E.1.3—Atomic energy levels

Syllabus
First assessment 2025
Objective
Level
SL

Read Spectral Evidence

Emission lines

An excited gas emits light at particular frequencies, producing bright spectral lines rather than a continuous spread of frequencies. Each line corresponds to a permitted energy difference between atomic states.

Absorption lines

When continuous light passes through a cooler gas, the atoms remove the same frequencies they can emit. The resulting dark lines therefore occur at specific, repeatable wavelengths.

Infer discrete levels

Because only particular photon energies are emitted or absorbed, the atom’s energy states are discrete rather than continuous. The spectrum is evidence for quantized atomic energy levels.

Common trap

Do not treat every visible line as a separate element without considering transitions. A spectrum is evidence of allowed energy differences; the pattern, not simply the number of lines, carries the information.

E.1.3 Exam Analysis

Assessment in practice

1–2 marks
How it is assessed

Questions count possible photon-emitting transitions or distinguish what spectra reveal about atoms.

Command terms

State / Identify

What earns marks

Count only allowed downward transitions for emission, and identify discrete atomic energy levels—not mass-energy equivalence—as the inference from line spectra.

Watch for

Counting energy levels instead of allowed transitions or claiming that line spectra directly provide evidence for mass-energy equivalence.

Retrieve the SL Atomic Model

Retrieve the evidence chain

Rutherford scattering supports a small positive nucleus; nuclear notation separates protons, neutrons and electrons; line spectra show discrete energy differences; and Eγ=hf=hc/λE_\gamma=hf=hc/\lambda connects transitions to photons.

Check the model

When reading a spectrum, identify the transition, use the energy difference rather than an absolute level, and compare characteristic lines with known spectra to identify elements.