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CAIE A-Level Chemistry 9 Period 3 Chemical Periodicity

Practise interpreting Period 3 trends in physical properties and explaining them through structure and bonding.

Syllabus
2028–2030
Course
Chemistry 9701
Level
AS

9. The Periodic Table: chemical periodicity question 1

[Maximum number: 7]

Question (a)

(a)

Table 1 gives physical data for some of the Period 3 elements.

Table 1

Table 1

[ 1 ]

Question (i)

(i)

Complete the row in the table labelled 'maximum oxidation number'.

[ 1 ]

Question (b)

(b)

Use the axes to sketch a graph that shows the trend in melting points of the elements with atomic numbers 11 to 17.

Figure for Question (b) — CAIE A-Level Chemistry AS
[ 2 ]

Question (c)

(c)

Dmitri Mendeleev published the first Periodic Table in 1869.

Mendeleev used his knowledge of chemical periodicity to propose the properties of gallium, 31Ga{ }_{31} \mathrm{Ga}, a Group 13 element.

Table 2 gives some chemical and physical data of elements in Group 13.

Table 2

Table 2

Complete the table by predicting values for the missing data.

[ 3 ]

Question (d)

(d)

Indium and aluminium are elements in Group 13 of the Periodic Table.

Indium has very similar chemical properties to aluminium.
- Indium reacts vigorously with hydrochloric acid to form a colourless gas and a salt in solution.
- Indium oxide, In2O3\mathrm{In}_{2} \mathrm{O}_{3}, is amphoteric.
- Gaseous indium bromide has the formula In2Br6\mathrm{In}_{2} \mathrm{Br}_{6}. This molecule contains coordinate bonds.

[ 1 ]

Question (i)

(i)

Construct an equation for the reaction of In2O3\mathrm{In}_{2} \mathrm{O}_{3} with excess aqueous NaOH .

[ 1 ]

9. The Periodic Table: chemical periodicity question 2

[Maximum number: 3]

The Group 17 elements are oxidising agents.

Question (a)

(a)

Write an equation to show the reaction in which Cl2\mathrm{Cl}_{2} oxidises aluminium metal.

[ 1 ]

Question (b)

(b)

Table 1.3 gives some information about MgCl2\mathrm{MgCl}_{2} and SiCl4\mathrm{SiCl}_{4}.

Table 1.3

Table 1.3

[ 2 ]

Question (i)

(i)

Suggest the pH of the solutions that form when each chloride is added to water.
MgCl2\mathrm{MgCl}_{2}SiCl4\mathrm{SiCl}_{4}

[ 2 ]

9. The Periodic Table: chemical periodicity question 3

[Maximum number: 1]

The element astatine, At, is below iodine in Group 17 of the Periodic Table.
Which statements concerning At are likely to be correct?

1 It is a dark-coloured solid at room temperature.
2 It is a more powerful oxidising agent than iodine.
3 Its hydride is more thermally stable than HBr .

A

1, 2 and 3 are correct

B

1 and 2 only are correct

C

2 and 3 only are correct

D

1 only is correct

9. The Periodic Table: chemical periodicity question 4

[Maximum number: 8]

The table gives some data for elements in the third period and some of their compounds.

Table for Question 9. The Periodic Table: chemical periodicity question 4 — CAIE A-Level Chemistry AS

Question (a)

(a)

Complete the table to show the bonding in the elements, and the formulae of their oxides and chlorides.

[ 3 ]

Question (b)

(b)

On the axes, sketch the trend in melting point of the elements Na to S .

Figure for Question (b) — CAIE A-Level Chemistry AS
[ 1 ]

Question (c)

(c)

Give three statements to explain your sketch.

1
2
3

[ 3 ]

Question (d)

(d)

Write an equation for the reaction of P4O10\mathrm{P}_{4} \mathrm{O}_{10} with water.

[ 1 ]
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