1.3.7 (HL)—Successive ionization energies

Syllabus
First assessment 2025
Objective
1.3.7
Level
HL

Successive Ionization Energies

HL only

Successive ionization energies rise as electrons are removed. A very large increase occurs when removal crosses from the outer shell into a lower, more tightly held shell.

Observation Deduction
Small increases before the large jump Electrons are being removed from the same outer shell
Large jump The next electron is from an inner shell
Number removed before the jump Outer-electron count and group pattern

Use the position of the first large jump, not its numerical size alone, to infer the group.

A jump after three outer-electron removals is the pattern used in the study guide for a group 13 element. The same count-before-the-jump method applies to new data.

Locate the first order-of-magnitude jump before naming the group. A large jump after the second electron is removed shows two outer-shell electrons; the third electron would come from a lower shell, supporting a group 2 assignment.

Electron Configurations Summary

Retrieve the chain: emission lines reveal discrete levels; capacities, sublevels, orbitals, and spin rules build configurations; first and successive ionization energies then reveal how electrons are held and arranged.

When checking an answer, ask: Did I link a line to a transition? Did I use 2n² and the filling rules? Did I explain an ionization trend or count electrons before a successive-IE jump?