2.3 - Waves and Particle Nature of Light

Syllabus
2021
Topic
2.3
Level
AS

Learning objectives

2.3.33Wave quantitiesUnderstand the terms amplitude, frequency, period, speed and wavelength2.3.34Wave equationBe able to use the wave equation v = fλ2.3.35Longitudinal wavesBe able to describe longitudinal waves in terms of pressure variation and the displacement of molecules2.3.36Transverse wavesBe able to describe transverse waves2.3.37Wave graphsBe able to draw and interpret graphs representing transverse and longitudinal waves including standing/stationary waves2.3.38Core Practical 4 - speed of sound in airCORE PRACTICAL 4: Determine the speed of sound in air using a 2-beam oscilloscope, signal generator, speaker and microphone2.3.39Wavefronts, coherence and interferenceKnow and understand what is meant by wavefront, coherence, path difference, superposition, interference and phase2.3.40Phase difference and path differenceBe able to use the relationship between phase difference and path difference2.3.41Standing waves, nodes and antinodesKnow what is meant by a standing or stationary wave, understand how it is formed, and identify nodes and antinodes.2.3.42Speed of a transverse wave on a stringUse v = √(T/μ) for the speed of a transverse wave on a string.2.3.43Core Practical 5 - vibrating string frequencyCORE PRACTICAL 5: Investigate how length, tension and mass per unit length affect the frequency of a vibrating string or wire.2.3.44Intensity of radiationUse I = P/A for the intensity of radiation.2.3.45Refraction at a boundaryUse n1 sin θ1 = n2 sin θ2 at a boundary between two media and refractive index n = c/v.2.3.46Critical angleCalculate critical angle using sin C = 1/n.2.3.47Total internal reflectionBe able to predict whether total internal reflection will occur at an interface2.3.48Measuring refractive indexUnderstand how to measure the refractive index of a solid material2.3.49Plane polarisationUnderstand what is meant by plane polarisation2.3.50Diffraction and Huygens’ constructionUnderstand what is meant by diffraction and use Huygens’ construction to explain what happens to a wave when it meets a slit or an obstacle2.3.51Diffraction grating equationBe able to use nλ = dsinθ for a diffraction grating2.3.52Core Practical 6 - wavelength using diffraction gratingCORE PRACTICAL 6: Determine the wavelength of light from a laser or other light source using a diffraction grating2.3.53Electron diffraction evidenceUnderstand how diffraction experiments provide evidence for the wave nature of electrons2.3.54De Broglie wavelengthUse the de Broglie equation λ = h/p.2.3.55Transmission and reflection at boundariesUnderstand that waves can be transmitted and reflected at an interface between media2.3.56Pulse-echo techniquesUnderstand how a pulse-echo technique can provide information about the position of an object and how the amount of information obtained may be limited by the wavelength of the radiation or by the duration of pulses2.3.57Wave and photon models of EM radiationUnderstand how the behaviour of electromagnetic radiation can be described in terms of a wave model and a photon model, and how these models developed over time2.3.58Photon energyBe able to use the equation E = hf, that relates the photon energy to the wave frequency2.3.59Photon absorption and photoelectron emissionUnderstand that the absorption of a photon can result in the emission of a photoelectron2.3.60Threshold frequency and work functionUnderstand threshold frequency and work function and use the photoelectric equation hf = φ + ½mvmax².2.3.61ElectronvoltBe able to use the electronvolt (eV) to express small energies2.3.62Photoelectric effect evidenceUnderstand how the photoelectric effect provides evidence for the particle nature of electromagnetic radiation2.3.63Atomic line spectra and energy levelsUnderstand atomic line spectra in terms of transitions between discrete energy levels and understand how to calculate the frequency of radiation that could be emitted or absorbed in a transition between energy levels.

Wave quantities describe oscillation and propagation

Quantity Meaning Unit
amplitude AA maximum displacement from equilibrium m, or the unit of the oscillating quantity
period TT time for one complete oscillation s
frequency ff complete oscillations per second; f=1/Tf=1/T Hz
wavelength λ\lambda shortest distance between points in the same phase m
wave speed vv speed at which a phase point or disturbance travels ms1\mathrm{m\,s^{-1}}

On a displacement graph, amplitude is measured from the equilibrium line to a crest or trough, not from crest to trough. A displacement-time graph at one position gives period; a displacement-distance snapshot at one time gives wavelength.

Wave speed is not the speed of a medium particle. In a mechanical wave, particles oscillate locally while the disturbance and energy propagate through the medium.

One wavelength travels during one period

The wave equation is v=fλv=f\lambda. During one period TT, a wavefront moves one wavelength, so v=λ/T=fλv=\lambda/T=f\lambda because f=1/Tf=1/T. Use speed in ms1\mathrm{m\,s^{-1}}, frequency in hertz and wavelength in metres.

Identify the wave speed in the relevant medium, convert prefixes such as MHz or nm, and rearrange before substituting. If speed stays constant, increasing frequency shortens wavelength in inverse proportion.

A sound wave of frequency 680Hz680\,\mathrm{Hz} travels at 340ms1340\,\mathrm{m\,s^{-1}}. Its wavelength is λ=v/f=340/680=0.50m\lambda=v/f=340/680=0.50\,\mathrm{m}.

Frequency is fixed by the source and normally stays unchanged when a wave crosses a boundary; a change in speed therefore changes wavelength, not frequency.

Longitudinal waves create pressure variations

In a longitudinal wave, molecules or particles oscillate parallel to the direction in which the wave travels. Their alternating crowding and separation produce compressions and rarefactions, so pressure varies as the disturbance passes.

Location in a sound wave Molecular pattern Pressure variation
compression molecules closer together than equilibrium pressure above equilibrium
rarefaction molecules farther apart than equilibrium pressure below equilibrium

The wavelength is the distance between neighbouring compressions, neighbouring rarefactions, or any two nearest points in the same phase. A molecule oscillates about its equilibrium position rather than travelling with the wave from source to receiver.

A drawn sine curve for a longitudinal wave is a graph of pressure or displacement; it is not the literal path followed by molecules.

Transverse oscillations are perpendicular to travel

In a transverse wave, the oscillating quantity is perpendicular to the direction of wave propagation. For a wave travelling horizontally along a string, each element of string may move vertically while the disturbance travels horizontally.

A displacement-distance snapshot may show crests and troughs. These mark positive and negative displacement from equilibrium, while wavelength is measured between neighbouring points in the same phase, such as crest to crest.

Transverse waves can be plane polarised because their oscillations have directions perpendicular to travel. This distinguishes them from longitudinal waves, whose oscillations lie along the travel direction.

The material does not travel along the drawn wave shape. Points in the medium oscillate locally as energy is transferred through the wave.

Choose the graph that can reveal the required wave quantity

Graph What it represents Read directly
displacement against time at one position one point's oscillation amplitude and period
displacement against distance at one instant spatial wave profile amplitude and wavelength
pressure against distance longitudinal pressure variation wavelength between equal-phase pressure points
standing-wave amplitude against position fixed amplitude pattern nodes, antinodes and their spacing

Label axes with quantity and unit, use the equilibrium line consistently, and apply any scale factor. Frequency comes from f=1/Tf=1/T after reading a full cycle. For a standing wave, neighbouring nodes or neighbouring antinodes are λ/2\lambda/2 apart.

A longitudinal wave may still be represented by a sinusoidal pressure-distance or displacement-distance graph. The vertical graph coordinate is a measured quantity, not a direction in which the wave itself travels.

A displacement-time graph contains no spatial scale, so wavelength cannot be read directly from it. Likewise, a spatial snapshot alone does not give period.

Core Practical 4: determine the speed of sound in air

Connect a signal generator to a loudspeaker and also to one channel of a 2-beam oscilloscope. Connect a microphone to the second channel. Display stable traces with the same timebase and place the microphone in line with the speaker.

Record the microphone position when the two traces have a clearly defined phase relation, such as in phase. Move the microphone away until that same phase relation next occurs; the displacement is one wavelength. For lower percentage uncertainty, move through several repeats and divide the total displacement by the number of wavelengths.

Read the period from the oscilloscope and calculate f=1/Tf=1/T, or use the calibrated generator frequency. Then calculate v=fλv=f\lambda. Repeat positions and use a best-fit relation where possible; record the air temperature because sound speed depends on conditions.

Moving from in-phase to antiphase corresponds to half a wavelength, not a whole wavelength. Avoid comparing unrelated peaks or using a timebase that cannot display a complete period.

Coherent waves interfere by superposition

Term Precise meaning
wavefront line or surface joining points in the same phase
coherent sources constant phase difference and the same frequency
path difference difference between distances travelled to a point
phase position within an oscillation cycle
superposition resultant displacement is the algebraic sum of individual displacements
interference spatial pattern produced when coherent waves superpose

Waves arriving in phase reinforce to give constructive interference and a larger resultant amplitude. Waves arriving in antiphase oppose and give destructive interference; equal amplitudes can cancel completely.

Interference does not permanently destroy energy. The waves superpose while overlapping, and energy is redistributed across the interference pattern.

Path difference fixes phase difference

A path difference of one wavelength corresponds to one complete phase cycle. Therefore Δϕ=2π(Δx/λ)\Delta\phi=2\pi(\Delta x/\lambda) radians, or Δϕ=360(Δx/λ)\Delta\phi=360^\circ(\Delta x/\lambda).

Path difference Phase difference Interference for waves initially in phase
mλm\lambda 2mπ2m\pi constructive
(m+12)λ(m+\tfrac12)\lambda (2m+1)π(2m+1)\pi destructive
λ/4\lambda/4 π/2\pi/2 intermediate

If Δx=3λ/8\Delta x=3\lambda/8, then Δϕ=2π(3/8)=3π/4\Delta\phi=2\pi(3/8)=3\pi/4 radians, or 135135^\circ. Equivalent phases may differ by any whole multiple of 2π2\pi.

Path difference is a distance; phase difference is an angle. Do not compare their numerical values until path difference has been divided by wavelength.

Opposing progressive waves form a stationary pattern

A standing or stationary wave forms when two coherent waves of the same frequency travel in opposite directions and superpose, commonly because an incident wave reflects. Their interference fixes a pattern of nodes and antinodes in space.

Position Oscillation amplitude Phase relation
node zero boundary between adjacent phase regions
antinode maximum all points between one pair of nodes oscillate in phase

Neighbouring nodes are λ/2\lambda/2 apart, as are neighbouring antinodes; a node and its nearest antinode are λ/4\lambda/4 apart. There is no net energy transfer along an ideal stationary wave, although energy moves locally between stores.

The drawn envelope is not a wave profile travelling sideways. Nodes remain fixed, while points away from nodes oscillate with position-dependent amplitude.

String-wave speed increases with tension and falls with linear density

For a transverse wave on a stretched string, v=T/μv=\sqrt{T/\mu}, where TT is tension in newtons and μ\mu is mass per unit length in kgm1\mathrm{kg\,m^{-1}}. Linear density can be measured from μ=m/L\mu=m/L.

At fixed μ\mu, multiplying tension by four doubles speed. At fixed tension, multiplying μ\mu by four halves speed. The square-root dependence means speed is not directly proportional to either quantity.

For T=90NT=90\,\mathrm{N} and μ=2.5×103kgm1\mu=2.5\times10^{-3}\,\mathrm{kg\,m^{-1}}, v=90/(2.5×103)=190ms1v=\sqrt{90/(2.5\times10^{-3})}=190\,\mathrm{m\,s^{-1}} to two significant figures.

Use tension, not automatically the hanging weight if another arrangement changes the force in the vibrating section. Linear density is mass per length, not total mass.

Core Practical 5: test what controls string frequency

Drive a stretched string with a vibration generator and signal generator. Adjust frequency until a clear stationary-wave pattern with a fixed number of loops appears. Measure vibrating length LL, obtain tension from a hanging load where T=mgT=mg, and determine μ\mu from the mass and length of a sample.

Variable changed Keep constant Linear test for the same mode
length LL T,μT,\mu ff against 1/L1/L
tension TT L,μL,\mu f2f^2 against TT
linear density μ\mu L,TL,T f2f^2 against 1/μ1/\mu

For the fundamental, λ=2L\lambda=2L and f=(1/2L)T/μf=(1/2L)\sqrt{T/\mu}. Change one variable at a time, retune to the same mode, repeat readings and use a best-fit line to judge the predicted relationship.

Comparisons are invalid if the number of loops changes between readings, because that changes wavelength as well as the chosen variable. Frequency does not depend on oscillation amplitude in this model.

Intensity is power distributed over area

Radiation intensity is power incident per unit area perpendicular to propagation: I=P/AI=P/A. Its SI unit is Wm2\mathrm{W\,m^{-2}}. Rearranging gives P=IAP=IA and, over time tt, transferred energy E=IAtE=IAt.

Radiation of intensity 250Wm2250\,\mathrm{W\,m^{-2}} falls normally on a 0.40m20.40\,\mathrm{m^2} surface. The incident power is P=(250)(0.40)=100WP=(250)(0.40)=100\,\mathrm{W}, so 300J300\,\mathrm{J} arrives in 3.0s3.0\,\mathrm{s}.

If a source radiates power uniformly in all directions, the relevant area at radius rr is 4πr24\pi r^2, so I=P/(4πr2)I=P/(4\pi r^2). This inverse-square result follows from the growing spherical area.

Intensity is not total power: the same power gives lower intensity when spread over a larger area. Use the area facing the radiation, not an unrelated surface area.

Refraction follows wave speed at a boundary

Refractive index is n=c/vn=c/v, where cc is light speed in vacuum and vv is light speed in the medium. A larger nn means lower wave speed.

At an interface, n1sinθ1=n2sinθ2n_1\sin\theta_1=n_2\sin\theta_2. Measure both angles from the normal. Light entering a higher-index medium bends toward the normal; entering a lower-index medium bends away.

Light travels from air (n1=1.00)(n_1=1.00) into glass (n2=1.50)(n_2=1.50) at 3030^\circ. Then sinθ2=(1.00/1.50)sin30=0.333\sin\theta_2=(1.00/1.50)\sin30^\circ=0.333, so θ2=19.5\theta_2=19.5^\circ.

Frequency remains fixed at the boundary. Speed and wavelength change together, so bending is not caused by a frequency change. Angles drawn to the surface must be converted to angles to the normal.

At the critical angle, the refracted ray follows the boundary

The critical angle CC is the incidence angle in the higher-index medium for which the refraction angle in the lower-index medium is 9090^\circ. For a material of refractive index nn meeting air, sinC=1/n\sin C=1/n.

Confirm that the ray travels from higher nn to lower nn, calculate 1/n1/n, then use the inverse sine in degree mode. For n=1.52n=1.52, C=sin1(1/1.52)=41.1C=\sin^{-1}(1/1.52)=41.1^\circ.

For two non-air media, Snell's law gives sinC=nlower/nhigher\sin C=n_{lower}/n_{higher}. The ratio must not exceed 1, consistent with the higher-to-lower condition.

At i=Ci=C, the ray is refracted along the interface; total internal reflection requires i>Ci>C. A critical angle is not defined for incidence from lower index to higher index.

Total internal reflection needs two conditions

Check Requirement for total internal reflection
direction wave travels from higher refractive index to lower refractive index
incidence angle i>Ci>C in the higher-index medium

If both conditions hold, no refracted ray propagates into the second medium and the wave reflects internally. At i=Ci=C, the refracted ray travels along the boundary. At i<Ci<C, some wave is transmitted by refraction and some may be reflected.

Identify the two media, locate the normal, calculate or read CC, and compare the incidence angle measured from the normal. State both the comparison and the resulting path.

A large incidence angle alone is insufficient. Total internal reflection cannot occur when light approaches a higher-index medium from a lower-index medium.

Measure refractive index from several angle pairs

Place a transparent block on paper and trace its outline. Direct a narrow monochromatic ray at one face. Mark the incident and transmitted paths, remove the block, join the marks, and draw the normal at the entry point. Measure incidence ii and refraction rr from the normal with a protractor.

Repeat for several incidence angles. For air entering the solid, calculate n=sini/sinrn=\sin i/\sin r, or plot sini\sin i vertically against sinr\sin r horizontally; the best-fit gradient is nn when nair1n_{air}\approx1.

Use a thin ray, widely separated path marks and angles neither extremely small nor near grazing incidence. Repeat measurements and use monochromatic light so different wavelengths do not refract by different amounts.

Do not measure angles from the block face. Measuring from the normal is essential, and one angle pair provides weaker evidence than the gradient of repeated data.

Plane polarisation restricts transverse oscillations

Unpolarised transverse radiation has oscillations in many directions perpendicular to travel. Plane-polarised radiation has oscillations restricted to one plane containing the direction of propagation.

A polarising filter transmits the component aligned with its transmission axis. A second filter acts as an analyser: aligned axes give strong transmission, while perpendicular axes ideally give no transmission. An intermediate angle transmits an intermediate intensity.

Polarisation is possible only when oscillations have a direction perpendicular to propagation. Its observation therefore supports the transverse nature of electromagnetic waves.

Polarisation does not mean the wave travels in one plane; it means the oscillation direction is confined. Longitudinal waves cannot be plane polarised in this way.

Huygens' wavelets explain diffraction

Diffraction is the spreading of waves after passing through a gap or around an obstacle. It is most noticeable when the gap or obstacle size is comparable with the wavelength.

In Huygens' construction, every point on an existing wavefront acts as a source of secondary wavelets. After a short time, the new wavefront is the envelope tangent to those wavelets.

Most wavelets are blocked at a barrier, but wavelets from points across a slit spread into the region beyond it. Their envelope is curved, predicting diffracted wavefronts. At an obstacle edge, unblocked wavelets extend into the geometric shadow.

Diffraction is not refraction: it does not require a change of medium or speed. A very wide gap compared with wavelength produces much less angular spreading.

A diffraction grating links order, spacing and angle

For normal incidence on a diffraction grating, principal maxima satisfy nλ=dsinθn\lambda=d\sin\theta. Here n=0,1,2,n=0,1,2,\ldots is order, dd is slit spacing and θ\theta is measured from the central normal.

Convert line density to spacing: if a grating has NN lines per metre, d=1/Nd=1/N. For lines per millimetre, first multiply by 10001000 to obtain lines per metre.

Identify the order, convert λ\lambda and dd to metres, solve for sinθ=nλ/d\sin\theta=n\lambda/d, then use inverse sine. A possible order must satisfy nλdn\lambda\le d because sinθ1\sin\theta\le1.

The symbol nn here is diffraction order, not refractive index. Measure θ\theta from the central straight-through direction, and do not use small-angle approximations unless justified.

Core Practical 6: determine wavelength with a grating

Mount a diffraction grating of known line density perpendicular to a narrow light beam. Place a screen a measured perpendicular distance DD away. For a laser, keep the beam below eye level, secure it, never view the beam directly and remove reflective objects.

Mark the central maximum and matching order +n+n and n-n maxima. Measure their separation and halve it to obtain xx, reducing centre-location error. Calculate θ\theta from tanθ=x/D\tan\theta=x/D.

Convert line density to dd, then calculate λ=dsinθ/n\lambda=d\sin\theta/n. Repeat with several orders or distances and average consistent values. A graph of sinθ\sin\theta against nn has gradient λ/d\lambda/d, providing a stronger multi-point result.

Screen displacement xx is not the grating angle. Use the right triangle to obtain θ\theta, keep order numbers correct, and do not replace sinθ\sin\theta by x/Dx/D unless the small-angle assumption is explicitly valid.

Electron diffraction reveals matter-wave behaviour

A beam of electrons passing through a thin crystalline target produces a diffraction pattern, such as concentric rings. The regular atomic spacing acts like a diffraction grating.

Diffraction is a wave phenomenon, so the pattern is evidence that electrons have wave behaviour. It occurs when the electron de Broglie wavelength is comparable with the spacing of atomic planes, allowing waves associated with different paths to interfere.

Changing electron momentum changes the de Broglie wavelength and therefore changes the diffraction geometry. The systematic pattern change links the effect to wavelength rather than to random particle scattering.

The experiment does not show electrons are ordinary classical waves or cease to behave as particles. It shows that a complete model must include wave behaviour for electrons.

Every moving particle has a de Broglie wavelength

The de Broglie relationship is λ=h/p\lambda=h/p, where h=6.63×1034Jsh=6.63\times10^{-34}\,\mathrm{J\,s} and pp is momentum in kgms1\mathrm{kg\,m\,s^{-1}}. For a non-relativistic particle, p=mvp=mv.

Calculate momentum first, then divide hh by it. A larger momentum gives a shorter wavelength, so diffraction becomes harder to observe for everyday macroscopic objects.

An electron with momentum 2.0×1023kgms12.0\times10^{-23}\,\mathrm{kg\,m\,s^{-1}} has λ=(6.63×1034)/(2.0×1023)=3.3×1011m\lambda=(6.63\times10^{-34})/(2.0\times10^{-23})=3.3\times10^{-11}\,\mathrm{m}.

Momentum magnitude belongs in the wavelength calculation; direction is not represented by a negative wavelength. The relation applies to material particles, not only electrons.

A boundary can reflect and transmit the same incident wave

When a wave reaches an interface between media, part of its energy may return as a reflected wave and part may enter the second medium as a transmitted wave. The proportions depend on the media and boundary conditions.

Quantity Reflected wave in original medium Transmitted wave in new medium
frequency unchanged unchanged
speed same as incident medium set by new medium
wavelength consistent with original speed changes so v=fλv=f\lambda remains true

For a straight boundary, reflection obeys equal incidence and reflection angles measured from the normal. Transmission may involve refraction when the wave speed changes.

Partial reflection does not mean the rest of the wave disappears. Track reflected and transmitted energy; amplitude is not itself an energy fraction.

Pulse-echo timing locates a reflecting boundary

A transducer sends a short pulse and detects its echo from an interface or object. If wave speed is vv and the delay from emission to echo is tt, the one-way distance is d=vt/2d=vt/2 because the pulse travels out and back.

An ultrasound echo returns after 40μs40\,\mu\mathrm{s} in material where v=4000ms1v=4000\,\mathrm{m\,s^{-1}}. Then d=(4000)(40×106)/2=0.080md=(4000)(40\times10^{-6})/2=0.080\,\mathrm{m}.

Limitation Why information is lost Improvement
wavelength too large nearby or small features cannot be distinguished spatially use shorter wavelength where suitable
pulse duration too long echoes from nearby boundaries overlap; pulse length is vΔtv\Delta t use shorter pulses

Never use vtvt as the object depth for a returned echo unless tt is explicitly a one-way time. Detection also requires the echo to arrive after the transmitted pulse has ended.

Wave and photon models answer different evidence

Model Behaviour it explains directly Core representation
wave model interference, diffraction, polarisation and propagation continuous wavefronts, phase and superposition
photon model discrete light-matter energy transfer and photoelectric emission packets with energy E=hfE=hf

The wave model grew from evidence for interference and diffraction, but a wave-only account could not explain all observations of energy exchange with matter. The photon model was developed to represent those exchanges as discrete interactions. Later evidence therefore extended the available modelling rather than simply erasing the successful wave description.

Choose the model that exposes the behaviour under study. Electromagnetic radiation can display wave behaviour during propagation and interference while exchanging energy with matter in photon-sized amounts.

A model is not a literal picture of everything radiation 'really is'. Neither model alone accounts most clearly for every observation, so evidence determines which representation is useful.

Photon energy is proportional to frequency

The energy of one photon is E=hfE=hf, where h=6.63×1034Jsh=6.63\times10^{-34}\,\mathrm{J\,s} and ff is frequency in hertz. Since f=c/λf=c/\lambda in vacuum, shorter-wavelength radiation has greater photon energy.

For f=6.0×1014Hzf=6.0\times10^{14}\,\mathrm{Hz}, E=(6.63×1034)(6.0×1014)=4.0×1019JE=(6.63\times10^{-34})(6.0\times10^{14})=4.0\times10^{-19}\,\mathrm{J} per photon to two significant figures.

Photon energy and beam intensity are different. At fixed frequency, greater intensity means more photon energy arriving per unit area per unit time, usually through a greater photon rate, not more energy per photon.

Use the frequency of the radiation, not its amplitude, to calculate the energy of one photon. Convert wavelength to frequency before using E=hfE=hf.

One absorbed photon transfers energy to one electron

In the photoelectric effect, one photon is absorbed in a one-to-one interaction with one electron. The photon transfers its energy hfhf as a single amount.

Part of that energy may be required to release the electron from the metal surface. If the photon energy is sufficient, the remaining energy becomes electron kinetic energy. If it is insufficient, increasing the number of identical low-energy photons does not release an electron in this model.

At a frequency above threshold, increasing intensity increases the rate at which photons arrive, so more electrons can be emitted per second. It does not increase the energy of each unchanged-frequency photon.

An electron does not gradually accumulate fractions of energy from many below-threshold photons in the photoelectric model required here; absorption transfers one photon's energy in one interaction.

Work function sets the photoelectric threshold

The work function ϕ\phi is the minimum energy needed to release an electron from a metal surface. The threshold frequency f0f_0 is the minimum radiation frequency that can cause emission, so ϕ=hf0\phi=hf_0.

Energy conservation for the most energetic emitted electrons is hf=ϕ+12mvmax2hf=\phi+\tfrac12mv_{max}^2. Photon energy pays the work function first; any remainder becomes maximum kinetic energy.

If hf=5.0×1019Jhf=5.0\times10^{-19}\,\mathrm{J} and ϕ=3.2×1019J\phi=3.2\times10^{-19}\,\mathrm{J}, then Ek,max=1.8×1019JE_{k,max}=1.8\times10^{-19}\,\mathrm{J}.

Below f0f_0, no emission occurs however intense the radiation. Above threshold, increasing frequency increases maximum kinetic energy; increasing intensity mainly increases the emission rate.

The electronvolt is a convenient small energy unit

One electronvolt is the energy transferred when a particle with elementary charge moves through a potential difference of one volt: 1eV=1.60×1019J1\,\mathrm{eV}=1.60\times10^{-19}\,\mathrm{J}.

Conversion Operation
eV to J multiply by 1.60×10191.60\times10^{-19}
J to eV divide by 1.60×10191.60\times10^{-19}

3.2eV=(3.2)(1.60×1019)=5.1×1019J3.2\,\mathrm{eV}=(3.2)(1.60\times10^{-19})=5.1\times10^{-19}\,\mathrm{J}. Conversely, 8.0×1019J=5.0eV8.0\times10^{-19}\,\mathrm{J}=5.0\,\mathrm{eV}.

The electronvolt is a unit of energy, not voltage and not charge. Do not attach a joule conversion factor twice when an equation already uses all energies in eV.

Photoelectric observations require photon-sized energy transfer

Observation Photon-model explanation
emission is effectively immediate one photon transfers its energy in one interaction
each metal has a threshold frequency one photon needs at least work-function energy
maximum electron kinetic energy rises with frequency Ek,max=hfϕE_{k,max}=hf-\phi
above threshold, emission rate rises with intensity more photons arrive per second

These observations support a particle description in which electromagnetic energy arrives in discrete photons. In particular, intense radiation below threshold still fails to emit electrons, whereas a continuous-wave-only energy accumulation picture would not predict this frequency cutoff and immediate response together.

Photoelectric evidence supports particle behaviour during energy transfer; it does not remove the independent wave evidence from interference, diffraction and polarisation.

Discrete energy levels produce line spectra

Electrons in an atom can occupy only discrete energy levels. An electron moving from a higher level EhE_h to a lower level ElE_l emits one photon with hf=EhElhf=E_h-E_l. Absorption occurs when a photon supplies the matching energy difference for an upward transition.

Because only particular level differences exist, only particular photon frequencies and wavelengths are emitted or absorbed. These appear as separate spectral lines rather than a continuous range.

For an energy difference ΔE=3.0×1019J\Delta E=3.0\times10^{-19}\,\mathrm{J}, f=ΔE/h=(3.0×1019)/(6.63×1034)=4.5×1014Hzf=\Delta E/h=(3.0\times10^{-19})/(6.63\times10^{-34})=4.5\times10^{14}\,\mathrm{Hz}. If required, wavelength follows from λ=c/f\lambda=c/f.

Use the magnitude of the energy-level difference for photon energy, then use the transition direction to decide emission or absorption. A spectral line does not represent an electron occupying an energy between allowed levels.