2.2.1—Covalent bonding
- Syllabus
- First assessment 2025
- Objective
- 2.2.1
- Level
- HL
A covalent bond is the electrostatic attraction between a shared electron pair and the nuclei of the bonded atoms. Lewis formulas show valence electrons and shared pairs.
Use the octet tendency to place shared and lone pairs, while remembering that the assessed Lewis scope allows up to four electron pairs around an atom.
Build a Lewis formula by counting all valence electrons, choosing a skeleton, completing outer octets and placing any remainder on the central atom. Then recount electrons and formal charge; a shared pair contributes to the attraction between both nuclei rather than belonging exclusively to either atom.
Charged-species check: NH₄⁺ has 5 + 4(1) − 1 = 8 valence electrons, so draw four N–H shared pairs, no lone pair on N, enclose the ion in brackets and write the overall + charge. A final audit must match the available electron total, complete the required outer-shell arrangements and reproduce the species charge; lone pairs, shared pairs and formal charges answer different parts of that audit.
Representative question
Draw the Lewis formula of the HCN molecule.
Hx˙CxxxxxN:N:
Accept any combination of dots or
crosses to represent electrons, or
lines to represent electron pairs.
Retrieve the covalent pathway: shared pairs and bond order lead to geometry, polarity and molecular polarity; structure determines network properties, IMF behaviour and chromatography; HL representations extend to resonance, formal charge, sigma/pi bonds and hybridization.
Check the representation first, then count domains, apply geometry, identify polarity or forces, and connect the structure to the requested property or HL bonding description.