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Edexcel IAL Chemistry 12.11 Thermodynamic and kinetic stability

For the sole direct task, state that positive ΔStotal makes the reaction feasible at 2048 K but high activation energy leaves it extremely slow.

Syllabus
First assessment 2019
Course
Chemistry YCH11
Level
A2

Exam points

  • Explain that positive ΔStotal can coexist with a very slow rate caused by high activation energy.

12.11—And distinguish between the concepts of thermodynamic stability and kinetic stability question 1

[Maximum number: 2]

Nitrous oxide, N2O\mathrm{N}_{2} \mathrm{O}, decomposes at high temperature to form nitrogen and oxygen.

N2O( g)N2( g)+1/2O2( g)\mathrm{N}_{2} \mathrm{O}(\mathrm{~g}) \rightleftharpoons \mathrm{N}_{2}(\mathrm{~g})+1 / 2 \mathrm{O}_{2}(\mathrm{~g})

Explain whether or not this reaction occurs at 2048 K by considering the values calculated in (a) and (b).

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