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10.1.4—Describe, and make predictions

Syllabus
9701–2028–2029
Objective
10.1.4
Level
AS

Use ionic size and charge density to predict Group 2 trends

Down Group 2, ionic radius increases while charge remains +2. Charge density therefore decreases, affecting hydration, lattice interactions, solubility and thermal stability.

Link a prediction to the relevant process: lower polarisation stabilises oxyanions, while hydration and lattice-energy changes determine solubility trends.

Ba²⁺ is larger than Mg²⁺, so BaCO₃ is more thermally stable. Hydroxide solubility rises down the group, whereas sulfate solubility falls.

Not every property changes in the same direction. State which competing energies control the particular trend instead of applying one arrow to all compounds.

ConceptA-Level CAIE Chemistry AS