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IGCSE Chemistry6.2 Rate of reactionQuestion Bank

Question 1

[Maximum number: 5]

Some elements are shown in the order they appear in the reactivity series. The most reactive element is at the top.
> sodium calcium magnesium aluminium zinc iron hydrogen copper

Question 1(e)

(a)

When zinc granules are added to aqueous copper(II) sulfate, a reaction occurs. During the reaction, a red-pink solid is formed and the solution becomes colourless.

[ 5 ]

Question 1(e)(iii)

(i)

Explain, in terms of particles, why the rate of this reaction increases when the temperature is increased.

[ 3 ]

Question 1(e)(iv)

(ii)

Suggest two other ways of increasing the rate of this reaction.

1

2

[ 2 ]

Question 12

[Maximum number: 1]

Which row describes the effect on the activation energy and the frequency of particle collisions when the temperature of a chemical reaction is increased?

activation

energy

frequency

of collisions

increases

increases

no change

increases

increases

no change

no change

no change

Question 12

[Maximum number: 1]

Which change increases the rate of reaction by decreasing the activation energy, EaE_{a} ?

A

addition of a catalyst

B

decrease in size of solid reactants

C

increase in concentration of solutions

D

increase in temperature

Question 13

[Maximum number: 1]

Which change in reaction conditions increases both the collision rate and the proportion of molecules with sufficient energy to react?

A

addition of a catalyst

B

increasing the concentration of a reactant

C

increasing the surface area of a reactant

D

increasing the temperature of the reaction

Question 2

[Maximum number: 5]

A student adds excess large pieces of magnesium carbonate, MgCO3\mathrm{MgCO}_{3}, to dilute hydrochloric acid, HCl , and measures the volume of carbon dioxide gas, CO2\mathrm{CO}_{2}, given off.

Question 2(d)

(a)

The graph shows how the volume of carbon dioxide gas changes with time.
volume of carbon dioxide gas

Question image
[ 5 ]

Question 2(d)(i)

(i)

Describe how the graph shows that the rate of this reaction decreases as time increases.

[ 1 ]

Question 2(d)(ii)

(ii)

Explain, in terms of particles, why the rate of this reaction decreases as time increases.

[ 2 ]

Question 2(d)(iii)

(iii)

The student repeats the experiment using powdered MgCO3\mathrm{MgCO}_{3} instead of large pieces.

All other conditions stay the same.
On the grid, draw the line expected when powdered MgCO3\mathrm{MgCO}_{3} is used instead of large pieces.

[ 2 ]

Question 2

[Maximum number: 3]

Ammonia is manufactured by the Haber process.

Question 2(c)

(a)

Explain, in terms of particles, what happens to the rate of this reaction when the temperature is increased.

[ 3 ]

Question 13

[Maximum number: 1]

A student adds excess magnesium ribbon to 10 cm310 \mathrm{~cm}^{3} of 0.5 mol/dm30.5 \mathrm{~mol} / \mathrm{dm}^{3} sulfuric acid.
The hydrogen gas produced is collected and its total volume is measured every 10 seconds.
The experiment is repeated with 5 cm35 \mathrm{~cm}^{3} of 0.5 mol/dm30.5 \mathrm{~mol} / \mathrm{dm}^{3} sulfuric acid added to 5 cm35 \mathrm{~cm}^{3} of water using the same mass of magnesium ribbon.

Which line on the graph shows the results of the second experiment?

Question image

Question 13

[Maximum number: 1]

An experiment is carried out to find the rate of reaction between hydrochloric acid and zinc.

Zn( s)+2HCl(aq)ZnCl2(aq)+H2( g)\mathrm{Zn}(\mathrm{~s})+2 \mathrm{HCl}(\mathrm{aq}) \rightarrow \mathrm{ZnCl}_{2}(\mathrm{aq})+\mathrm{H}_{2}(\mathrm{~g})

The results of the experiment are shown.

Question image

What is the label on the y-axis?

A

amount of ZnCl2\mathrm{ZnCl}_{2} produced

B

concentration of HCl

C

mass of Zn reacted

D

volume of H2\mathrm{H}_{2} produced

Question 13

[Maximum number: 1]

Magnesium powder reacts with an excess of dilute hydrochloric acid to produce hydrogen gas.
Which statements about this reaction are correct?
1 The smaller the particles of magnesium powder, the more slowly the hydrogen is produced.

2 The higher the temperature, the faster the magnesium powder disappears.
3 The lower the concentration of dilute hydrochloric acid, the faster the rate of reaction.

4 The faster the magnesium powder disappears, the faster the rate of reaction.

A

1 and 2

B

2 and 3

C

2 and 4

D

3 and 4

Question 13

An excess of calcium carbonate reacts with dilute hydrochloric acid. The volume of carbon dioxide produced is measured at regular time intervals. The results are shown as experiment 1.

The experiment is repeated with only one change to the reaction conditions.
The results are shown as experiment 2 .

Question image

Which change is made in experiment 2 ?
A The concentration of the acid is increased.
B The volume of acid is increased.
C The mass of calcium carbonate is increased.
D The calcium carbonate is powdered.

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