IB Chemistry SL 1.1.3 Temperature and Kinetic Energy Topic Practice

Question 1

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Nitrogen dioxide, NO2\mathrm{NO}_{2}, is a brown, toxic and corrosive gas. It can be made in a school laboratory by heating a group II metal nitrate or by the reaction of copper, Cu , with concentrated nitric acid, HNO3\mathrm{HNO}_{3}.

The initial amount of NO2\mathrm{NO}_{2} was determined by titration. The oxide was first dissolved in water according to the following equation:

2NO2( g)+H2O(l)HNO3(aq)+HNO2(aq)2 \mathrm{NO}_{2}(\mathrm{~g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{HNO}_{3}(\mathrm{aq})+\mathrm{HNO}_{2}(\mathrm{aq})

The solution was made up to 250.0 cm3250.0 \mathrm{~cm}^{3} and 25.0 cm325.0 \mathrm{~cm}^{3} portions of this solution were then titrated against a 0.0500 moldm30.0500 \mathrm{~mol} \mathrm{dm}^{-3} standard solution of sodium hydroxide, NaOH .

Calculate the values for temperature, T , in degrees kelvin, K , and complete the table.

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