35. Polymerisation
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35.1 Condensation polymerisation
• Describe the formation of polyesters:: (a) the reaction between a diol and a dicarboxylic acid or dioyl chloride; (b) the reaction of a hydroxycarboxylic acid
• Describe the formation of polyamides:: (a) the reaction between a diamine and a dicarboxylic acid or dioyl chloride; (b) the reaction of an aminocarboxylic acid; (c) the reaction between amino acids
• Deduce the repeat unit of a condensation polymer obtained from a given monomer or pair of monomers
• Identify the monomer(s) present in a given section of a condensation polymer molecule
35.2 Predicting the type of polymerisation
35.2.1The type of polymerisation reaction
• Predict the type of polymerisation reaction for a given monomer or pair of monomers
35.2.2The type of polymerisation reaction
• Deduce the type of polymerisation reaction which produces a given section of a polymer molecule
35.3 Degradable polymers
• Recognise that poly(alkenes) are chemically inert and can therefore be difficult to biodegrade
• Recognise that some polymers can be degraded by the action of light
• Recognise that polyesters and polyamides are biodegradable by acidic and alkaline hydrolysis