3.2.5—IUPAC nomenclature
- Syllabus
- First assessment 2025
- Objective
- 3.2.5
- Level
- HL
| Step | Naming decision |
|---|---|
| 1 | Choose the longest parent chain |
| 2 | Number to give the relevant feature the lowest locant |
| 3 | Identify unsaturation and functional group |
| 4 | Assemble prefixes, locants, and suffix |
Apply the systematic sequence to saturated or mono-unsaturated compounds with up to six carbons and one functional-group type.
For CH₃CH(OH)CH(CH₃)CH₃, choose the four-carbon chain containing –OH, number from the end that gives –OH the lower locant, and name 3-methylbutan-2-ol. The principal suffix controls numbering before a substituent does; check locants, punctuation and retained unsaturation at the end.
Representative question
Deduce the systematic name of X using IUPAC nomenclature.
3,5,5-trimethylhexanal
Marking guidance:
Accept 5,5,3 instead of 3,5,5 do not penalize missing hyphen/dash
Retrieve the route: translate formulae, identify functional groups and series, name and classify isomers, then use mass, IR, and NMR evidence together to determine structure.
Check connectivity, functional-group evidence, formula/mass constraint, shifts and integration, splitting neighbours, and agreement across every technique.