3.2.11—Reduction of unsaturated compounds
- Syllabus
- First assessment 2025
- Objective
- 3.2.11
- Level
- HL
Hydrogenation adds H2 across π bonds. Continue addition until the required saturated product is formed; nickel, palladium or platinum catalysts with heat or pressure are typical conditions.
Count π bonds to determine hydrogen demand: one mole of H₂ saturates one C=C, while full conversion of one C≡C to C–C needs two moles of H₂. Keep the carbon skeleton unchanged when drawing the product.
Representative question
State the reagent and conditions needed and draw the structural formula of the product.
Official product structure shown in the figure.
Reagent:
H2 with Ni, Pd or Pt catalyst
Product:
CH3CH2CH2CH2CH2CH3
Accept the condensed formula CH3(CH2)4CH3.
Retrieve the route: assign oxidation states, balance half-equations, predict displacement, label cells, trace electrons and ions, follow organic redox pathways, calculate potentials and choose electrolysis products.
Check electron loss/gain, anode/cathode versus polarity, spontaneous sign, salt-bridge direction, ions present, organic functional-group direction and object-cathode placement.