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Edexcel IAL Chemistry A2 11.9 SN1 and SN2 rate evidence

Edexcel IAL Chemistry A2 11.9 SN1 and SN2 rate evidence
Pearson Edexcel IAL Chemistry syllabusChemistry YCH11First assessment 2019

Determine which concentrations appear in the rate law, connect first-order RX dependence to carbocation formation and two-reactant dependence to concerted attack.

How this is tested

  • Link rate = k[RX] to an SN1 slow ionisation step and carbocation intermediate.
  • Support SN2 when rate is first order in both halogenoalkane and nucleophile.
  • Interpret a two-peak SN1 profile with a carbocation intermediate between transition states.