Construct an equation for the reaction of In2O3 with excess aqueous NaOH .
Correct equation:
In2O3+2NaOH+3H2O→2NaIn(OH)4
The Group 17 elements are oxidising agents.
Write an equation to show the reaction in which Cl2 oxidises aluminium metal.
2Al+3Cl2→2AlCl3}
Table 1.3 gives some information about MgCl2 and SiCl4.

Table 1.3
Suggest the pH of the solutions that form when each chloride is added to water.
MgCl2SiCl4
M1 MgCl2pH=7
M2 SiCl4pH0−4
The element astatine, At, is below iodine in Group 17 of the Periodic Table.
Which statements concerning At are likely to be correct?
1 It is a dark-coloured solid at room temperature.
2 It is a more powerful oxidising agent than iodine.
3 Its hydride is more thermally stable than HBr .
1, 2 and 3 are correct
1 and 2 only are correct
2 and 3 only are correct
1 only is correct
D
The table gives some data for elements in the third period and some of their compounds.

Complete the table to show the bonding in the elements, and the formulae of their oxides and chlorides.
| Na | Mg | Al | Si | P |
|---|---|---|---|---|
| metallic | metallic | metallic | covalent | covalent |
| Na2O | MgO | Al2O3 | SiO2 | P4O10 |
| NaCl | MgCl2 | AlCl3 | SiCl4 | PCl5 |
On the axes, sketch the trend in melting point of the elements Na to S .

graph rises to maximum for Si , then falls
Give three statements to explain your sketch.
1
2
3
Max. 3 from:
- increasing strength of metallic bond; Na<Mg<Al
OR stronger attraction between delocalised electrons and (positive) ion so melting point of Na<Mg<Al
- Si is giant covalent AND it has the highest melting point due to breaking / presence of strong (covalent) bonds OR Si requires the most energy because the covalent bonds in Si are stronger than metallic bonds (in Na / Mg / Al )
- P and S have weak(er) intermolecular forces / induced dipoles / van der Waals forces (than covalent / metallic bonds) so have low(er) melting points
- S(8) has stronger/more intermolecular forces/van der Waals forces/induced dipoles than P(4) so melting point of S(8) is higher
Write an equation for the reaction of P4O10 with water.
P4O10+6H2O→4H3PO4