IB Chemistry HL 2.2.5 Bond Polarity Questions
Use exam questions to classify polar bonds, compare electronegativity differences and annotate δ+ and δ− dipoles in structural formulas.
- Syllabus
- First assessment 2025
- Course
- Chemistry HL
- Level
- HL
Use exam questions to classify polar bonds, compare electronegativity differences and annotate δ+ and δ− dipoles in structural formulas.
Phosphine (IUPAC name phosphane) is a hydride of phosphorus, with the formula PH3.
Outline whether you expect the bonds in phosphine to be polar or non-polar, giving a brief reason.
Phosphine has a much greater molar mass than ammonia. Explain why phosphine has a significantly lower boiling point than ammonia.
PH_3 has London «dispersion» forces
NH_3 forms H-bonds
H-bonds are stronger
OR
London forces are weaker
Marking guidance:
Accept van der Waals' forces, dispersion forces and instantaneous dipole - induced dipole forces.
Accept "dipole-dipole forces" as molecule is polar.
H-bonds in NH_3 (only) must be mentioned to score [2].
Do not award M2 or M3 if:
- implies covalent bond is the H-bond
- implies covalent bonds break.
Accept "dipole-dipole forces are weaker".
2 max