11.1 Atoms, nuclei and radiation
- Syllabus
- 9702–2028–2029
- Topic
- 11.1
- Level
- AS
Most alpha particles passed through thin foil, but a small fraction were deflected through large angles; this implies most atomic volume is empty with mass and positive charge concentrated in a tiny nucleus.
Use the scattering observations as evidence and distinguish the nuclear model from the older diffuse-charge model.
A near head-on deflection is rare because the nucleus occupies a tiny cross-section, yet it reveals strong repulsion from concentrated positive charge.
The experiment did not show electrons orbiting like planets; it established nuclear concentration, not a complete modern atom model.
A simple nuclear model places positively charged protons and neutral neutrons in a tiny nucleus, with negatively charged electrons occupying the surrounding region.
Mass is concentrated mainly in nucleons while atomic size is set by the electron region. This is a model, not a literal set of classical orbits.
Changing the number of electrons can make an ion without changing the nucleus or the element identity.
Electrons are not inside the nucleus in this model, and a neutral atom does not mean it contains no charged particles.
Proton number Z is the number of protons; nucleon number A is total protons plus neutrons, so neutron number is A−Z.
Z determines chemical identity. A can vary between isotopes while Z remains fixed.
A nuclide with A=23 and Z=11 contains 11 protons and 12 neutrons.
Nucleon number is not the number of electrons, and changing A alone does not create a new element.
Isotopes have the same proton number but different numbers of neutrons, so they share chemical identity but differ in mass and nuclear properties.
Compare Z first, then A. Isotopic abundance affects relative atomic mass without changing the element symbol.
Carbon-12 and carbon-14 both have Z=6; carbon-14 has two more neutrons and is radioactive.
Isotopes are not different elements, and isotope differences are not caused by different electron counts in neutral atoms.
⁽(A)Z)X:A=nucleonnumber,Z=protonnumber,X=elementsymbol
| Quantity | Count |
|---|---|
| protons | Z |
| neutrons | A − Z |
| electrons in a neutral atom | Z |
| electrons in an ion of charge +ne | Z − n |
| electrons in an ion of charge −ne | Z + n |
For ²³⁹₉₄Pu⁺, protons = 94, neutrons = 239 − 94 = 145 and electrons = 94 − 1 = 93. The + sign means one electron has been removed; it does not change the nucleus.
To write a nuclide symbol, use the periodic-table identity to select X and Z, then place total protons plus neutrons as A at upper left and Z at lower left.
Do not swap A and Z. A is not neutron number, and an ionic charge changes electron count only; it does not change A, Z or the isotope.
ΣAbefore=ΣAafterandΣ(q/e)before=Σ(q/e)after
| Emitted object | nucleon number A | charge number q/e |
|---|---|---|
| α particle | 4 | +2 |
| β⁻ electron | 0 | −1 |
| β⁺ positron | 0 | +1 |
| γ photon or (anti)neutrino | 0 | 0 |
Write every reactant and product, then total the upper numbers for nucleon number and the signed lower charge numbers independently. A missing particle or wrong daughter is exposed when either ledger fails.
Alpha decay conserves A through A = (A − 4) + 4 and charge through Z = (Z − 2) + 2. In beta-minus decay, the daughter's nuclear proton number rises by one, but total charge still balances: Z = (Z + 1) + (−1).
Proton number and neutron number are not each separately conserved in beta decay: one nucleon changes type. The conserved quantities here are total nucleon number and total electric charge across all products.
| Radiation | Composition | Rest mass | Charge |
|---|---|---|---|
| α | helium nucleus: 2 protons + 2 neutrons | about 4 u | +2e |
| β⁻ | electron | 9.11 × 10⁻³¹ kg ≈ 5.49 × 10⁻⁴ u | −e |
| β⁺ | positron | same as electron | +e |
| γ | electromagnetic photon | 0 | 0 |
Identify radiation from all three requested properties. Positive charge alone is insufficient: both α and β⁺ are positive, but α has charge magnitude 2e and a mass thousands of times larger.
α=24He,β−=−10e,β+=+10e,γ=00γ
Gamma radiation is electromagnetic radiation, not a neutral nucleon. A beta particle has the electron/positron rest mass; its high speed does not make its rest mass zero.
The antiparticle corresponding to a particle has the same rest mass and electric charge of equal magnitude but opposite sign.
| Particle | Antiparticle | Mass relation | Charge relation |
|---|---|---|---|
| electron e⁻ | positron e⁺ | equal | −e and +e |
| proton p | antiproton p̄ | equal | +e and −e |
If a top quark has charge +(2/3)e, its antiquark has the same mass and charge −(2/3)e. Reverse the sign; do not change the magnitude or mass.
A positron is specifically the electron's antiparticle. It is not a proton: both carry +e, but their masses and particle identities are different.
| Decay | Nucleon change | Charged beta particle | Neutral lepton |
|---|---|---|---|
| β⁻ | neutron → proton | electron e⁻ | electron antineutrino ν̄ₑ |
| β⁺ | proton → neutron | positron e⁺ | electron neutrino νₑ |
n→p+e−+νˉep→n+e++νe
Match the beta sign first: β⁻ is the electron and therefore accompanies the antineutrino; β⁺ is the positron and accompanies the neutrino. Both (anti)neutrinos have zero charge and zero nucleon number.
The (anti)neutrino is an additional emitted particle, not another name for the beta particle. Omitting it makes a beta-decay equation incomplete for this syllabus.
Alpha decay between quantised nuclear levels gives particles with characteristic discrete energies; beta decay shares energy with a neutrino, producing a continuous range.
Interpret line spectra and broad beta spectra as evidence about the number of bodies sharing decay energy.
A detector can show sharp alpha peaks but a broad beta distribution ending at a maximum energy.
A continuous beta spectrum does not mean beta particles are emitted with random violation of energy conservation; total energy is conserved event by event.
α:ZAX→−2A−4Y+24Heβ−:ZAX→+1AY+−10e+00νˉeβ+:ZAX→−1AY++10e+00νe
Identify the decay type, calculate the daughter A and Z, use Z to identify its element symbol, add every emitted particle, then check that upper numbers and signed lower numbers balance separately.
| Decay | Complete example | Check |
|---|---|---|
| α | ²³⁸₉₂U → ²³⁴₉₀Th + ⁴₂He | 238 = 234 + 4; 92 = 90 + 2 |
| β⁻ | ³₁H → ³₂He + ⁰₋₁e + ⁰₀ν̄ₑ | 3 = 3; 1 = 2 − 1 |
| β⁺ | ¹²₇N → ¹²₆C + ⁰₊₁e + ⁰₀νₑ | 12 = 12; 7 = 6 + 1 |
A is unchanged in beta decay. The daughter Z rises for β⁻ and falls for β⁺, and the correct electron (anti)neutrino must be included even though it contributes 0 to both number checks.
One unified atomic mass unit, 1 u, is one twelfth of the mass of a neutral carbon-12 atom. Use 1 u = 1.66 × 10⁻²⁷ kg.
massinkg=massinu×1.66×10−27massinu=massinkg÷(1.66×10−27)
A particle of mass 12.0 u has mass 12.0 × 1.66 × 10⁻²⁷ = 1.99 × 10⁻²⁶ kg.
A nucleus of mass 7.30 × 10⁻²⁶ kg has mass (7.30 × 10⁻²⁶)/(1.66 × 10⁻²⁷) = 44.0 u.
Nucleon number A is an integer count, not an exact nuclear mass in u. Binding energy causes the actual mass of a nucleus to differ from the simple sum of free nucleon masses.