Edexcel IGCSE Chemistry B Crude Oil Questions
Practise crude oil questions on fractions, boiling points, fuel combustion, acid rain, cracking and alkane or alkene formulae.
- Syllabus
- First assessment 2019
- Course
- Chemistry 4CH1
Practise crude oil questions on fractions, boiling points, fuel combustion, acid rain, cracking and alkane or alkene formulae.
Crude oil is a mixture of hydrocarbons.
Name the process used to separate crude oil into fractions.
fractional distillation
Accept:
- fractionation / fractionating
Ignore:
- distillation alone
Give one use of the kerosene fraction.
aircraft fuel / jet fuel / paraffin / fuel for lamps or heaters
Allow:
- heating oil
- cooking fuel
Catalytic cracking is used to convert long-chain alkanes into shorter-chain alkanes.
Name the catalyst used in catalytic cracking.
alumina / silica
Accept:
- aluminium oxide
- silicon dioxide
- AlX2OX3
- SiOX2
- zeolite(s)
- aluminosilicate(s)
Explain why it is necessary to convert long-chain alkanes into shorter-chain alkanes.
An explanation that links the following two points:
- greater demand for short-chain alkanes than long-chain alkanes
- more long-chain alkanes than are needed / too great a supply of / surplus of long-chain alkanes, or not enough short-chain alkanes to meet demand
Allow:
- short-chain alkanes are more useful than long-chain alkanes
- short-chain alkanes are needed for specific uses, e.g. petrol
Catalytic cracking also produces alkenes.
CX11HX24 can undergo cracking to give pentane (CX5HX12) and two different alkenes.
Complete the equation for this cracking reaction.
CX11HX24 -> CX5HX12 + ...... + ......
CX11HX24CX5HX12+CX2HX4+CX4HX8
Marking guidance:
- Alkenes can be in either order.
- 1 mark for CX2HX4.
- 1 mark for CX4HX8.
Allow:
- CX6HX12 / 2CX3HX6 / CX3HX6 + CX3HX6 for 1 mark
- correct displayed formulae
Crude oil is an important source of organic compounds.
The diagram shows crude oil being separated into different fractions.
Name the process used to separate crude oil into different fractions.
fractional distillation
Allow:
- fractionating / fractionation
State what happens to the crude oil at X .
crude oil/it is heated/vapourised
ALLOW boiled
IGNORE evaporates
Describe the differences between fraction B and fraction E.
In your answer, refer to
- size of the molecules
- boiling point
- colour
- viscosity
A description which refers to the following four points:
- B contains larger / longer molecules
- B has a higher boiling point
- B has a darker colour
- B is more viscous / has greater viscosity
Accept:
- reverse arguments for E
- E is more volatile
- comparison giving specific colours, e.g. B is orange and E is pale yellow
- E is more runny
Ignore:
- melting point
Marking guidance:
- Maximum 2 marks if no reference is made to fractions B or E.
Crude oil often contains sulfur as an impurity.
Explain why this is a problem when using crude oil fractions as fuels.
An explanation which links the following two points:
- when sulfur burns, sulfur dioxide / SOX2 is formed
- this causes acid rain
Allow:
- sulfur trioxide / SOX3
- a specified harmful effect of acid rain
- references to causing / exacerbating respiratory problems
- greenhouse gas / causes global warming / climate change
Ignore:
- sulfur oxides
Some cars in Brazil use ethanol, C2H5OH, as a fuel instead of petrol.
The ethanol is made by the fermentation of glucose which is obtained from sugar cane.
The sugar is extracted from the sugar cane and then dissolved in water to make a sugar solution.
State what is meant by the term fuel.
a substance that releases thermal energy / heat energy when burned / combusted
Ignore:
- energy on its own
Crude oil is a mixture of hydrocarbons.
Name the process used to separate crude oil into fractions.
fractional distillation
Accept:
- fractionation / fractionating
Ignore:
- distillation alone
Crude oil is a mixture of hydrocarbons.
Give one use of the kerosene fraction.
aircraft fuel / jet fuel / paraffin / fuel for lamps or heaters
Allow:
- heating oil
- cooking fuel
Crude oil is an important source of organic compounds.
The diagram shows crude oil being separated into different fractions.
Describe the differences between fraction B and fraction E.
In your answer, refer to
- size of the molecules
- boiling point
- colour
- viscosity
A description which refers to the following four points:
- B contains larger / longer molecules
- B has a higher boiling point
- B has a darker colour
- B is more viscous / has greater viscosity
Accept:
- reverse arguments for E
- E is more volatile
- comparison giving specific colours, e.g. B is orange and E is pale yellow
- E is more runny
Ignore:
- melting point
Marking guidance:
- Maximum 2 marks if no reference is made to fractions B or E.
This question is about hydrocarbons.
One homologous series of hydrocarbons is the alkanes.
Pentane (C5H12) is an alkane.
Incomplete combustion can occur when the oxygen supply is limited.
Give the names of two products of the incomplete combustion of pentane.
1 ................................
2 ................................
Any two from:
- carbon monoxide
- carbon
- water
Accept:
- correct formulae / symbols
- soot for carbon
This question is about hydrocarbons.
One homologous series of hydrocarbons is the alkanes.
Pentane (C5H12) is an alkane.
One of the products of incomplete combustion is a poisonous gas.
State why this gas is poisonous to humans.
reduces / limits the capacity of blood to transport oxygen
Accept:
- prevents blood from carrying oxygen
- correct references to haemoglobin, e.g. prevents haemoglobin from carrying oxygen
This question is about octane (C8H18) which is produced in the gasoline fraction during fractional distillation of crude oil.
A car is driven at constant speed for 4.00 km .
The exhaust gases are collected and their volume at room temperature and pressure (rtp) is 5.02×105 cm3.
The exhaust gases include carbon dioxide and oxides of nitrogen.
The carbon dioxide is removed from the exhaust gases. The volume of the remaining gases at rtp is 2.96×105 cm3.
Explain how oxides of nitrogen form in a car engine.
M1 nitrogen (from the air) reacts / combines with oxygen (from the air)
REJECT any implication that oxygen or nitrogen come from the fuel.
Crude oil is an important source of organic compounds.
Crude oil often contains sulfur as an impurity.
Explain why this is a problem when using crude oil fractions as fuels.
An explanation which links the following two points:
- when sulfur burns, sulfur dioxide / SOX2 is formed
- this causes acid rain
Allow:
- sulfur trioxide / SOX3
- a specified harmful effect of acid rain
- references to causing / exacerbating respiratory problems
- greenhouse gas / causes global warming / climate change
Ignore:
- sulfur oxides
This question is about octane (C8H18) which is produced in the gasoline fraction during fractional distillation of crude oil.
A car is driven at constant speed for 4.00 km .
The exhaust gases are collected and their volume at room temperature and pressure (rtp) is 5.02×105 cm3.
The exhaust gases include carbon dioxide and oxides of nitrogen.
The carbon dioxide is removed from the exhaust gases. The volume of the remaining gases at rtp is 2.96×105 cm3.
Give a reason why oxides of nitrogen should not be released into the atmosphere.
Any one from:
acid rain
respiratory problems
Crude oil is a mixture of hydrocarbons.
Catalytic cracking is used to convert long-chain alkanes into shorter-chain alkanes.
Explain why it is necessary to convert long-chain alkanes into shorter-chain alkanes.
An explanation that links the following two points:
- greater demand for short-chain alkanes than long-chain alkanes
- more long-chain alkanes than are needed / too great a supply of / surplus of long-chain alkanes, or not enough short-chain alkanes to meet demand
Allow:
- short-chain alkanes are more useful than long-chain alkanes
- short-chain alkanes are needed for specific uses, e.g. petrol