IB Chemistry HL 2.4 From Models to Materials Questions

Practise bonding classification, alloy structure and polymer chemistry, including how monomers, chain architecture and condensation shape material properties.

Syllabus
First assessment 2025
Course
Chemistry HL
Level
HL

Exam points

  • Use electronegativity difference and average values to classify bonds and estimate percentage ionic character.
  • Place compounds on the bonding triangle to predict material properties or explain mixed bonding.
  • Distinguish an alloy from a composite using the constituents and arrangement of their phases.
  • Explain how size-mismatched alloy atoms distort layers, changing hardness, strength or conductivity.
  • Compare thermoplastics, thermosets and elastomers through cross-links, flexibility and heat response.
  • Relate polymer branching, tacticity or plasticisers to chain packing, melting point and flexibility.
  • Judge plastic uses or end-of-life options from material performance, recycling and biodegradability evidence.
  • Draw addition-polymer repeat units or recover alkene monomers with side-group connectivity intact.
  • Distinguish addition from condensation polymers by monomers, repeating linkages and small-molecule by-products.

Question 1

[Maximum number: 3]

Iron may be extracted from iron (II) sulfide, FeS.

Question (a)

(a)

Iron (II) sulfide, FeS, is ionically bonded.

[ 1 ]

Question (i)

(i)

Suggest why chemists find it convenient to classify bonding into ionic, covalent and metallic.

[ 1 ]

Question (b)

(b)

Explain why the addition of small amounts of carbon to iron makes the metal harder.

[ 2 ]

Question 2

[Maximum number: 2]

A sample of bromine has the following composition by mass:

79Br:50.75%81Br:49.25%\begin{array}{cc} { }^{79} \mathrm{Br}: & 50.75 \% \\ { }^{81} \mathrm{Br}: & 49.25 \% \end{array}

Deduce, showing your working, the type of bonding and percentage covalent character in calcium bromide, CaBr2\mathrm{CaBr}_{2}. Use sections 9 and 17 of the data booklet.

Question 3

[Maximum number: 2]

Titanium and vanadium are consecutive elements in the first transition metal series.

Explain why an aluminium-titanium alloy is harder than pure aluminium.

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