CAIE A-Level Chemistry A2 26.1.1 And Use the Terms Rate Equation Order Topic Practice

Question 1

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A four-step mechanism is suggested for the reaction between hydrogen peroxide and iodide ions in an acidic solution.

step 1 H2O2+I−→IO−+H2O\mathrm{H}_{2} \mathrm{O}_{2}+\mathrm{I}^{-} \rightarrow \mathrm{IO}^{-}+\mathrm{H}_{2} \mathrm{O}

step 2 H++IO−→HIO\mathrm{H}^{+}+\mathrm{IO}^{-} \rightarrow \mathrm{HIO}

step 3 HIO+I−→I2+OH−\mathrm{HIO}+\mathrm{I}^{-} \rightarrow \mathrm{I}_{2}+\mathrm{OH}^{-}

step 4 OH−+H+→H2O\mathrm{OH}^{-}+\mathrm{H}^{+} \rightarrow \mathrm{H}_{2} \mathrm{O}

Step 1 is the rate-determining step.

State what is meant by the term rate-determining step.

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