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Edexcel IAL Chemistry AS 10.13 C–X bond enthalpy and reactivity

Edexcel IAL Chemistry AS 10.13 C–X bond enthalpy and reactivity
Pearson Edexcel IAL Chemistry syllabusChemistry YCH11First assessment 2019

Compare C–Cl, C–Br and C–I strengths directly: the weaker lower-enthalpy bond breaks more readily, so the iodoalkane hydrolyses fastest.

How this is tested

  • Rank hydrolysis as iodoalkane faster than bromoalkane faster than chloroalkane.
  • Justify the order using decreasing C–X bond enthalpy rather than polarity or solubility.