3.1.5—Metal/non-metal continuum

Syllabus
First assessment 2025
Objective
3.1.5
Level
SL

Oxides Across the Continuum

Region Typical oxide character Water/reaction reasoning
Metal side Basic Can form alkaline solution with water
Boundary Amphoteric Can react as acid or base in the appropriate context
Non-metal side Acidic Can form an acid with water

Use balanced equations as evidence for the classification: Na₂O + H₂O → 2NaOH and SO₃ + H₂O → H₂SO₄ are representative basic and acidic cases. The bonding/electronegativity trend explains why the character changes across the period, but it does not guarantee that every oxide reacts readily with water.

Al₂O₃ is the useful boundary case: it is amphoteric, so it can react with an acid such as HCl and with a strong base such as NaOH. Do not label an oxide from the element's position alone—check the stated reaction and distinguish a water reaction from acid–base behaviour in another medium.

Environmental link: sulfur oxides dissolve and can be oxidized to acids that increase HX+\ce{H+} in rainwater, causing acid rain. Atmospheric COX2\ce{CO2} dissolves in seawater and participates in COX2+HX2OHX2COX3HX++HCOX3X\ce{CO2 + H2O <=> H2CO3 <=> H+ + HCO3-}, increasing HX+\ce{H+} and lowering ocean pH. These are acidification mechanisms; do not treat every non-metal oxide as reacting with water in exactly the same way.

Writing Oxide Reactions

Assessment in practice

Representative question

Question 1

[Maximum number: 1]

Write the equation for the reaction between sodium oxide and water.

The Periodic Table Summary

Retrieve the route: locate an element from configuration, explain periodic and group trends, write oxide/reaction and oxidation-state answers, then connect incomplete d-sublevels to transition properties, ion configurations, and colours.

Check that every trend explanation names its particle-level cause, every equation is balanced, every oxidation state is a formal charge convention, and every transition colour uses absorbed/observed complementarity.