1.3.4—Sublevels

Syllabus
First assessment 2025
Objective
1.3.4
Level
SL

Sublevels, Orbitals, and Blocks

A main energy level contains only the sublevels allowed by its principal quantum number: n = 1 has s; n = 2 has s and p; n = 3 has s, p and d; and n = 4 can include s, p, d and f. Within one main level the sublevels rise in energy s < p < d < f, while the filling order across different levels can interleave, as the next card makes explicit. Each sublevel contains a fixed number of orbitals.

A spherical s orbital and three perpendicular dumbbell-shaped p orbitals are linked to the orbital hierarchy and periodic-table blocks.
A spherical s orbital and three perpendicular dumbbell-shaped p orbitals are linked to the orbital hierarchy and periodic-table blocks.
A spherical s orbital and three perpendicular dumbbell-shaped p orbitals are linked to the orbital hierarchy and periodic-table blocks.
Sublevel Number of orbitals Maximum electrons Assessed shape evidence Periodic-table block
s 1 2 spherical s block
p 3 6 three dumbbell orbitals with different orientations p block
d 5 10 shape detail not required here d block
f 7 14 shape detail not required here f block

The block is identified by the subshell being filled; sublevel capacity is not the same as actual occupancy.

For recognition questions, keep the hierarchy clear: main energy level → sublevel → orbital. The s and p shapes are the explicitly required shape evidence here.

Use the hierarchy as a classification test: a p sublevel contains three orbitals, and each orbital can hold two electrons. An orbital describes a probability region with a characteristic shape; it is not a circular route travelled by an electron.

Recognising Orbital Shapes

[ 2 ]

Sketch the shapes of two different orbital types in the second energy level and label each orbital.

Drawing canvas

Electron Configurations Summary

Retrieve the chain: emission lines reveal discrete levels; capacities, sublevels, orbitals, and spin rules build configurations; first and successive ionization energies then reveal how electrons are held and arranged.

When checking an answer, ask: Did I link a line to a transition? Did I use 2n² and the filling rules? Did I explain an ionization trend or count electrons before a successive-IE jump?