IB Chemistry HL 2.1.2 Mole ratio Question Bank

Two groups of students (Group A and Group B) carried out a project* on the chemistry of some group 7 elements (the halogens) and their compounds.

The students reacted ICl(l) with CsBr(s) to form a yellow solid, $\mathrm{CsICl}_{2}(\mathrm{~s})$, as one of the products. $\mathrm{CsICl}_{2}(\mathrm{~s})$ has been found to produce very pure CsCl(s) which is used in cancer treatment.

To confirm the composition of the yellow solid, Group A determined the amount of iodine in 0.2015 g of $\mathrm{CsICl}_{2}(\mathrm{~s})$ by titrating it with $0.0500 \mathrm{moldm}^{-3} \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}(\mathrm{aq})$. The following data were recorded for the titration.

The overall reaction taking place during the titration is:

Calculate the amount, in mol, of iodine atoms, I , present in the sample of $\mathrm{CsICl}_{2}(\mathrm{~s})$.