IB Chemistry HL 3.2.1 Oxidation and Reduction Questions

Use real HL exam questions to track oxidation-state and electron changes, identify redox agents and interpret redox equations.

Syllabus
First assessment 2025
Course
Chemistry HL
Level
HL

Exam points

  • Identify oxidation or reduction from oxidation-state changes, electron loss or gain, and oxygen/hydrogen changes in the stated species.
  • Identify the oxidizing and reducing agents and the species oxidized or reduced, justifying each assignment from the redox change.
  • Write or interpret redox and disproportionation equations and distinguish redox reactions from non-redox reaction types using the reactants and products.

IB Chemistry HL 3.2.1 Oxidation and Reduction Questions question 1

[Maximum number: 3]

Phosphine (IUPAC name phosphane) is a hydride of phosphorus, with the formula PH3\mathrm{PH}_{3}.

Phosphine is usually prepared by heating white phosphorus, one of the allotropes of phosphorus, with concentrated aqueous sodium hydroxide. The equation for the reaction is:

P4( s)+3OH(aq)+3H2O(l)PH3( g)+3H2PO2(aq)\mathrm{P}_{4}(\mathrm{~s})+3 \mathrm{OH}^{-}(\mathrm{aq})+3 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{PH}_{3}(\mathrm{~g})+3 \mathrm{H}_{2} \mathrm{PO}_{2}^{-}(\mathrm{aq})

Oxidation is now defined in terms of change of oxidation number. Explore how earlier definitions of oxidation and reduction may have led to conflicting answers for the conversion of P4\mathrm{P}_{4} to H2PO2\mathrm{H}_{2} \mathrm{PO}_{2}^{-}and the way in which the use of oxidation numbers has resolved this.

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