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Edexcel IAL Chemistry A2 17.9 why some aqueous ions are colourless

Edexcel IAL Chemistry A2 17.9 why some aqueous ions are colourless
Pearson Edexcel IAL Chemistry syllabusChemistry YCH11First assessment 2019

A colourless ion often lacks the right transition: full d, empty d, no f electrons or an energy gap outside the visible region prevents visible absorption.

How this is tested

  • Explain colourless ions by full or empty d subshells preventing d-d transitions.
  • Use energy gaps outside the visible spectrum to justify a colourless ion.
  • Apply f-electron reasoning to colourless lanthanide aqua ions when needed.