B.3.3—Ideal gas model

Syllabus
First assessment 2025
Objective
Level
SL

Model an Ideal Gas

Ideal-gas model

An ideal gas is a kinetic-theory model: particles are in constant random motion, occupy negligible volume compared with the container, and interact negligibly except during collisions. Collisions are treated as elastic.

Connect microscopic and macroscopic quantities

Temperature is related to average translational kinetic energy. Pressure comes from momentum transfer when particles collide with the container walls. More energetic or more frequent collisions can increase pressure.

It is an approximation

Real gases have finite-size particles and intermolecular forces. The ideal model is most reliable when particles are far apart and interactions are relatively unimportant.

Common trap

The model does not say every particle has the same speed. It uses a distribution of speeds and averages over many particles.

B.3.3 Exam Analysis

Assessment in practice

1–2 marks
How it is assessed

The evidence uses a two-mark outline of the kinetic theory and a multiple-choice question about elastic collisions with container walls.

Command terms

Outline / State

What earns marks

Describe the kinetic-theory assumptions that connect observables to molecules: random motion, elastic wall collisions, momentum transfer causing pressure, and temperature related to average kinetic energy.

Watch for

Saying all particles have the same speed or that pressure is a static property unrelated to collisions.

Representative question

Question 1

[Maximum number: 2]

Outline how the kinetic theory of gases relates observable properties of a gas to the motion of the molecules.

Synthesize B.3 Gas Laws

Macroscopic equations

Pressure is P=F/AP=F_{\perp}/A. For a fixed amount of gas, empirical laws combine to PV/T=constantPV/T=\text{constant}, and the ideal-gas equations are PV=nRT=NkBTPV=nRT=Nk_BT.

Microscopic model

Particles move randomly and collide elastically with walls. Momentum transfer produces pressure, with P=13ρv2P=\frac13\rho\overline{v^2}. For a monatomic ideal gas, U=32NkBT=32nRTU=\frac32Nk_BT=\frac32nRT.

Bridge the descriptions

Use n=N/NAn=N/N_A to move between moles and particles. Choose the equation from the data provided, convert temperature to kelvin, and keep SI units consistent.

Model boundary

The ideal approximation works best at high temperature and low pressure or density. At high density, high pressure or near condensation, finite particle size and intermolecular forces matter.