CAIE IGCSE Chemistry 6.2 Rate of Reaction Topic Practice

Question 1

[Maximum number: 1]

Powdered magnesium carbonate is added to excess dilute hydrochloric acid.
The total volume of gas produced is measured over time.
A graph of the results is shown.

Figure for Question 1 — CAIE IGCSE Chemistry

The experiment is repeated but the concentration of the hydrochloric acid is doubled.

All other conditions are kept the same.
Which statements about the second experiment are correct?

1 The final volume of gas is 360 cm3360 \mathrm{~cm}^{3}.
2 The reaction finishes before 90 seconds.
3 The activation energy of the reaction is lower.

A

1 and 2

B

1 and 3

C

2 and 3

D

2 only

Question 2

[Maximum number: 1]

The equation for the decomposition of hydrogen peroxide, H2O2\mathrm{H}_{2} \mathrm{O}_{2}, is shown.

2H2O2→2H2O+O22 \mathrm{H}_{2} \mathrm{O}_{2} \rightarrow 2 \mathrm{H}_{2} \mathrm{O}+\mathrm{O}_{2}

In an experiment, the total volume of oxygen produced is 100 cm3100 \mathrm{~cm}^{3}.
The experiment is repeated using 1.00 g of a solid catalyst. All other conditions remain the same.
Which row describes the total volume of oxygen and the mass of the catalyst at the end of the second experiment?

total volume of oxygen
/cm3/ \mathrm{cm}^{3}

mass of catalyst
/g

more than 100

less than 1.00

100

less than 1.00

100

1.00

more than 100

1.00

Question 3

[Maximum number: 1]

The apparatus shown is used to measure the rate of a reaction.

Figure for Question 3 — CAIE IGCSE Chemistry

Which equation represents a reaction where the rate can be measured using this apparatus?

A

Mg(s)+2HCl(aq)→MgCl2(aq)+H2( g)\mathrm{Mg}(\mathrm{s})+2 \mathrm{HCl}(\mathrm{aq}) \rightarrow \mathrm{MgCl}_{2}(\mathrm{aq})+\mathrm{H}_{2}(\mathrm{~g})

B

HCl(aq)+NaOH(aq)→NaCl(aq)+H2O(l)\mathrm{HCl}(\mathrm{aq})+\mathrm{NaOH}(\mathrm{aq}) \rightarrow \mathrm{NaCl}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l})

C

Fe(s)+CuSO4(aq)→Cu(s)+FeSO4(aq)\mathrm{Fe}(\mathrm{s})+\mathrm{CuSO}_{4}(\mathrm{aq}) \rightarrow \mathrm{Cu}(\mathrm{s})+\mathrm{FeSO}_{4}(\mathrm{aq})

D

2Na(s)+Br2(l)→2NaBr(s)2 \mathrm{Na}(\mathrm{s})+\mathrm{Br}_{2}(\mathrm{l}) \rightarrow 2 \mathrm{NaBr}(\mathrm{s})

Question 4

[Maximum number: 1]

A student adds excess magnesium ribbon to 10 cm310 \mathrm{~cm}^{3} of 0.5 mol/dm30.5 \mathrm{~mol} / \mathrm{dm}^{3} sulfuric acid.
The hydrogen gas produced is collected and its total volume is measured every 10 seconds.
The experiment is repeated with 5 cm35 \mathrm{~cm}^{3} of 0.5 mol/dm30.5 \mathrm{~mol} / \mathrm{dm}^{3} sulfuric acid added to 5 cm35 \mathrm{~cm}^{3} of water using the same mass of magnesium ribbon.

Which line on the graph shows the results of the second experiment?

Figure for Question 4 — CAIE IGCSE Chemistry

Question 5

[Maximum number: 1]

Which change in conditions increases the energy of the particles in a reaction?

A

addition of a catalyst

B

increase in concentration

C

increase in surface area

D

increase in temperature

Question 6

[Maximum number: 1]

Which statements explain why increasing the temperature changes the rate of a chemical reaction?

1 It increases the activation energy.
2 It increases the frequency of collisions between the reacting particles.
3 It increases the kinetic energy of the reacting particles.
4 It increases the number of particles per unit volume.

A

1 and 2

B

1 and 4

C

2 and 3

D

3 and 4

Question 7

[Maximum number: 1]

Hydrogen iodide thermally decomposes into iodine and hydrogen. The reaction is reversible.

2HI( g) colourless gas →⇌I2( g) purple gas +H2( g) colourless gas \underset{\text { colourless gas }}{2 \mathrm{HI}(\mathrm{~g})} \rightarrow \underset{\substack{\mathrm{I}_{2}(\mathrm{~g}) \\ \text { purple gas }}}{\rightleftharpoons}+\underset{\substack{\mathrm{H}_{2}(\mathrm{~g}) \\ \text { colourless gas }}}{ }

Fig. 4.1 shows a gas syringe containing a mixture of hydrogen iodide, iodine and hydrogen gases. The gas syringe is sealed and the mixture is heated to 300∘C300^{\circ} \mathrm{C}. The mixture of gases reaches equilibrium and is purple.

Fig. 4.1

Fig. 4.1

Methanol is manufactured by reacting carbon monoxide with hydrogen.

CO( g)+2H2( g)⇌CH3OH( g)\mathrm{CO}(\mathrm{~g})+2 \mathrm{H}_{2}(\mathrm{~g}) \rightleftharpoons \mathrm{CH}_{3} \mathrm{OH}(\mathrm{~g})

The rate of formation of methanol increases when a catalyst is used.

State the effect that a catalyst has on the activation energy, EaE_{\mathrm{a}}, of a reaction.

All question bank results loaded