IB Chemistry HL 2.2.10 Chromatography Questions
Use exam questions to calculate and interpret Rf or retention data and explain separation through competing phase attractions.
- Syllabus
- First assessment 2025
- Course
- Chemistry HL
- Level
- HL
Use exam questions to calculate and interpret Rf or retention data and explain separation through competing phase attractions.
A student wanted to determine what colour inks were mixed to produce black ink and their relative polarities using paper chromatography. The student decided to use two different solvent systems for the separation, both a mixture of propan-2-ol and water. System 1 was 20 % propan-2-ol and system 2 was 80 % propan-2-ol.
Calculate the retardation factor, RF, of the red ink in both chromatograms.
Substances & RF values
Red ink separated with 20\% propan-2-ol & 0.566
Red ink separated with 80\% propan-2-ol & 0.451
Marking guidance:
Accept 0.530-0.580 for M1.
Accept 0.430-0.480 for M2.
Deduce, with a reason, which coloured ink is more polar, red or blue.
blue AND travels further with higher concentration water/lower concentration propan-2-ol
OR
blue AND travels less with lower concentration water/higher concentration propan-2-ol
higher concentration water mixture more polar
OR
higher concentration propan-2-ol mixture less polar
-
Explain how the separation of inks is achieved using paper chromatography.
«inks» have different attraction to mobile phase AND stationary phase OR
«inks» separated based on solubilities in/affinities to the two phases OR
separations based on polarities/polar attractions
continuous cycle of adsorption and desorption/dissolution
OR
ink/sample/solute moves when in solvent AND does not move when on paper
Marking guidance:
Allow answers in terms of an equilibrium/partitioning for M1.