Edexcel IGCSE Chemistry G Covalent Bonding Questions
Practise covalent bonding through definitions, dot-and-cross diagrams, molecular boiling points and giant covalent structure-property links.
- Syllabus
- First assessment 2019
- Course
- Chemistry 4CH1
Practise covalent bonding through definitions, dot-and-cross diagrams, molecular boiling points and giant covalent structure-property links.
The atoms in methanol are held together by covalent bonds.
State what is meant by the term covalent bond.
- two / a pair of electrons
- shared between two atoms
Accept:
- electrons attracted to the nuclei of the two atoms in the bond
- electrostatic attraction between two nuclei and the shared pair(s) of electrons between them
Draw a dot-and-cross diagram to show the bonding in a molecule of methanol.
Show only the outer electrons of each atom.
- four pairs of electrons around the central carbon atom, with one pair to O and three pairs to H
- the rest of the molecule fully correct
Allow:
- any combination of dots and crosses
Marking guidance:
- M2 depends on M1.
This question is about the covalent compounds hydrogen chloride and silicon dioxide.
Describe the forces of attraction in a covalent bond.
Either:
- attraction between nuclei
- and shared pairs of electrons
Or:
- attraction between shared pairs of electrons
- and nuclei
Reject:
- intermolecular forces for both marks
Marking guidance:
- Nucleus must be plural.
Hydrogen chloride has the formula HCl
Draw a dot-and-cross diagram to show the bonding in a hydrogen chloride molecule.
Show only the outer shell electrons in each atom.
M1 one shared pair of electrons
M2 rest of the molecule correct
ALLOW any combination of dots and crosses
ALLOW any inner shells of chlorine as long as they are correct
Explain why the boiling point of hydrogen chloride is low.
- intermolecular forces of attraction are weak
- so they require little energy to overcome
Allow:
- weak forces between molecules
Do not accept:
- less energy alone
Marking guidance:
- Energy mark depends on the weak-forces mark.
The diagram shows part of the structure of silicon dioxide.
Silicon dioxide has the same structure as diamond.
Silicon dioxide is very hard and has a very high melting point.
Explain these properties.
Refer to the structure and bonding of silicon dioxide in your answer.
an explanation linking any 5 of the following points:
NB do not credit high melting point as in the question
M1 giant (covalent) structure / lattice
M2 covalent bonds are strong
M3 which requires a lot of energy to break the (covalent) bonds
M4 3D / tetrahedral structure
M5 every silicon atom makes 4 bonds / 4 pairs of electrons shared
M6 no layers / atoms cannot slide over each other
ALLOW strong attraction between shared pairs of electrons and nuclei
M3 being dep on covalent do not allow more energy
Lose 1 mark if they mention intermolecular forces or ionic bonding
A student uses this apparatus to investigate the decomposition of hydrogen peroxide solution.
This is the equation for the reaction.
Complete the dot-and-cross diagram for a molecule of hydrogen peroxide.
Show outer electrons only.
- 3 bond pairs correct
- rest of molecule fully correct
Allow:
- any combination of dots and crosses
Marking guidance:
- The full-molecule mark depends on the bond-pairs mark.
- Use the verified answer image for the dot-and-cross diagram.
The atoms in methanol are held together by covalent bonds.
State what is meant by the term covalent bond.
- two / a pair of electrons
- shared between two atoms
Accept:
- electrons attracted to the nuclei of the two atoms in the bond
- electrostatic attraction between two nuclei and the shared pair(s) of electrons between them
This question is about the covalent compounds hydrogen chloride and silicon dioxide.
Describe the forces of attraction in a covalent bond.
Either:
- attraction between nuclei
- and shared pairs of electrons
Or:
- attraction between shared pairs of electrons
- and nuclei
Reject:
- intermolecular forces for both marks
Marking guidance:
- Nucleus must be plural.
Carbon dioxide is a simple molecular covalent substance.
Explain why carbon dioxide turns from a solid to a gas at a very low temperature.
An explanation that links the following two points:
- weak forces of attraction between molecules / weak intermolecular forces of attraction
- little energy is needed to overcome the intermolecular forces
Allow:
- weak intermolecular bonds
- weak intermolecular attractions
- little energy needed to separate the molecules
Ignore:
- less energy
Marking guidance:
- The second mark depends on the first mark being correct or missing.
The table gives some information about five gases.
Why does chlorine have the highest boiling point of the gases in the table?
chlorine has the strongest covalent bonds between its atoms
chlorine has the strongest covalent bonds between its molecules
chlorine has the strongest ionic bonds between its atoms
chlorine has the strongest forces of attraction between its molecules
D
This question is about the covalent compounds hydrogen chloride and silicon dioxide.
The diagram shows part of the structure of silicon dioxide.
Silicon dioxide has the same structure as diamond.
Silicon dioxide is very hard and has a very high melting point.
Explain these properties.
Refer to the structure and bonding of silicon dioxide in your answer.
an explanation linking any 5 of the following points:
NB do not credit high melting point as in the question
M1 giant (covalent) structure / lattice
M2 covalent bonds are strong
M3 which requires a lot of energy to break the (covalent) bonds
M4 3D / tetrahedral structure
M5 every silicon atom makes 4 bonds / 4 pairs of electrons shared
M6 no layers / atoms cannot slide over each other
ALLOW strong attraction between shared pairs of electrons and nuclei
M3 being dep on covalent do not allow more energy
Lose 1 mark if they mention intermolecular forces or ionic bonding
Diamond and graphite are both giant covalent substances made up of carbon atoms.
- diamonds are used in cutting tools
- graphite is used in pencils to make marks on paper
Explain, with reference to structure and bonding, why each substance is suitable for its particular use.
Any explanation that links any three of the following points for diamond
M1 each (carbon) atom is (covalently) bonded to four other (carbon) atoms
M2 in a (giant) tetrahedral lattice /network / structure
M3 the (covalent) bonds are (very) strong
M4 (therefore) diamond is (very) hard (and so good for cutting tools)
Any explanation that links any three of the following points for graphite
M5 each (carbon) atom is (covalently) bonded to three other (carbon) atoms
M6 (the structure is) in layers
M7 weak forces (between layers)
M8 (the layers can) slide over each other/ rub off
M9 this makes graphite soft (so it can make marks on paper)
ALLOW each carbon has four bonds
ALLOW 3D/rigid in place of tetrahedral
ALLOW reference to lot of energy needed to break the (covalent) bonds
ALLOW there are lots of/many (covalent) bonds
ALLOW diamond is (very) strong
If mention of intermolecular forces in diamond MAX 2 for diamond
If mention of ions in diamond only M4 can be scored
ALLOW sheets
ALLOW slippery
If mention of intermolecular forces in graphite MAX 2 for graphite
If mention of ions in graphite only M9 can be scored