IB Chemistry HL Structure 2 Models of Bonding and Structure Questions

Practise IB Chemistry HL Structure 2 with reviewed questions on bonding, resonance, hybridisation, molecular structure, materials and intermolecular forces.

Syllabus
First assessment 2025
Course
Chemistry HL
Level
HL

Exam points

  • Predict ion formation and construct neutral ionic formulae from electron configurations and ion charges.
  • Construct and interpret Lewis structures, including formal charge, resonance and expanded octets.
  • Use VSEPR, hybridization and sigma/pi bonding to predict geometry, bond angles and polarity.
  • Explain bond-strength trends, covalent-network properties and delocalization using structure and electron models.
  • Identify intermolecular forces and use them to explain phase changes, solubility and material properties.

Question 1

[Maximum number: 1]

How does a lithium atom form the most stable ion?

A

The atom gains a proton to form a positive ion.

B

The atom loses a proton to form a negative ion.

C

The atom loses an electron to form a positive ion.

D

The atom gains an electron to form a negative ion.

Question 2

[Maximum number: 4]

Phosphine (IUPAC name phosphane) is a hydride of phosphorus, with the formula PH3\mathrm{PH}_{3}.

Question (a)

(a)

Draw a Lewis (electron dot) structure of phosphine.

[ 1 ]

Question (b)

(b)

State the hybridization of the phosphorus atom in phosphine.

[ 1 ]

Question (c)

(c)

Outline whether you expect the bonds in phosphine to be polar or non-polar, giving a brief reason.

Figure for Question (c) — IB Chemistry HL

Phosphine has a much greater molar mass than ammonia. Explain why phosphine has a significantly lower boiling point than ammonia.

[ 2 ]

Question 3

[Maximum number: 7]

Titanium and vanadium are consecutive elements in the first transition metal series.

Question (a)

(a)

Describe the bonding in metals.

[ 2 ]

Question (b)

(b)

Suggest why the melting point of vanadium is higher than that of titanium.

[ 1 ]

Question (c)

(c)

Explain why an aluminium-titanium alloy is harder than pure aluminium.

[ 2 ]

Question (d)

(d)

State the type of bonding in potassium chloride which melts at 1043 K .

[ 1 ]

Question (e)

(e)

A chloride of titanium, TiCl4\mathrm{TiCl}_{4}, melts at 248 K . Suggest why the melting point is so much lower than that of KCl .

[ 1 ]

Question 4

[Maximum number: 6]

Iron may be extracted from iron (II) sulfide, FeS.

Question (a)

(a)

Outline why metals, like iron, can conduct electricity.

[ 1 ]

Question (b)

(b)

Iron (II) sulfide, FeS, is ionically bonded.

[ 3 ]

Question (i)

(i)

Describe the bonding in this type of solid.

[ 2 ]

Question (ii)

(ii)

Suggest why chemists find it convenient to classify bonding into ionic, covalent and metallic.

[ 1 ]

Question (c)

(c)

Explain why the addition of small amounts of carbon to iron makes the metal harder.

[ 2 ]
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