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AP Chemistry Unit 4.6: Titrations

Practice AP Chemistry Unit 4.6 questions on reading titration volumes, using equivalence-point mole ratios, calculating unknown concentrations, and evaluating experimental choices.

Syllabus
Effective Fall 2025
Course
AP Chemistry

Exam points

  • Use acid–base equilibria and titration data to calculate pH, Ka, Kb, and concentrations at key points.
  • Interpret buffer composition, neutralization, and indicator behavior to explain titration curves.

4.6 Introduction to Titration question 1

[Maximum number: 2]

A student dissolved a 0.139 g sample of oxalic acid, H2C2O4\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}, in water in an Erlenmeyer flask. Then the student titrated the H2C2O4\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4} solution in the flask with a solution of KMnO4\mathrm{KMnO}_{4}, which has a dark purple color. The balanced chemical equation for the reaction that occurred during the titration is shown above.

Question (a)

(a)

The student used a 50.0 mL buret to add the KMnO4(aq)\mathrm{KMnO}_{4}(a q) to the H2C2O4(aq)\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(a q) until a faint lavender color was observed in the flask, an indication that the end point of the titration had been reached. The initial and final volume readings of the solution in the buret are shown below. Write down the initial reading and the final reading and use them to determine the volume of KMnO4(aq)\mathrm{KMnO}_{4}(a q) that was added during the titration.

Figure for Question (a) — AP Chemistry
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Question (b)

(b)

The student proposes to perform another titration using a 0.139 g sample of H2C2O4\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}, but this time using 0.00143MKMnO4(aq)0.00143 M \mathrm{KMnO}_{4}(a q) in the buret. Would this titrant concentration be a reasonable choice to use if the student followed the same procedure and used the same equipment as before? Justify your response.

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