Unit 2: Waves and Electricity

Syllabus
2021
Section
—
Level
AS

2.3 - Waves and Particle Nature of Light

Syllabus
2021
Topic
2.3
Level
AS

Wave quantities describe oscillation and propagation

Quantity Meaning Unit
amplitude AA maximum displacement from equilibrium m, or the unit of the oscillating quantity
period TT time for one complete oscillation s
frequency ff complete oscillations per second; f=1/Tf=1/T Hz
wavelength λ\lambda shortest distance between points in the same phase m
wave speed vv speed at which a phase point or disturbance travels m s−1\mathrm{m\,s^{-1}}

On a displacement graph, amplitude is measured from the equilibrium line to a crest or trough, not from crest to trough. A displacement-time graph at one position gives period; a displacement-distance snapshot at one time gives wavelength.

Wave speed is not the speed of a medium particle. In a mechanical wave, particles oscillate locally while the disturbance and energy propagate through the medium.

One wavelength travels during one period

The wave equation is v=fλv=f\lambda. During one period TT, a wavefront moves one wavelength, so v=λ/T=fλv=\lambda/T=f\lambda because f=1/Tf=1/T. Use speed in m s−1\mathrm{m\,s^{-1}}, frequency in hertz and wavelength in metres.

Identify the wave speed in the relevant medium, convert prefixes such as MHz or nm, and rearrange before substituting. If speed stays constant, increasing frequency shortens wavelength in inverse proportion.

A sound wave of frequency 680 Hz680\,\mathrm{Hz} travels at 340 m s−1340\,\mathrm{m\,s^{-1}}. Its wavelength is λ=v/f=340/680=0.50 m\lambda=v/f=340/680=0.50\,\mathrm{m}.

Frequency is fixed by the source and normally stays unchanged when a wave crosses a boundary; a change in speed therefore changes wavelength, not frequency.

Longitudinal waves create pressure variations

In a longitudinal wave, molecules or particles oscillate parallel to the direction in which the wave travels. Their alternating crowding and separation produce compressions and rarefactions, so pressure varies as the disturbance passes.

Location in a sound wave Molecular pattern Pressure variation
compression molecules closer together than equilibrium pressure above equilibrium
rarefaction molecules farther apart than equilibrium pressure below equilibrium

The wavelength is the distance between neighbouring compressions, neighbouring rarefactions, or any two nearest points in the same phase. A molecule oscillates about its equilibrium position rather than travelling with the wave from source to receiver.

A drawn sine curve for a longitudinal wave is a graph of pressure or displacement; it is not the literal path followed by molecules.

Transverse oscillations are perpendicular to travel

In a transverse wave, the oscillating quantity is perpendicular to the direction of wave propagation. For a wave travelling horizontally along a string, each element of string may move vertically while the disturbance travels horizontally.

A displacement-distance snapshot may show crests and troughs. These mark positive and negative displacement from equilibrium, while wavelength is measured between neighbouring points in the same phase, such as crest to crest.

Transverse waves can be plane polarised because their oscillations have directions perpendicular to travel. This distinguishes them from longitudinal waves, whose oscillations lie along the travel direction.

The material does not travel along the drawn wave shape. Points in the medium oscillate locally as energy is transferred through the wave.

Choose the graph that can reveal the required wave quantity

Graph What it represents Read directly
displacement against time at one position one point's oscillation amplitude and period
displacement against distance at one instant spatial wave profile amplitude and wavelength
pressure against distance longitudinal pressure variation wavelength between equal-phase pressure points
standing-wave amplitude against position fixed amplitude pattern nodes, antinodes and their spacing

Label axes with quantity and unit, use the equilibrium line consistently, and apply any scale factor. Frequency comes from f=1/Tf=1/T after reading a full cycle. For a standing wave, neighbouring nodes or neighbouring antinodes are λ/2\lambda/2 apart.

A longitudinal wave may still be represented by a sinusoidal pressure-distance or displacement-distance graph. The vertical graph coordinate is a measured quantity, not a direction in which the wave itself travels.

A displacement-time graph contains no spatial scale, so wavelength cannot be read directly from it. Likewise, a spatial snapshot alone does not give period.

Core Practical 4: determine the speed of sound in air

Connect a signal generator to a loudspeaker and also to one channel of a 2-beam oscilloscope. Connect a microphone to the second channel. Display stable traces with the same timebase and place the microphone in line with the speaker.

Record the microphone position when the two traces have a clearly defined phase relation, such as in phase. Move the microphone away until that same phase relation next occurs; the displacement is one wavelength. For lower percentage uncertainty, move through several repeats and divide the total displacement by the number of wavelengths.

Read the period from the oscilloscope and calculate f=1/Tf=1/T, or use the calibrated generator frequency. Then calculate v=fλv=f\lambda. Repeat positions and use a best-fit relation where possible; record the air temperature because sound speed depends on conditions.

Moving from in-phase to antiphase corresponds to half a wavelength, not a whole wavelength. Avoid comparing unrelated peaks or using a timebase that cannot display a complete period.

Coherent waves interfere by superposition

Term Precise meaning
wavefront line or surface joining points in the same phase
coherent sources constant phase difference and the same frequency
path difference difference between distances travelled to a point
phase position within an oscillation cycle
superposition resultant displacement is the algebraic sum of individual displacements
interference spatial pattern produced when coherent waves superpose

Waves arriving in phase reinforce to give constructive interference and a larger resultant amplitude. Waves arriving in antiphase oppose and give destructive interference; equal amplitudes can cancel completely.

Interference does not permanently destroy energy. The waves superpose while overlapping, and energy is redistributed across the interference pattern.

Path difference fixes phase difference

A path difference of one wavelength corresponds to one complete phase cycle. Therefore Δϕ=2π(Δx/λ)\Delta\phi=2\pi(\Delta x/\lambda) radians, or Δϕ=360∘(Δx/λ)\Delta\phi=360^\circ(\Delta x/\lambda).

Path difference Phase difference Interference for waves initially in phase
mλm\lambda 2mπ2m\pi constructive
(m+12)λ(m+\tfrac12)\lambda (2m+1)π(2m+1)\pi destructive
λ/4\lambda/4 π/2\pi/2 intermediate

If Δx=3λ/8\Delta x=3\lambda/8, then Δϕ=2π(3/8)=3π/4\Delta\phi=2\pi(3/8)=3\pi/4 radians, or 135∘135^\circ. Equivalent phases may differ by any whole multiple of 2π2\pi.

Path difference is a distance; phase difference is an angle. Do not compare their numerical values until path difference has been divided by wavelength.

Opposing progressive waves form a stationary pattern

A standing or stationary wave forms when two coherent waves of the same frequency travel in opposite directions and superpose, commonly because an incident wave reflects. Their interference fixes a pattern of nodes and antinodes in space.

Position Oscillation amplitude Phase relation
node zero boundary between adjacent phase regions
antinode maximum all points between one pair of nodes oscillate in phase

Neighbouring nodes are λ/2\lambda/2 apart, as are neighbouring antinodes; a node and its nearest antinode are λ/4\lambda/4 apart. There is no net energy transfer along an ideal stationary wave, although energy moves locally between stores.

The drawn envelope is not a wave profile travelling sideways. Nodes remain fixed, while points away from nodes oscillate with position-dependent amplitude.

String-wave speed increases with tension and falls with linear density

For a transverse wave on a stretched string, v=T/μv=\sqrt{T/\mu}, where TT is tension in newtons and μ\mu is mass per unit length in kg m−1\mathrm{kg\,m^{-1}}. Linear density can be measured from μ=m/L\mu=m/L.

At fixed μ\mu, multiplying tension by four doubles speed. At fixed tension, multiplying μ\mu by four halves speed. The square-root dependence means speed is not directly proportional to either quantity.

For T=90 NT=90\,\mathrm{N} and μ=2.5×10−3 kg m−1\mu=2.5\times10^{-3}\,\mathrm{kg\,m^{-1}}, v=90/(2.5×10−3)=190 m s−1v=\sqrt{90/(2.5\times10^{-3})}=190\,\mathrm{m\,s^{-1}} to two significant figures.

Use tension, not automatically the hanging weight if another arrangement changes the force in the vibrating section. Linear density is mass per length, not total mass.

Core Practical 5: test what controls string frequency

Drive a stretched string with a vibration generator and signal generator. Adjust frequency until a clear stationary-wave pattern with a fixed number of loops appears. Measure vibrating length LL, obtain tension from a hanging load where T=mgT=mg, and determine μ\mu from the mass and length of a sample.

Variable changed Keep constant Linear test for the same mode
length LL T,μT,\mu ff against 1/L1/L
tension TT L,μL,\mu f2f^2 against TT
linear density μ\mu L,TL,T f2f^2 against 1/μ1/\mu

For the fundamental, λ=2L\lambda=2L and f=(1/2L)T/μf=(1/2L)\sqrt{T/\mu}. Change one variable at a time, retune to the same mode, repeat readings and use a best-fit line to judge the predicted relationship.

Comparisons are invalid if the number of loops changes between readings, because that changes wavelength as well as the chosen variable. Frequency does not depend on oscillation amplitude in this model.

Intensity is power distributed over area

Radiation intensity is power incident per unit area perpendicular to propagation: I=P/AI=P/A. Its SI unit is W m−2\mathrm{W\,m^{-2}}. Rearranging gives P=IAP=IA and, over time tt, transferred energy E=IAtE=IAt.

Radiation of intensity 250 W m−2250\,\mathrm{W\,m^{-2}} falls normally on a 0.40 m20.40\,\mathrm{m^2} surface. The incident power is P=(250)(0.40)=100 WP=(250)(0.40)=100\,\mathrm{W}, so 300 J300\,\mathrm{J} arrives in 3.0 s3.0\,\mathrm{s}.

If a source radiates power uniformly in all directions, the relevant area at radius rr is 4πr24\pi r^2, so I=P/(4πr2)I=P/(4\pi r^2). This inverse-square result follows from the growing spherical area.

Intensity is not total power: the same power gives lower intensity when spread over a larger area. Use the area facing the radiation, not an unrelated surface area.

Refraction follows wave speed at a boundary

Refractive index is n=c/vn=c/v, where cc is light speed in vacuum and vv is light speed in the medium. A larger nn means lower wave speed.

At an interface, n1sin⁡θ1=n2sin⁡θ2n_1\sin\theta_1=n_2\sin\theta_2. Measure both angles from the normal. Light entering a higher-index medium bends toward the normal; entering a lower-index medium bends away.

Light travels from air (n1=1.00)(n_1=1.00) into glass (n2=1.50)(n_2=1.50) at 30∘30^\circ. Then sin⁡θ2=(1.00/1.50)sin⁡30∘=0.333\sin\theta_2=(1.00/1.50)\sin30^\circ=0.333, so θ2=19.5∘\theta_2=19.5^\circ.

Frequency remains fixed at the boundary. Speed and wavelength change together, so bending is not caused by a frequency change. Angles drawn to the surface must be converted to angles to the normal.

At the critical angle, the refracted ray follows the boundary

The critical angle CC is the incidence angle in the higher-index medium for which the refraction angle in the lower-index medium is 90∘90^\circ. For a material of refractive index nn meeting air, sin⁡C=1/n\sin C=1/n.

Confirm that the ray travels from higher nn to lower nn, calculate 1/n1/n, then use the inverse sine in degree mode. For n=1.52n=1.52, C=sin⁡−1(1/1.52)=41.1∘C=\sin^{-1}(1/1.52)=41.1^\circ.

For two non-air media, Snell's law gives sin⁡C=nlower/nhigher\sin C=n_{lower}/n_{higher}. The ratio must not exceed 1, consistent with the higher-to-lower condition.

At i=Ci=C, the ray is refracted along the interface; total internal reflection requires i>Ci>C. A critical angle is not defined for incidence from lower index to higher index.

Total internal reflection needs two conditions

Check Requirement for total internal reflection
direction wave travels from higher refractive index to lower refractive index
incidence angle i>Ci>C in the higher-index medium

If both conditions hold, no refracted ray propagates into the second medium and the wave reflects internally. At i=Ci=C, the refracted ray travels along the boundary. At i<Ci<C, some wave is transmitted by refraction and some may be reflected.

Identify the two media, locate the normal, calculate or read CC, and compare the incidence angle measured from the normal. State both the comparison and the resulting path.

A large incidence angle alone is insufficient. Total internal reflection cannot occur when light approaches a higher-index medium from a lower-index medium.

Measure refractive index from several angle pairs

Place a transparent block on paper and trace its outline. Direct a narrow monochromatic ray at one face. Mark the incident and transmitted paths, remove the block, join the marks, and draw the normal at the entry point. Measure incidence ii and refraction rr from the normal with a protractor.

Repeat for several incidence angles. For air entering the solid, calculate n=sin⁡i/sin⁡rn=\sin i/\sin r, or plot sin⁡i\sin i vertically against sin⁡r\sin r horizontally; the best-fit gradient is nn when nair≈1n_{air}\approx1.

Use a thin ray, widely separated path marks and angles neither extremely small nor near grazing incidence. Repeat measurements and use monochromatic light so different wavelengths do not refract by different amounts.

Do not measure angles from the block face. Measuring from the normal is essential, and one angle pair provides weaker evidence than the gradient of repeated data.

Plane polarisation restricts transverse oscillations

Unpolarised transverse radiation has oscillations in many directions perpendicular to travel. Plane-polarised radiation has oscillations restricted to one plane containing the direction of propagation.

A polarising filter transmits the component aligned with its transmission axis. A second filter acts as an analyser: aligned axes give strong transmission, while perpendicular axes ideally give no transmission. An intermediate angle transmits an intermediate intensity.

Polarisation is possible only when oscillations have a direction perpendicular to propagation. Its observation therefore supports the transverse nature of electromagnetic waves.

Polarisation does not mean the wave travels in one plane; it means the oscillation direction is confined. Longitudinal waves cannot be plane polarised in this way.

Huygens' wavelets explain diffraction

Diffraction is the spreading of waves after passing through a gap or around an obstacle. It is most noticeable when the gap or obstacle size is comparable with the wavelength.

In Huygens' construction, every point on an existing wavefront acts as a source of secondary wavelets. After a short time, the new wavefront is the envelope tangent to those wavelets.

Most wavelets are blocked at a barrier, but wavelets from points across a slit spread into the region beyond it. Their envelope is curved, predicting diffracted wavefronts. At an obstacle edge, unblocked wavelets extend into the geometric shadow.

Diffraction is not refraction: it does not require a change of medium or speed. A very wide gap compared with wavelength produces much less angular spreading.

A diffraction grating links order, spacing and angle

For normal incidence on a diffraction grating, principal maxima satisfy nλ=dsin⁡θn\lambda=d\sin\theta. Here n=0,1,2,…n=0,1,2,\ldots is order, dd is slit spacing and θ\theta is measured from the central normal.

Convert line density to spacing: if a grating has NN lines per metre, d=1/Nd=1/N. For lines per millimetre, first multiply by 10001000 to obtain lines per metre.

Identify the order, convert λ\lambda and dd to metres, solve for sin⁡θ=nλ/d\sin\theta=n\lambda/d, then use inverse sine. A possible order must satisfy nλ≤dn\lambda\le d because sin⁡θ≤1\sin\theta\le1.

The symbol nn here is diffraction order, not refractive index. Measure θ\theta from the central straight-through direction, and do not use small-angle approximations unless justified.

Core Practical 6: determine wavelength with a grating

Mount a diffraction grating of known line density perpendicular to a narrow light beam. Place a screen a measured perpendicular distance DD away. For a laser, keep the beam below eye level, secure it, never view the beam directly and remove reflective objects.

Mark the central maximum and matching order +n+n and −n-n maxima. Measure their separation and halve it to obtain xx, reducing centre-location error. Calculate θ\theta from tan⁡θ=x/D\tan\theta=x/D.

Convert line density to dd, then calculate λ=dsin⁡θ/n\lambda=d\sin\theta/n. Repeat with several orders or distances and average consistent values. A graph of sin⁡θ\sin\theta against nn has gradient λ/d\lambda/d, providing a stronger multi-point result.

Screen displacement xx is not the grating angle. Use the right triangle to obtain θ\theta, keep order numbers correct, and do not replace sin⁡θ\sin\theta by x/Dx/D unless the small-angle assumption is explicitly valid.

Electron diffraction reveals matter-wave behaviour

A beam of electrons passing through a thin crystalline target produces a diffraction pattern, such as concentric rings. The regular atomic spacing acts like a diffraction grating.

Diffraction is a wave phenomenon, so the pattern is evidence that electrons have wave behaviour. It occurs when the electron de Broglie wavelength is comparable with the spacing of atomic planes, allowing waves associated with different paths to interfere.

Changing electron momentum changes the de Broglie wavelength and therefore changes the diffraction geometry. The systematic pattern change links the effect to wavelength rather than to random particle scattering.

The experiment does not show electrons are ordinary classical waves or cease to behave as particles. It shows that a complete model must include wave behaviour for electrons.

Every moving particle has a de Broglie wavelength

The de Broglie relationship is λ=h/p\lambda=h/p, where h=6.63×10−34 J sh=6.63\times10^{-34}\,\mathrm{J\,s} and pp is momentum in kg m s−1\mathrm{kg\,m\,s^{-1}}. For a non-relativistic particle, p=mvp=mv.

Calculate momentum first, then divide hh by it. A larger momentum gives a shorter wavelength, so diffraction becomes harder to observe for everyday macroscopic objects.

An electron with momentum 2.0×10−23 kg m s−12.0\times10^{-23}\,\mathrm{kg\,m\,s^{-1}} has λ=(6.63×10−34)/(2.0×10−23)=3.3×10−11 m\lambda=(6.63\times10^{-34})/(2.0\times10^{-23})=3.3\times10^{-11}\,\mathrm{m}.

Momentum magnitude belongs in the wavelength calculation; direction is not represented by a negative wavelength. The relation applies to material particles, not only electrons.

A boundary can reflect and transmit the same incident wave

When a wave reaches an interface between media, part of its energy may return as a reflected wave and part may enter the second medium as a transmitted wave. The proportions depend on the media and boundary conditions.

Quantity Reflected wave in original medium Transmitted wave in new medium
frequency unchanged unchanged
speed same as incident medium set by new medium
wavelength consistent with original speed changes so v=fλv=f\lambda remains true

For a straight boundary, reflection obeys equal incidence and reflection angles measured from the normal. Transmission may involve refraction when the wave speed changes.

Partial reflection does not mean the rest of the wave disappears. Track reflected and transmitted energy; amplitude is not itself an energy fraction.

Pulse-echo timing locates a reflecting boundary

A transducer sends a short pulse and detects its echo from an interface or object. If wave speed is vv and the delay from emission to echo is tt, the one-way distance is d=vt/2d=vt/2 because the pulse travels out and back.

An ultrasound echo returns after 40 μs40\,\mu\mathrm{s} in material where v=4000 m s−1v=4000\,\mathrm{m\,s^{-1}}. Then d=(4000)(40×10−6)/2=0.080 md=(4000)(40\times10^{-6})/2=0.080\,\mathrm{m}.

Limitation Why information is lost Improvement
wavelength too large nearby or small features cannot be distinguished spatially use shorter wavelength where suitable
pulse duration too long echoes from nearby boundaries overlap; pulse length is vΔtv\Delta t use shorter pulses

Never use vtvt as the object depth for a returned echo unless tt is explicitly a one-way time. Detection also requires the echo to arrive after the transmitted pulse has ended.

Wave and photon models answer different evidence

Model Behaviour it explains directly Core representation
wave model interference, diffraction, polarisation and propagation continuous wavefronts, phase and superposition
photon model discrete light-matter energy transfer and photoelectric emission packets with energy E=hfE=hf

The wave model grew from evidence for interference and diffraction, but a wave-only account could not explain all observations of energy exchange with matter. The photon model was developed to represent those exchanges as discrete interactions. Later evidence therefore extended the available modelling rather than simply erasing the successful wave description.

Choose the model that exposes the behaviour under study. Electromagnetic radiation can display wave behaviour during propagation and interference while exchanging energy with matter in photon-sized amounts.

A model is not a literal picture of everything radiation 'really is'. Neither model alone accounts most clearly for every observation, so evidence determines which representation is useful.

Photon energy is proportional to frequency

The energy of one photon is E=hfE=hf, where h=6.63×10−34 J sh=6.63\times10^{-34}\,\mathrm{J\,s} and ff is frequency in hertz. Since f=c/λf=c/\lambda in vacuum, shorter-wavelength radiation has greater photon energy.

For f=6.0×1014 Hzf=6.0\times10^{14}\,\mathrm{Hz}, E=(6.63×10−34)(6.0×1014)=4.0×10−19 JE=(6.63\times10^{-34})(6.0\times10^{14})=4.0\times10^{-19}\,\mathrm{J} per photon to two significant figures.

Photon energy and beam intensity are different. At fixed frequency, greater intensity means more photon energy arriving per unit area per unit time, usually through a greater photon rate, not more energy per photon.

Use the frequency of the radiation, not its amplitude, to calculate the energy of one photon. Convert wavelength to frequency before using E=hfE=hf.

One absorbed photon transfers energy to one electron

In the photoelectric effect, one photon is absorbed in a one-to-one interaction with one electron. The photon transfers its energy hfhf as a single amount.

Part of that energy may be required to release the electron from the metal surface. If the photon energy is sufficient, the remaining energy becomes electron kinetic energy. If it is insufficient, increasing the number of identical low-energy photons does not release an electron in this model.

At a frequency above threshold, increasing intensity increases the rate at which photons arrive, so more electrons can be emitted per second. It does not increase the energy of each unchanged-frequency photon.

An electron does not gradually accumulate fractions of energy from many below-threshold photons in the photoelectric model required here; absorption transfers one photon's energy in one interaction.

Work function sets the photoelectric threshold

The work function ϕ\phi is the minimum energy needed to release an electron from a metal surface. The threshold frequency f0f_0 is the minimum radiation frequency that can cause emission, so ϕ=hf0\phi=hf_0.

Energy conservation for the most energetic emitted electrons is hf=ϕ+12mvmax2hf=\phi+\tfrac12mv_{max}^2. Photon energy pays the work function first; any remainder becomes maximum kinetic energy.

If hf=5.0×10−19 Jhf=5.0\times10^{-19}\,\mathrm{J} and ϕ=3.2×10−19 J\phi=3.2\times10^{-19}\,\mathrm{J}, then Ek,max=1.8×10−19 JE_{k,max}=1.8\times10^{-19}\,\mathrm{J}.

Below f0f_0, no emission occurs however intense the radiation. Above threshold, increasing frequency increases maximum kinetic energy; increasing intensity mainly increases the emission rate.

The electronvolt is a convenient small energy unit

One electronvolt is the energy transferred when a particle with elementary charge moves through a potential difference of one volt: 1 eV=1.60×10−19 J1\,\mathrm{eV}=1.60\times10^{-19}\,\mathrm{J}.

Conversion Operation
eV to J multiply by 1.60×10−191.60\times10^{-19}
J to eV divide by 1.60×10−191.60\times10^{-19}

3.2 eV=(3.2)(1.60×10−19)=5.1×10−19 J3.2\,\mathrm{eV}=(3.2)(1.60\times10^{-19})=5.1\times10^{-19}\,\mathrm{J}. Conversely, 8.0×10−19 J=5.0 eV8.0\times10^{-19}\,\mathrm{J}=5.0\,\mathrm{eV}.

The electronvolt is a unit of energy, not voltage and not charge. Do not attach a joule conversion factor twice when an equation already uses all energies in eV.

Photoelectric observations require photon-sized energy transfer

Observation Photon-model explanation
emission is effectively immediate one photon transfers its energy in one interaction
each metal has a threshold frequency one photon needs at least work-function energy
maximum electron kinetic energy rises with frequency Ek,max=hf−ϕE_{k,max}=hf-\phi
above threshold, emission rate rises with intensity more photons arrive per second

These observations support a particle description in which electromagnetic energy arrives in discrete photons. In particular, intense radiation below threshold still fails to emit electrons, whereas a continuous-wave-only energy accumulation picture would not predict this frequency cutoff and immediate response together.

Photoelectric evidence supports particle behaviour during energy transfer; it does not remove the independent wave evidence from interference, diffraction and polarisation.

Discrete energy levels produce line spectra

Electrons in an atom can occupy only discrete energy levels. An electron moving from a higher level EhE_h to a lower level ElE_l emits one photon with hf=Eh−Elhf=E_h-E_l. Absorption occurs when a photon supplies the matching energy difference for an upward transition.

Because only particular level differences exist, only particular photon frequencies and wavelengths are emitted or absorbed. These appear as separate spectral lines rather than a continuous range.

For an energy difference ΔE=3.0×10−19 J\Delta E=3.0\times10^{-19}\,\mathrm{J}, f=ΔE/h=(3.0×10−19)/(6.63×10−34)=4.5×1014 Hzf=\Delta E/h=(3.0\times10^{-19})/(6.63\times10^{-34})=4.5\times10^{14}\,\mathrm{Hz}. If required, wavelength follows from λ=c/f\lambda=c/f.

Use the magnitude of the energy-level difference for photon energy, then use the transition direction to decide emission or absorption. A spectral line does not represent an electron occupying an energy between allowed levels.

2.4 - Electric Circuits

Syllabus
2021
Topic
2.4
Level
AS

Current measures charge flow rate

Electric current is the rate at which charge passes a point: I=ΔQ/ΔtI=\Delta Q/\Delta t. One ampere is one coulomb per second. Rearranging gives ΔQ=IΔt\Delta Q=I\Delta t.

Current can be carried by different charged particles. In a metal the mobile carriers are electrons, but conventional current is defined in the direction positive charge would move, opposite to electron drift.

A steady current of 0.40 A0.40\,\mathrm{A} flows for 3.0 min=180 s3.0\,\mathrm{min}=180\,\mathrm{s}. The charge transferred is Q=(0.40)(180)=72 CQ=(0.40)(180)=72\,\mathrm{C}. The number of electrons is Q/e=4.5×1020Q/e=4.5\times10^{20}.

Current is not charge stored in a component; it is a rate of charge flow. Convert time to seconds and use the magnitude of carrier charge when counting particles.

Potential difference is energy transferred per charge

The potential difference between two points is the energy transferred per unit charge moving between them: V=W/QV=W/Q. One volt is one joule per coulomb. Rearrangements are W=VQW=VQ and Q=W/VQ=W/V.

Across a component, electrical energy is transferred to other stores. A larger p.d. means more energy is transferred for each coulomb, not necessarily that more charge flows; current also depends on the circuit resistance.

Moving 2.5 C2.5\,\mathrm{C} through a p.d. of 12 V12\,\mathrm{V} transfers W=(12)(2.5)=30 JW=(12)(2.5)=30\,\mathrm{J}. An electron accelerated through 108 V108\,\mathrm{V} gains energy of magnitude eVeV.

Potential difference is measured between two points and is not the same as electric current. The equation uses charge in coulombs, not a number of electrons unless that number has been multiplied by ee.

Ohm's law is a constant-temperature special case

Resistance at an operating point is defined by R=V/IR=V/I and measured in ohms. It compares the p.d. across a component with the current through it.

Ohm's law states that I∝VI\propto V for a conductor at constant temperature. The ratio V/IV/I is then constant, so an II-against-VV graph is a straight line through the origin.

If V=6.0 VV=6.0\,\mathrm{V} produces I=0.25 AI=0.25\,\mathrm{A}, then R=6.0/0.25=24 ΩR=6.0/0.25=24\,\Omega. Doubling VV doubles II only if conditions, especially temperature, keep RR constant.

The definition R=V/IR=V/I can be applied to a non-ohmic component at a chosen point. It does not make that component ohmic; Ohm's law additionally requires direct proportionality at constant temperature.

Circuit distributions follow charge and energy conservation

Circuit location Conservation statement Consequence
unbranched series path charge cannot accumulate in steady state current is the same through every component
junction charge entering per second equals charge leaving per second ∑Iin=∑Iout\sum I_{in}=\sum I_{out}
complete loop energy gained per charge equals energy transferred per charge source e.m.f. equals the sum of p.d.s around the loop
parallel branches each branch connects the same two nodes each branch has the same p.d.

Current division is a charge-flow statement; p.d. division is an energy-per-charge statement. A larger series resistance receives a larger share of p.d. because the same current flows and V=IRV=IR.

Current is not 'used up' by a component. Charge continues around the circuit while energy is transferred; it is p.d., not current, that records energy transferred per coulomb.

Equivalent-resistance formulas come from conservation

In series, current II is common and p.d.s add. Using VT=V1+V2+⋯V_T=V_1+V_2+\cdots and V=IRV=IR gives IRT=IR1+IR2+⋯IR_T=IR_1+IR_2+\cdots, so RT=R1+R2+⋯R_T=R_1+R_2+\cdots.

In parallel, p.d. VV is common and branch currents add. Using IT=I1+I2+⋯I_T=I_1+I_2+\cdots and I=V/RI=V/R gives V/RT=V/R1+V/R2+⋯V/R_T=V/R_1+V/R_2+\cdots, so 1/RT=1/R1+1/R2+⋯1/R_T=1/R_1+1/R_2+\cdots.

Two resistors 6.0 Ω6.0\,\Omega and 3.0 Ω3.0\,\Omega give 9.0 Ω9.0\,\Omega in series but 2.0 Ω2.0\,\Omega in parallel. A parallel equivalent must be smaller than the smallest branch resistance because it provides more paths for charge.

Do not apply a memorised formula before identifying which components truly share one path or the same pair of nodes. Adding a parallel branch reduces, rather than increases, that section's equivalent resistance.

Electrical power is the rate of energy transfer

Relationship Best used when
P=VIP=VI p.d. and current are known
W=VIt=PtW=VIt=Pt energy over a time interval is required
P=I2RP=I^2R current and resistance are known
P=V2/RP=V^2/R p.d. and resistance are known

Substituting V=IRV=IR into P=VIP=VI gives P=I2RP=I^2R. Substituting I=V/RI=V/R gives P=V2/RP=V^2/R. The choice matters when comparing circuits: at fixed current, power rises with RR; at fixed p.d., power falls with RR.

A 12 Ω12\,\Omega resistor carries 0.50 A0.50\,\mathrm{A}. It dissipates P=(0.50)2(12)=3.0 WP=(0.50)^2(12)=3.0\,\mathrm{W} and transfers W=(3.0)(40)=120 JW=(3.0)(40)=120\,\mathrm{J} in 40 s40\,\mathrm{s}.

Do not use P=I2RP=I^2R to claim power always increases with resistance without stating what is held constant. In a fixed-voltage circuit, current changes as resistance changes.

I-V graph shape reveals changing resistance

Component II against VV graph Physical interpretation
ohmic conductor at constant temperature straight through origin, symmetric constant V/IV/I
filament bulb symmetric curve becomes less steep as ∣V∣|V| rises heating increases resistance
NTC thermistor symmetric curve becomes steeper as ∣V∣|V| rises self-heating decreases resistance
diode almost no current in reverse or at small forward p.d.; rapid forward rise after threshold region strongly direction-dependent resistance

At any point, resistance is V/IV/I, not simply the gradient of an II-against-VV curve. A steeper ray from the origin corresponds to larger I/VI/V and therefore smaller resistance.

To obtain a graph, place an ammeter in series and a voltmeter across the component, vary p.d. safely, and reverse polarity when negative values are required. Include a current-limiting resistor for a diode.

A curved graph does not mean the definition of resistance has failed; it means V/IV/I changes with operating point. Never infer diode resistance is exactly infinite from a graph showing current too small to resolve.

Resistivity separates material from conductor geometry

For a uniform conductor, R=ρl/AR=\rho l/A, where ll is length, AA is cross-sectional area and ρ\rho is resistivity in Ω m\Omega\,\mathrm{m}. Rearranging gives ρ=RA/l\rho=RA/l.

For the same material and temperature, resistance is directly proportional to length and inversely proportional to area. Doubling length doubles RR; doubling diameter makes area four times larger and reduces RR to one quarter.

A wire has R=3.0 ΩR=3.0\,\Omega, l=2.0 ml=2.0\,\mathrm{m} and A=1.5×10−6 m2A=1.5\times10^{-6}\,\mathrm{m^2}. Then ρ=(3.0)(1.5×10−6)/2.0=2.3×10−6 Ω m\rho=(3.0)(1.5\times10^{-6})/2.0=2.3\times10^{-6}\,\Omega\,\mathrm{m}.

Resistance describes a particular sample; resistivity describes its material under stated conditions. Use cross-sectional area perpendicular to current and convert diameter before calculating A=πd2/4A=\pi d^2/4.

Core Practical 7: determine electrical resistivity

Measure wire diameter with a micrometer at several positions and orientations, correct any zero error, average it and calculate A=πd2/4A=\pi d^2/4. Measure the test length ll between electrical contacts with a metre rule.

Connect the test wire and ammeter in series with a d.c. supply, switch and variable resistor; connect a voltmeter across the measured length. Use a low current and close the switch only for readings so heating does not change resistivity.

For several lengths, record VV and II and calculate R=V/IR=V/I. Plot RR vertically against ll horizontally. From R=(ρ/A)lR=(\rho/A)l, best-fit gradient m=ρ/Am=\rho/A, so ρ=mA\rho=mA. A single-length result may instead use ρ=RA/l\rho=RA/l, but repeated lengths give a stronger test.

Measure voltage across exactly the length used for ll, and control temperature. Diameter uncertainty is amplified because area depends on d2d^2.

Charge-carrier density helps explain resistivity range

The current carried through cross-sectional area AA is I=nqvAI=nqvA. Here nn is mobile charge-carrier number density, qq is charge per carrier and vv is mean drift speed.

For a given area, current is larger when more mobile carriers are available or when their drift response is greater. Metals have a large density of conduction electrons and therefore conduct readily. Insulators have extremely few mobile carriers, producing tiny current for an applied field; semiconductors can change carrier number strongly with temperature or illumination.

If two wires carry the same current with the same nn and qq, but one has four times the area, its drift speed is one quarter as large. Conversely, simultaneous fourfold increases in II and AA leave vv unchanged.

Number density counts mobile carriers per cubic metre, not all particles in the material. The large resistivity range cannot be explained by geometry, because resistivity is a material property.

Potential falls linearly along a uniform current-carrying wire

A uniform wire has constant resistivity and cross-sectional area, so resistance from one end to distance xx is Rx=ρx/AR_x=\rho x/A. In steady current II, the p.d. across that length is Vx=IRxV_x=IR_x, hence Vx∝xV_x\propto x.

A graph of potential against distance is a straight line for a uniform wire carrying constant current. Its sign of gradient depends on the chosen direction and reference potential; its magnitude is the potential gradient.

If a wire drops 6.0 V6.0\,\mathrm{V} uniformly over 1.5 m1.5\,\mathrm{m}, the drop is 4.0 V m−14.0\,\mathrm{V\,m^{-1}}. A point 0.40 m0.40\,\mathrm{m} from the high-potential end is 1.6 V1.6\,\mathrm{V} below that end.

Linear variation requires a uniform wire and steady current. A change in material, area or temperature changes resistance per unit length and therefore changes the graph gradient.

A potential divider shares input p.d. in the resistance ratio

Two resistors R1R_1 and R2R_2 in series carry the same current I=Vin/(R1+R2)I=V_{in}/(R_1+R_2). The output across R2R_2 is therefore Vout=IR2=VinR2/(R1+R2)V_{out}=IR_2=V_{in}R_2/(R_1+R_2).

Output measured across Output fraction
R1R_1 R1/(R1+R2)R_1/(R_1+R_2)
R2R_2 R2/(R1+R2)R_2/(R_1+R_2)

With Vin=12 VV_{in}=12\,\mathrm{V}, R1=2.0 kΩR_1=2.0\,\mathrm{k\Omega} and R2=4.0 kΩR_2=4.0\,\mathrm{k\Omega}, the output across R2R_2 is 12(4.0/6.0)=8.0 V12(4.0/6.0)=8.0\,\mathrm{V}.

The larger series resistance has the larger p.d., because current is common. The simple ratio assumes the output is not significantly loaded by another component drawing current.

Sensor position decides how a divider output changes

For an unloaded divider, the output across a component is Vout=VinRout/RtotalV_{out}=V_{in}R_{out}/R_{total}. First mark exactly which resistor the output spans; then change the sensor resistance and recompute the ratio.

Sensor Environmental increase Sensor resistance Output across sensor Output across fixed resistor
NTC thermistor temperature rises decreases decreases increases
LDR illumination rises decreases decreases increases

A control circuit switches when VoutV_{out} crosses a threshold. To predict its response, find sensor resistance at the stated condition, calculate output, then determine how the output moves on either side of that condition.

Saying 'thermistor resistance falls, so output falls' is incomplete until the output location is known. The same resistance change produces the opposite output trend across the other series component.

E.m.f. includes energy lost inside a source

Quantity Energy-per-charge meaning
e.m.f. ε\varepsilon energy supplied by the source per coulomb
terminal p.d. VV energy delivered to the external circuit per coulomb
internal loss IrIr energy per coulomb transferred inside a source of internal resistance rr

When a cell supplies current, energy conservation gives ε=V+Ir\varepsilon=V+Ir, so V=ε−IrV=\varepsilon-Ir. Increasing current increases the lost volts and lowers terminal p.d. if ε\varepsilon and rr remain constant.

With negligible current, Ir≈0Ir\approx0 and terminal p.d. is approximately the e.m.f. Under load, the source behaves like an ideal e.m.f. in series with its internal resistance.

E.m.f. is measured in volts but is not a force. Terminal p.d. equals e.m.f. only when internal loss is negligible, not for every operating current.

Core Practical 8: determine e.m.f. and internal resistance

Connect the cell, ammeter, switch and variable resistor in series. Connect a voltmeter directly across the cell terminals. Use high-resistance voltmeter and vary the external resistance to obtain a safe range of current values.

For each setting, close the switch briefly, record current II and terminal p.d. VV, then open it to reduce heating and cell discharge. Repeat readings and do not include a zero-resistance short circuit.

From V=ε−IrV=\varepsilon-Ir, plot VV vertically against II horizontally. Draw a best-fit line: the vertical intercept is ε\varepsilon, and the negative gradient is −r-r, so internal resistance is the positive magnitude of the gradient.

Use a large gradient triangle, include V A−1=Ω\mathrm{V\,A^{-1}}=\Omega, and inspect scatter or curvature before accepting a constant-rr model. The intercept is extrapolated, so a well-spread data range improves it.

Do not identify internal resistance with the graph intercept or report a negative resistance from the negative slope. The intercept is e.m.f.; rr is the magnitude of gradient.

Temperature changes resistance by two competing mechanisms

Material Effect of higher temperature Dominant model Resistance change
metal lattice ions vibrate more conduction electrons collide more often; carrier number is roughly unchanged increases
NTC thermistor more electrons gain enough energy to become conduction carriers carrier number rises strongly despite increased vibration decreases

For the same applied p.d., a metal's rising resistance reduces current. In an NTC thermistor, higher temperature increases conduction-electron number, lowering resistance and increasing current.

In a potential divider, translate this resistance change only after identifying the output position. As an NTC thermistor warms, p.d. across it falls if it is the output resistor, while p.d. across the fixed series resistor rises.

Higher temperature does not make every material more resistive. Both lattice scattering and carrier number matter; different materials are dominated by different changes.

Illumination increases carriers and lowers LDR resistance

When illumination increases, more light energy arrives at an LDR and more electrons become available as conduction carriers. The increased carrier number allows a larger current for the same p.d., so the LDR's resistance decreases.

In lower illumination, fewer conduction electrons are available and resistance is higher. This carrier-number model connects the environmental input to the electrical response rather than treating the LDR as a switch with only two states.

In a fixed-voltage series circuit, lower LDR resistance lowers total resistance and raises current. In a potential divider, output across the LDR falls with illumination, while output across the fixed resistor rises.

Greater illumination does not directly increase the energy of each conduction electron in the circuit. Its key effect in this model is to increase the number of available charge carriers.