CAIE A-Level Chemistry AS 8.3 Homogeneous and Heterogeneous Catalysts Questions

Practise explaining catalysis through an alternative lower-EA mechanism, energy profiles and Boltzmann distributions.

Syllabus
2028–2030
Course
Chemistry 9701
Level
AS

Exam points

  • state that a catalyst provides a different mechanism with a lower activation energy
  • show the catalysed pathway with lower peak height but unchanged reactant, product and ΔH levels
  • use the larger Boltzmann area above the lower EA to explain the increased effective-collision frequency

Question 1

[Maximum number: 1]

The Boltzmann distribution for the hydrogenation of an alkene at a particular temperature in the absence of a catalyst is shown.

Figure for Question 1 — CAIE A-Level Chemistry AS

Which row correctly describes the effects of adding a nickel catalyst to the reaction vessel?

the shape of the Boltzmann distribution

activation energy, EaE_{a}

changes

decreases

changes

increases

does not change

decreases

does not change

increases

Question 2

[Maximum number: 1]

Gas Q decomposes slowly at room temperature.

Q( g)X( g)+Z( g)\mathrm{Q}(\mathrm{~g}) \rightarrow \mathrm{X}(\mathrm{~g})+\mathrm{Z}(\mathrm{~g})

The Boltzmann distribution curve for gas Q at room temperature is shown.

Figure for Question 2 — CAIE A-Level Chemistry AS

Which change occurs when a catalyst is added to gas Q ?

A

The peak of the curve moves to the right on the diagram.

B

The number of particles with enough energy to decompose increases.

C

The kinetic energy of the unreacted particles increases.

D

The value of EaE_{\mathrm{a}} decreases, moving the vertical dotted line to the right on the diagram.

Question 3

[Maximum number: 1]

Two experiments are carried out to study the reaction between zinc and sulfuric acid.
experiment 1 Small lumps of zinc are added to excess dilute sulfuric acid.
experiment 2 The reaction is carried out at a lower temperature and with one other change.

Both experiments produce the same total volume of gas and are completed in the same time.
What is the second change made in experiment 2 ?

A

A catalyst is added.

B

A greater mass of zinc is added.

C

A greater volume of sulfuric acid is added.

D

Larger lumps of zinc are used.

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