Edexcel IGCSE Chemistry E Chemical Formulae Equations and Calculations Questions

Practise balancing equations and using formulae, Mr and mole ratios for reacting masses, yields and composition.

Syllabus
First assessment 2019
Course
Chemistry 4CH1

Exam points

  • balance formula units and state symbols before taking stoichiometric ratios
  • convert between mass and moles using Mr, then apply the balanced-equation ratio
  • calculate percentage composition, yield or empirical formula from supplied data

Question 1

[Maximum number: 5]

This question is about magnesium metal and its compounds.

Question (a)

(a)

Magnesium burns in oxygen gas to form solid magnesium oxide.

[ 2 ]

Question (i)

(i)

Complete the chemical equation for the reaction by balancing the equation and adding the state symbols.

Figure for Question (i) — Edexcel IGCSE Chemistry
[ 2 ]

Question (b)

(b)

A student uses this method to make a solution of magnesium chloride.

Step 1. measure 25 cm325 \mathrm{~cm}^{3} of dilute hydrochloric acid into a beaker
Step 2 add magnesium powder a little at a time
Step 3 keep adding magnesium powder until it is in excess
Step 4 remove the excess magnesium powder by filtration

This is the equation for the reaction.

Figure for Question (b) — Edexcel IGCSE Chemistry
[ 3 ]

Question (i)

(i)

Calculate the minimum mass of magnesium needed to react with 25.0 cm325.0 \mathrm{~cm}^{3} of 2.00 mol/dm32.00 \mathrm{~mol} / \mathrm{dm}^{3} hydrochloric acid.
[for Mg,Ar=24\mathrm{Mg}, \mathrm{A}_{\mathrm{r}}=24 ]

mass = g

[ 3 ]

Question 2

[Maximum number: 1]

Crude oil is a mixture of hydrocarbons.

One of the hydrocarbons in the refinery gas fraction is an alkane with the structural formula CH3CH2CH2CH3\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}

Calculate the relative molecular mass (Mr)\left(M_{\mathrm{r}}\right) of this alkane.

Mr=M_{r}=

Question 3

[Maximum number: 3]

The diagram shows the positions of some elements in part of the Periodic Table.

Na Al S Cl
K Xe
In

Table for Question 3 — Edexcel IGCSE Chemistry

A teacher adds a small piece of sodium to a glass trough containing water and universal indicator.

The universal indicator changes colour.
The equation for the reaction is

2Na( s)+2H2O(l)→2NaOH(aq)+H2( g)2 \mathrm{Na}(\mathrm{~s})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \rightarrow 2 \mathrm{NaOH}(\mathrm{aq})+\mathrm{H}_{2}(\mathrm{~g})

The reaction with sodium produces 0.036 g of hydrogen gas.

One mole of hydrogen gas contains 6.0×10236.0 \times 10^{23} molecules.
Calculate the number of molecules of hydrogen gas produced in the reaction with sodium.

Give your answer to two significant figures.
number of molecules of hydrogen gas =

Question 4

[Maximum number: 2]

This question is about magnesium metal and its compounds.

Magnesium burns in oxygen gas to form solid magnesium oxide.

Complete the chemical equation for the reaction by balancing the equation and adding the state symbols.

Figure for Question 4 — Edexcel IGCSE Chemistry

Question 5

[Maximum number: 3]

A sample of iron(III) oxide reacts with excess carbon monoxide.

This is the equation for the reaction.

Fe2O3+3CO→2Fe+3CO2\mathrm{Fe}_{2} \mathrm{O}_{3}+3 \mathrm{CO} \rightarrow 2 \mathrm{Fe}+3 \mathrm{CO}_{2}

Calculate the minimum mass of iron(III) oxide needed to produce a theoretical yield of 28 g of iron.
[for Fe2O3Mr=160\mathrm{Fe}_{2} \mathrm{O}_{3} \quad M_{\mathrm{r}}=160 ]
minimum mass of iron(III) oxide =

Question 6

[Maximum number: 2]

A sample of iron(III) oxide reacts with excess carbon monoxide.

This is the equation for the reaction.

Fe2O3+3CO→2Fe+3CO2\mathrm{Fe}_{2} \mathrm{O}_{3}+3 \mathrm{CO} \rightarrow 2 \mathrm{Fe}+3 \mathrm{CO}_{2}

The actual yield of iron from this sample is 21 g .

Calculate the percentage yield of iron.

Question 7

[Maximum number: 4]

Sodium sulfate can be prepared by the reaction between sodium hydroxide solution and sodium hydrogensulfate ( NaHSO4\mathrm{NaHSO}_{4} ) solution.

This is the equation for the reaction.

NaOH(aq)+NaHSO4(aq)→Na2SO4(aq)+H2O(l)\mathrm{NaOH}(\mathrm{aq})+\mathrm{NaHSO}_{4}(\mathrm{aq}) \rightarrow \mathrm{Na}_{2} \mathrm{SO}_{4}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l})

Sodium hydrogensulfate solution is acidic.
A student adds 25.0 cm325.0 \mathrm{~cm}^{3} of sodium hydroxide solution to a conical flask and adds two drops of indicator.

The student does a titration.

Crystals of hydrated sodium sulfate decompose when heated.

This is the equation for the decomposition.

Figure for Question 7 — Edexcel IGCSE Chemistry

A student uses this apparatus to find the value of x .
hydrated sodium sulfate

Figure for Question 7 — Edexcel IGCSE Chemistry

The student heats the crystals until the decomposition is complete.
The table shows the student's results.

Table for Question 7 — Edexcel IGCSE Chemistry

Use the results to calculate the value of x .
[for Na2SO4,Mr=142\mathrm{Na}_{2} \mathrm{SO}_{4}, M_{\mathrm{r}}=142 for H2O,Mr=18\mathrm{H}_{2} \mathrm{O}, M_{\mathrm{r}}=18 ]


value of x=

Question 8

[Maximum number: 2]

Ocimene is an organic compound that gives some plants their particular smell.
The molecular formula of ocimene is C10H16\mathrm{C}_{10} \mathrm{H}_{16}

Using ocimene as an example, explain what is meant by the term empirical formula.

Question 9

[Maximum number: 5]

The table shows the structures of six organic compounds.

Table for Question 9 — Edexcel IGCSE Chemistry

Question (a)

(a)

Another compound, G, has this percentage composition by mass.

C=37.8%H=6.3%Cl=55.9%\mathrm{C}=37.8 \% \quad \mathrm{H}=6.3 \% \quad \mathrm{Cl}=55.9 \%

Show by calculation that the empirical formula of compound G is C2H4Cl\mathrm{C}_{2} \mathrm{H}_{4} \mathrm{Cl}

[ 3 ]

Question (b)

(b)

The relative formula mass ( MrM_{\mathrm{r}} ) of G is 127

Determine the molecular formula of G .

[ 2 ]

Question 10

[Maximum number: 3]

This question is about magnesium metal and its compounds.

A student uses this method to make a solution of magnesium chloride.

Step 1. measure 25 cm325 \mathrm{~cm}^{3} of dilute hydrochloric acid into a beaker
Step 2 add magnesium powder a little at a time
Step 3 keep adding magnesium powder until it is in excess
Step 4 remove the excess magnesium powder by filtration

This is the equation for the reaction.

Figure for Question 10 — Edexcel IGCSE Chemistry

Calculate the minimum mass of magnesium needed to react with 25.0 cm325.0 \mathrm{~cm}^{3} of 2.00 mol/dm32.00 \mathrm{~mol} / \mathrm{dm}^{3} hydrochloric acid.
[for Mg,Ar=24\mathrm{Mg}, \mathrm{A}_{\mathrm{r}}=24 ]

mass = g

Question 11

[Maximum number: 5]

This question is about octane (C8H18)\left(\mathrm{C}_{8} \mathrm{H}_{18}\right) which is produced in the gasoline fraction during fractional distillation of crude oil.

A car is driven at constant speed for 4.00 km .

The exhaust gases are collected and their volume at room temperature and pressure (rtp) is 5.02×105 cm35.02 \times 10^{5} \mathrm{~cm}^{3}.

The exhaust gases include carbon dioxide and oxides of nitrogen.
The carbon dioxide is removed from the exhaust gases. The volume of the remaining gases at rtp is 2.96×105 cm32.96 \times 10^{5} \mathrm{~cm}^{3}.

Show that the car produces less than 100 g of carbon dioxide per km.
[molar volume of carbon dioxide at rtp =24000 cm3=24000 \mathrm{~cm}^{3} ]

Question 12

[Maximum number: 4]

Question (a)

(a)

A student uses this apparatus to determine the formula of magnesium oxide.

Figure for Question (a) — Edexcel IGCSE Chemistry

This is the student's method.
- find mass of empty crucible and lid
- place some magnesium ribbon in crucible
- find mass of crucible, lid and magnesium ribbon
- heat crucible, lifting lid occasionally
- after five minutes, find mass of crucible, lid and magnesium oxide

[ 4 ]

Question (i)

(i)

Explain why the student lifts the lid.

[ 2 ]

Question (ii)

(ii)

The mass of magnesium oxide formed is less than expected.

Describe what the student should do next to obtain a more accurate value for the mass of magnesium oxide.

[ 2 ]
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