E.1.11 (HL)—Bohr angular momentum
- Syllabus
- First assessment 2025
- Objective
- —
- Level
- HL
Apply the angular-momentum condition
The Bohr model permits only integer values of n=1,2,3,…. The electron's orbital angular momentum is therefore quantized rather than continuously variable.
L=mvr=\frac{nh}{2\pi}
Worked example — n=4
For n=4, L=4h/(2π)=4(6.63×10−34)/(2π)=4.22×10−34kgm2s−1. An intermediate value is not an allowed Bohr-orbit angular momentum.
Connect quantization to energy
Only selected radii, speeds and total energies are allowed. The electron cannot occupy an intermediate orbit energy in this model, which explains discrete atomic levels and line spectra.
Use ratios efficiently
For hydrogen, combining the quantization condition with the electrostatic circular-orbit model gives rn∝n2 and vn∝1/n. If r2/r1=4, then v2/v1=1/2.
Common trap
Do not say that quantization fixes only the radius. The condition restricts angular momentum and leads to discrete allowed energies; do not treat mvr as an arbitrary continuous value.
Questions ask for the consequence of quantization or use radius and energy relationships to compare electron speeds in different states.
Outline / Determine
State that energy is discrete, then use the correct proportional relationship or quantization condition for a ratio calculation.
Saying that the energy remains continuous or using v proportional to r instead of the inverse square-root or inverse-n relationship required by the model.