2.3 - Waves and Particle Nature of Light
- Syllabus
- 2021
- Topic
- 2.3
- Level
- AS
| Quantity | Meaning | Unit |
|---|---|---|
| amplitude A | maximum displacement from equilibrium | m, or the unit of the oscillating quantity |
| period T | time for one complete oscillation | s |
| frequency f | complete oscillations per second; f=1/T | Hz |
| wavelength λ | shortest distance between points in the same phase | m |
| wave speed v | speed at which a phase point or disturbance travels | ms−1 |
On a displacement graph, amplitude is measured from the equilibrium line to a crest or trough, not from crest to trough. A displacement-time graph at one position gives period; a displacement-distance snapshot at one time gives wavelength.
Wave speed is not the speed of a medium particle. In a mechanical wave, particles oscillate locally while the disturbance and energy propagate through the medium.
The wave equation is v=fλ. During one period T, a wavefront moves one wavelength, so v=λ/T=fλ because f=1/T. Use speed in ms−1, frequency in hertz and wavelength in metres.
Identify the wave speed in the relevant medium, convert prefixes such as MHz or nm, and rearrange before substituting. If speed stays constant, increasing frequency shortens wavelength in inverse proportion.
A sound wave of frequency 680Hz travels at 340ms−1. Its wavelength is λ=v/f=340/680=0.50m.
Frequency is fixed by the source and normally stays unchanged when a wave crosses a boundary; a change in speed therefore changes wavelength, not frequency.
In a longitudinal wave, molecules or particles oscillate parallel to the direction in which the wave travels. Their alternating crowding and separation produce compressions and rarefactions, so pressure varies as the disturbance passes.
| Location in a sound wave | Molecular pattern | Pressure variation |
|---|---|---|
| compression | molecules closer together than equilibrium | pressure above equilibrium |
| rarefaction | molecules farther apart than equilibrium | pressure below equilibrium |
The wavelength is the distance between neighbouring compressions, neighbouring rarefactions, or any two nearest points in the same phase. A molecule oscillates about its equilibrium position rather than travelling with the wave from source to receiver.
A drawn sine curve for a longitudinal wave is a graph of pressure or displacement; it is not the literal path followed by molecules.
In a transverse wave, the oscillating quantity is perpendicular to the direction of wave propagation. For a wave travelling horizontally along a string, each element of string may move vertically while the disturbance travels horizontally.
A displacement-distance snapshot may show crests and troughs. These mark positive and negative displacement from equilibrium, while wavelength is measured between neighbouring points in the same phase, such as crest to crest.
Transverse waves can be plane polarised because their oscillations have directions perpendicular to travel. This distinguishes them from longitudinal waves, whose oscillations lie along the travel direction.
The material does not travel along the drawn wave shape. Points in the medium oscillate locally as energy is transferred through the wave.
| Graph | What it represents | Read directly |
|---|---|---|
| displacement against time at one position | one point's oscillation | amplitude and period |
| displacement against distance at one instant | spatial wave profile | amplitude and wavelength |
| pressure against distance | longitudinal pressure variation | wavelength between equal-phase pressure points |
| standing-wave amplitude against position | fixed amplitude pattern | nodes, antinodes and their spacing |
Label axes with quantity and unit, use the equilibrium line consistently, and apply any scale factor. Frequency comes from f=1/T after reading a full cycle. For a standing wave, neighbouring nodes or neighbouring antinodes are λ/2 apart.
A longitudinal wave may still be represented by a sinusoidal pressure-distance or displacement-distance graph. The vertical graph coordinate is a measured quantity, not a direction in which the wave itself travels.
A displacement-time graph contains no spatial scale, so wavelength cannot be read directly from it. Likewise, a spatial snapshot alone does not give period.
Connect a signal generator to a loudspeaker and also to one channel of a 2-beam oscilloscope. Connect a microphone to the second channel. Display stable traces with the same timebase and place the microphone in line with the speaker.
Record the microphone position when the two traces have a clearly defined phase relation, such as in phase. Move the microphone away until that same phase relation next occurs; the displacement is one wavelength. For lower percentage uncertainty, move through several repeats and divide the total displacement by the number of wavelengths.
Read the period from the oscilloscope and calculate f=1/T, or use the calibrated generator frequency. Then calculate v=fλ. Repeat positions and use a best-fit relation where possible; record the air temperature because sound speed depends on conditions.
Moving from in-phase to antiphase corresponds to half a wavelength, not a whole wavelength. Avoid comparing unrelated peaks or using a timebase that cannot display a complete period.
| Term | Precise meaning |
|---|---|
| wavefront | line or surface joining points in the same phase |
| coherent sources | constant phase difference and the same frequency |
| path difference | difference between distances travelled to a point |
| phase | position within an oscillation cycle |
| superposition | resultant displacement is the algebraic sum of individual displacements |
| interference | spatial pattern produced when coherent waves superpose |
Waves arriving in phase reinforce to give constructive interference and a larger resultant amplitude. Waves arriving in antiphase oppose and give destructive interference; equal amplitudes can cancel completely.
Interference does not permanently destroy energy. The waves superpose while overlapping, and energy is redistributed across the interference pattern.
A path difference of one wavelength corresponds to one complete phase cycle. Therefore Δϕ=2π(Δx/λ) radians, or Δϕ=360∘(Δx/λ).
| Path difference | Phase difference | Interference for waves initially in phase |
|---|---|---|
| mλ | 2mπ | constructive |
| (m+21)λ | (2m+1)π | destructive |
| λ/4 | π/2 | intermediate |
If Δx=3λ/8, then Δϕ=2π(3/8)=3π/4 radians, or 135∘. Equivalent phases may differ by any whole multiple of 2π.
Path difference is a distance; phase difference is an angle. Do not compare their numerical values until path difference has been divided by wavelength.
A standing or stationary wave forms when two coherent waves of the same frequency travel in opposite directions and superpose, commonly because an incident wave reflects. Their interference fixes a pattern of nodes and antinodes in space.
| Position | Oscillation amplitude | Phase relation |
|---|---|---|
| node | zero | boundary between adjacent phase regions |
| antinode | maximum | all points between one pair of nodes oscillate in phase |
Neighbouring nodes are λ/2 apart, as are neighbouring antinodes; a node and its nearest antinode are λ/4 apart. There is no net energy transfer along an ideal stationary wave, although energy moves locally between stores.
The drawn envelope is not a wave profile travelling sideways. Nodes remain fixed, while points away from nodes oscillate with position-dependent amplitude.
For a transverse wave on a stretched string, v=T/μ, where T is tension in newtons and μ is mass per unit length in kgm−1. Linear density can be measured from μ=m/L.
At fixed μ, multiplying tension by four doubles speed. At fixed tension, multiplying μ by four halves speed. The square-root dependence means speed is not directly proportional to either quantity.
For T=90N and μ=2.5×10−3kgm−1, v=90/(2.5×10−3)=190ms−1 to two significant figures.
Use tension, not automatically the hanging weight if another arrangement changes the force in the vibrating section. Linear density is mass per length, not total mass.
Drive a stretched string with a vibration generator and signal generator. Adjust frequency until a clear stationary-wave pattern with a fixed number of loops appears. Measure vibrating length L, obtain tension from a hanging load where T=mg, and determine μ from the mass and length of a sample.
| Variable changed | Keep constant | Linear test for the same mode |
|---|---|---|
| length L | T,μ | f against 1/L |
| tension T | L,μ | f2 against T |
| linear density μ | L,T | f2 against 1/μ |
For the fundamental, λ=2L and f=(1/2L)T/μ. Change one variable at a time, retune to the same mode, repeat readings and use a best-fit line to judge the predicted relationship.
Comparisons are invalid if the number of loops changes between readings, because that changes wavelength as well as the chosen variable. Frequency does not depend on oscillation amplitude in this model.
Radiation intensity is power incident per unit area perpendicular to propagation: I=P/A. Its SI unit is Wm−2. Rearranging gives P=IA and, over time t, transferred energy E=IAt.
Radiation of intensity 250Wm−2 falls normally on a 0.40m2 surface. The incident power is P=(250)(0.40)=100W, so 300J arrives in 3.0s.
If a source radiates power uniformly in all directions, the relevant area at radius r is 4πr2, so I=P/(4πr2). This inverse-square result follows from the growing spherical area.
Intensity is not total power: the same power gives lower intensity when spread over a larger area. Use the area facing the radiation, not an unrelated surface area.
Refractive index is n=c/v, where c is light speed in vacuum and v is light speed in the medium. A larger n means lower wave speed.
At an interface, n1sinθ1=n2sinθ2. Measure both angles from the normal. Light entering a higher-index medium bends toward the normal; entering a lower-index medium bends away.
Light travels from air (n1=1.00) into glass (n2=1.50) at 30∘. Then sinθ2=(1.00/1.50)sin30∘=0.333, so θ2=19.5∘.
Frequency remains fixed at the boundary. Speed and wavelength change together, so bending is not caused by a frequency change. Angles drawn to the surface must be converted to angles to the normal.
The critical angle C is the incidence angle in the higher-index medium for which the refraction angle in the lower-index medium is 90∘. For a material of refractive index n meeting air, sinC=1/n.
Confirm that the ray travels from higher n to lower n, calculate 1/n, then use the inverse sine in degree mode. For n=1.52, C=sin−1(1/1.52)=41.1∘.
For two non-air media, Snell's law gives sinC=nlower/nhigher. The ratio must not exceed 1, consistent with the higher-to-lower condition.
At i=C, the ray is refracted along the interface; total internal reflection requires i>C. A critical angle is not defined for incidence from lower index to higher index.
| Check | Requirement for total internal reflection |
|---|---|
| direction | wave travels from higher refractive index to lower refractive index |
| incidence angle | i>C in the higher-index medium |
If both conditions hold, no refracted ray propagates into the second medium and the wave reflects internally. At i=C, the refracted ray travels along the boundary. At i<C, some wave is transmitted by refraction and some may be reflected.
Identify the two media, locate the normal, calculate or read C, and compare the incidence angle measured from the normal. State both the comparison and the resulting path.
A large incidence angle alone is insufficient. Total internal reflection cannot occur when light approaches a higher-index medium from a lower-index medium.
Place a transparent block on paper and trace its outline. Direct a narrow monochromatic ray at one face. Mark the incident and transmitted paths, remove the block, join the marks, and draw the normal at the entry point. Measure incidence i and refraction r from the normal with a protractor.
Repeat for several incidence angles. For air entering the solid, calculate n=sini/sinr, or plot sini vertically against sinr horizontally; the best-fit gradient is n when nair≈1.
Use a thin ray, widely separated path marks and angles neither extremely small nor near grazing incidence. Repeat measurements and use monochromatic light so different wavelengths do not refract by different amounts.
Do not measure angles from the block face. Measuring from the normal is essential, and one angle pair provides weaker evidence than the gradient of repeated data.
Unpolarised transverse radiation has oscillations in many directions perpendicular to travel. Plane-polarised radiation has oscillations restricted to one plane containing the direction of propagation.
A polarising filter transmits the component aligned with its transmission axis. A second filter acts as an analyser: aligned axes give strong transmission, while perpendicular axes ideally give no transmission. An intermediate angle transmits an intermediate intensity.
Polarisation is possible only when oscillations have a direction perpendicular to propagation. Its observation therefore supports the transverse nature of electromagnetic waves.
Polarisation does not mean the wave travels in one plane; it means the oscillation direction is confined. Longitudinal waves cannot be plane polarised in this way.
Diffraction is the spreading of waves after passing through a gap or around an obstacle. It is most noticeable when the gap or obstacle size is comparable with the wavelength.
In Huygens' construction, every point on an existing wavefront acts as a source of secondary wavelets. After a short time, the new wavefront is the envelope tangent to those wavelets.
Most wavelets are blocked at a barrier, but wavelets from points across a slit spread into the region beyond it. Their envelope is curved, predicting diffracted wavefronts. At an obstacle edge, unblocked wavelets extend into the geometric shadow.
Diffraction is not refraction: it does not require a change of medium or speed. A very wide gap compared with wavelength produces much less angular spreading.
For normal incidence on a diffraction grating, principal maxima satisfy nλ=dsinθ. Here n=0,1,2,… is order, d is slit spacing and θ is measured from the central normal.
Convert line density to spacing: if a grating has N lines per metre, d=1/N. For lines per millimetre, first multiply by 1000 to obtain lines per metre.
Identify the order, convert λ and d to metres, solve for sinθ=nλ/d, then use inverse sine. A possible order must satisfy nλ≤d because sinθ≤1.
The symbol n here is diffraction order, not refractive index. Measure θ from the central straight-through direction, and do not use small-angle approximations unless justified.
Mount a diffraction grating of known line density perpendicular to a narrow light beam. Place a screen a measured perpendicular distance D away. For a laser, keep the beam below eye level, secure it, never view the beam directly and remove reflective objects.
Mark the central maximum and matching order +n and −n maxima. Measure their separation and halve it to obtain x, reducing centre-location error. Calculate θ from tanθ=x/D.
Convert line density to d, then calculate λ=dsinθ/n. Repeat with several orders or distances and average consistent values. A graph of sinθ against n has gradient λ/d, providing a stronger multi-point result.
Screen displacement x is not the grating angle. Use the right triangle to obtain θ, keep order numbers correct, and do not replace sinθ by x/D unless the small-angle assumption is explicitly valid.
A beam of electrons passing through a thin crystalline target produces a diffraction pattern, such as concentric rings. The regular atomic spacing acts like a diffraction grating.
Diffraction is a wave phenomenon, so the pattern is evidence that electrons have wave behaviour. It occurs when the electron de Broglie wavelength is comparable with the spacing of atomic planes, allowing waves associated with different paths to interfere.
Changing electron momentum changes the de Broglie wavelength and therefore changes the diffraction geometry. The systematic pattern change links the effect to wavelength rather than to random particle scattering.
The experiment does not show electrons are ordinary classical waves or cease to behave as particles. It shows that a complete model must include wave behaviour for electrons.
The de Broglie relationship is λ=h/p, where h=6.63×10−34Js and p is momentum in kgms−1. For a non-relativistic particle, p=mv.
Calculate momentum first, then divide h by it. A larger momentum gives a shorter wavelength, so diffraction becomes harder to observe for everyday macroscopic objects.
An electron with momentum 2.0×10−23kgms−1 has λ=(6.63×10−34)/(2.0×10−23)=3.3×10−11m.
Momentum magnitude belongs in the wavelength calculation; direction is not represented by a negative wavelength. The relation applies to material particles, not only electrons.
When a wave reaches an interface between media, part of its energy may return as a reflected wave and part may enter the second medium as a transmitted wave. The proportions depend on the media and boundary conditions.
| Quantity | Reflected wave in original medium | Transmitted wave in new medium |
|---|---|---|
| frequency | unchanged | unchanged |
| speed | same as incident medium | set by new medium |
| wavelength | consistent with original speed | changes so v=fλ remains true |
For a straight boundary, reflection obeys equal incidence and reflection angles measured from the normal. Transmission may involve refraction when the wave speed changes.
Partial reflection does not mean the rest of the wave disappears. Track reflected and transmitted energy; amplitude is not itself an energy fraction.
A transducer sends a short pulse and detects its echo from an interface or object. If wave speed is v and the delay from emission to echo is t, the one-way distance is d=vt/2 because the pulse travels out and back.
An ultrasound echo returns after 40μs in material where v=4000ms−1. Then d=(4000)(40×10−6)/2=0.080m.
| Limitation | Why information is lost | Improvement |
|---|---|---|
| wavelength too large | nearby or small features cannot be distinguished spatially | use shorter wavelength where suitable |
| pulse duration too long | echoes from nearby boundaries overlap; pulse length is vΔt | use shorter pulses |
Never use vt as the object depth for a returned echo unless t is explicitly a one-way time. Detection also requires the echo to arrive after the transmitted pulse has ended.
| Model | Behaviour it explains directly | Core representation |
|---|---|---|
| wave model | interference, diffraction, polarisation and propagation | continuous wavefronts, phase and superposition |
| photon model | discrete light-matter energy transfer and photoelectric emission | packets with energy E=hf |
The wave model grew from evidence for interference and diffraction, but a wave-only account could not explain all observations of energy exchange with matter. The photon model was developed to represent those exchanges as discrete interactions. Later evidence therefore extended the available modelling rather than simply erasing the successful wave description.
Choose the model that exposes the behaviour under study. Electromagnetic radiation can display wave behaviour during propagation and interference while exchanging energy with matter in photon-sized amounts.
A model is not a literal picture of everything radiation 'really is'. Neither model alone accounts most clearly for every observation, so evidence determines which representation is useful.
The energy of one photon is E=hf, where h=6.63×10−34Js and f is frequency in hertz. Since f=c/λ in vacuum, shorter-wavelength radiation has greater photon energy.
For f=6.0×1014Hz, E=(6.63×10−34)(6.0×1014)=4.0×10−19J per photon to two significant figures.
Photon energy and beam intensity are different. At fixed frequency, greater intensity means more photon energy arriving per unit area per unit time, usually through a greater photon rate, not more energy per photon.
Use the frequency of the radiation, not its amplitude, to calculate the energy of one photon. Convert wavelength to frequency before using E=hf.
In the photoelectric effect, one photon is absorbed in a one-to-one interaction with one electron. The photon transfers its energy hf as a single amount.
Part of that energy may be required to release the electron from the metal surface. If the photon energy is sufficient, the remaining energy becomes electron kinetic energy. If it is insufficient, increasing the number of identical low-energy photons does not release an electron in this model.
At a frequency above threshold, increasing intensity increases the rate at which photons arrive, so more electrons can be emitted per second. It does not increase the energy of each unchanged-frequency photon.
An electron does not gradually accumulate fractions of energy from many below-threshold photons in the photoelectric model required here; absorption transfers one photon's energy in one interaction.
The work function ϕ is the minimum energy needed to release an electron from a metal surface. The threshold frequency f0 is the minimum radiation frequency that can cause emission, so ϕ=hf0.
Energy conservation for the most energetic emitted electrons is hf=ϕ+21mvmax2. Photon energy pays the work function first; any remainder becomes maximum kinetic energy.
If hf=5.0×10−19J and ϕ=3.2×10−19J, then Ek,max=1.8×10−19J.
Below f0, no emission occurs however intense the radiation. Above threshold, increasing frequency increases maximum kinetic energy; increasing intensity mainly increases the emission rate.
One electronvolt is the energy transferred when a particle with elementary charge moves through a potential difference of one volt: 1eV=1.60×10−19J.
| Conversion | Operation |
|---|---|
| eV to J | multiply by 1.60×10−19 |
| J to eV | divide by 1.60×10−19 |
3.2eV=(3.2)(1.60×10−19)=5.1×10−19J. Conversely, 8.0×10−19J=5.0eV.
The electronvolt is a unit of energy, not voltage and not charge. Do not attach a joule conversion factor twice when an equation already uses all energies in eV.
| Observation | Photon-model explanation |
|---|---|
| emission is effectively immediate | one photon transfers its energy in one interaction |
| each metal has a threshold frequency | one photon needs at least work-function energy |
| maximum electron kinetic energy rises with frequency | Ek,max=hf−ϕ |
| above threshold, emission rate rises with intensity | more photons arrive per second |
These observations support a particle description in which electromagnetic energy arrives in discrete photons. In particular, intense radiation below threshold still fails to emit electrons, whereas a continuous-wave-only energy accumulation picture would not predict this frequency cutoff and immediate response together.
Photoelectric evidence supports particle behaviour during energy transfer; it does not remove the independent wave evidence from interference, diffraction and polarisation.
Electrons in an atom can occupy only discrete energy levels. An electron moving from a higher level Eh to a lower level El emits one photon with hf=Eh−El. Absorption occurs when a photon supplies the matching energy difference for an upward transition.
Because only particular level differences exist, only particular photon frequencies and wavelengths are emitted or absorbed. These appear as separate spectral lines rather than a continuous range.
For an energy difference ΔE=3.0×10−19J, f=ΔE/h=(3.0×10−19)/(6.63×10−34)=4.5×1014Hz. If required, wavelength follows from λ=c/f.
Use the magnitude of the energy-level difference for photon energy, then use the transition direction to decide emission or absorption. A spectral line does not represent an electron occupying an energy between allowed levels.