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CAIE A-Level Chemistry 4.2.3 Deducing Structure and Bonding

Practise using physical and chemical evidence to infer bonding and structure without relying on formula alone.

Syllabus
2028–2030
Course
Chemistry 9701
Level
AS

Exam points

  • use melting or boiling point to distinguish simple molecular substances from giant structures
  • use solid, molten and aqueous conductivity to identify available mobile ions or electrons
  • combine solubility, hydrolysis and mechanical evidence with physical data before choosing a structure

4.2.3—The type of structure and bonding present question 1

[Maximum number: 2]

Bismuth is an element in Group 15 of the Periodic Table.

Bismuth reduces water to form bismuth oxide, Bi2O3\mathrm{Bi}_{2} \mathrm{O}_{3}. A colourless gas that ignites with a squeaky pop also forms.

Bi2O3\mathrm{Bi}_{2} \mathrm{O}_{3} is a yellow insoluble solid that melts at 1090 K . The molten compound conducts electricity.

Deduce the structure and bonding of Bi2O3\mathrm{Bi}_{2} \mathrm{O}_{3}. Explain your answer.

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