1.4 - Materials

Syllabus
2021
Topic
1.4
Level
AS

Learning objectives

1.4.23DensityUse density ρ = m/V.1.4.24Upthrust and displaced fluidUnderstand how to use the relationship upthrust = weight of fluid displaced1.4.25Stokes’ law and viscosityA be able to use the equation for viscous drag (Stokes’ Law), F = 6πηrv. b understand that this equation applies only to small spherical objects moving at low speeds with laminar flow (or in the absence of turbulent flow) and that viscosity is temperature dependent1.4.26Core Practical 2 - viscosity by falling-ball methodCORE PRACTICAL 2: Use a falling-ball method to determine the viscosity of a liquid1.4.27Hooke’s lawBe able to use the Hooke’s law equation, ∆F = k∆x, where k is the stiffness of the object1.4.28Stress, strain and Young modulusUnderstand how to use the relationships • (tensile or compressive) stress = force/cross-sectional area • (tensile or compressive) strain= change in length/original length Young modulus = stress/strain.1.4.29Force-extension and force-compression graphsA be able to draw and interpret force-extension and force-compression graphs b understand the terms limit of proportionality, elastic limit, yield point, elastic deformation and plastic deformation and be able to apply them to these graphs1.4.30Stress-strain graphs and breaking stressBe able to draw and interpret tensile or compressive stress-strain graphs, and understand the term breaking stress1.4.31Core Practical 3 - Young modulusCORE PRACTICAL 3: Determine the Young modulus of a material1.4.32Elastic strain energyCalculate elastic strain energy using ΔEel = ½FΔx and the area under a force–extension graph, including estimating areas for linear and non-linear graphs.

Density links mass to occupied volume

Density is mass per unit volume: ρ=m/V\rho=m/V. In SI units, mass is in kilograms, volume in cubic metres and density in kgm3\mathrm{kg\,m^{-3}}. The relationship can be rearranged to m=ρVm=\rho V or V=m/ρV=m/\rho.

Identify the material volume represented by the data, convert each measurement before substitution, and check powers of ten carefully. For a regular solid, calculate volume from its dimensions; for an irregular solid, a measured displacement volume may be used.

A sample has mass 0.54kg0.54\,\mathrm{kg} and volume 2.0×104m32.0\times10^{-4}\,\mathrm{m^3}. Its density is 0.54/(2.0×104)=2.7×103kgm30.54/(2.0\times10^{-4})=2.7\times10^3\,\mathrm{kg\,m^{-3}}.

Density is not the same as mass: a small sample and a large sample of the same uniform material have different masses but the same density under the same conditions. Convert cm3\mathrm{cm^3} to m3\mathrm{m^3} cubically, not linearly.

Upthrust equals the weight of displaced fluid

A body in a fluid experiences an upward force because fluid pressure is greater at greater depth. The resulting upthrust equals the weight of fluid displaced: U=mfluidg=ρfluidVdisplacedgU=m_{fluid}g=\rho_{fluid}V_{displaced}g.

Situation Displaced volume Force conclusion
fully submerged submerged object's external volume compare UU with weight and other forces
partly submerged volume below the fluid surface floating equilibrium gives U=WU=W if no other vertical force
accelerating upward resultant upward force is positive, so UU exceeds downward forces

A fully submerged object displaces 3.0×104m33.0\times10^{-4}\,\mathrm{m^3} of water of density 1000kgm31000\,\mathrm{kg\,m^{-3}}. Its upthrust is (1000)(3.0×104)(9.81)=2.9N(1000)(3.0\times10^{-4})(9.81)=2.9\,\mathrm{N}.

Use the volume of fluid actually displaced, not automatically the object's total volume. Floating does not mean there is no weight; it normally means upthrust balances weight.

Stokes' law is a conditional model of viscous drag

For a small sphere moving slowly through a fluid with laminar flow, Stokes' law gives viscous drag F=6πηrvF=6\pi\eta rv. Here η\eta is dynamic viscosity in Pas\mathrm{Pa\,s}, rr is sphere radius and vv is speed relative to the fluid. Drag acts opposite to relative motion.

Change while other terms stay fixed Effect on Stokes drag
viscosity η\eta increases drag increases in direct proportion
radius rr increases drag increases in direct proportion at the same speed
speed vv increases drag increases in direct proportion

At terminal speed for a falling sphere, W=U+FdragW=U+F_{drag}. Therefore Fdrag=WUF_{drag}=W-U can be inserted into Stokes' law to find viscosity or speed. For the liquids considered here, increasing temperature reduces viscosity, so a given sphere reaches a greater terminal speed.

Do not use Stokes' law without checking its conditions: the object must be small and spherical, speed low, and flow laminar rather than turbulent. Temperature must be controlled because viscosity is temperature dependent.

Core Practical 2: determine viscosity with a falling ball

Measure the sphere's diameter in several orientations with a micrometer and average it to obtain rr. Obtain the sphere's weight and the liquid density, or measure the quantities needed to calculate them. Keep the transparent liquid column vertical and record its temperature.

Place at least three horizontal markers on the tube. Release the sphere centrally without pushing it. Put the first timing marker far enough below the surface for acceleration to have ended. Confirm terminal motion by showing that equal distances take equal times, or that speeds in consecutive marked regions agree.

Measure a marker separation ss with a metre rule and time the same point on the sphere crossing the two markers. Repeat and average, then calculate v=s/tv=s/t. Reduce reaction-time error with a longer timed distance or calibrated video, while keeping the sphere in the terminal-speed region.

At terminal speed, use W=U+6πηrvW=U+6\pi\eta rv, with U=ρliquidVspheregU=\rho_{liquid}V_{sphere}g, and rearrange for η\eta. Keep all quantities in SI units and compare repeats before quoting an appropriately precise result.

A constant speed must be demonstrated, not assumed immediately after release. Control temperature and avoid timing near the surface or bottom, where the motion may not represent the Stokes-law model.

Hooke's law defines stiffness in the proportional region

Hooke's law is ΔF=kΔx\Delta F=k\Delta x: change in force is proportional to change in extension or compression while the response remains proportional. The stiffness k=ΔF/Δxk=\Delta F/\Delta x is measured in Nm1\mathrm{N\,m^{-1}}.

Measure extension from the unloaded length, not the total length. On a force-against-extension graph, kk is the gradient of the straight proportional section. Rearrange to Δx=ΔF/k\Delta x=\Delta F/k when stiffness and force change are known.

A spring length changes from 0.180m0.180\,\mathrm{m} to 0.230m0.230\,\mathrm{m} when force increases by 4.0N4.0\,\mathrm{N}. Since Δx=0.050m\Delta x=0.050\,\mathrm{m}, k=4.0/0.050=80Nm1k=4.0/0.050=80\,\mathrm{N\,m^{-1}}.

Hooke's law does not describe every load. Beyond the limit of proportionality the graph is no longer linear, so one constant value of kk no longer predicts the whole response. Stiffness describes the object and depends on its dimensions as well as its material.

Stress and strain separate material response from sample size

Quantity Relationship Unit
stress σ\sigma F/AF/A, using cross-sectional area perpendicular to force Pa=Nm2\mathrm{Pa}=\mathrm{N\,m^{-2}}
strain ε\varepsilon ΔL/L\Delta L/L, using original length no unit
Young modulus EE σ/ε\sigma/\varepsilon Pa\mathrm{Pa}

Stress measures force intensity; strain measures fractional length change. Young modulus compares them in the linear elastic region and measures material stiffness: a larger EE means more stress is required for the same strain.

Convert diameter to radius and calculate A=πr2A=\pi r^2 for a circular wire. Use extension rather than final length in strain. Equivalently, substituting the definitions gives E=FL/(AΔL)E=FL/(A\Delta L).

Young modulus is a material property only when the response is in the appropriate linear elastic region. Strain is a ratio, so it has no unit; extension alone cannot compare differently sized samples fairly.

Force-deformation graphs distinguish proportionality from recovery

Feature Meaning on a force-extension or force-compression graph
limit of proportionality end of the straight region where FΔxF\propto\Delta x
elastic limit greatest deformation from which the object returns to its original dimensions when unloaded
yield point large additional deformation occurs for a small force increase
elastic deformation removed when the force is removed
plastic deformation permanent deformation remains after unloading

In the initial straight region, gradient ΔF/Δx\Delta F/\Delta x is stiffness. A curved graph beyond the proportional limit may still include some elastic behaviour, so the limit of proportionality and elastic limit are different ideas.

To decide whether deformation is elastic or plastic, consider what happens after the force is removed. Returning to zero deformation indicates elastic recovery; a non-zero intercept on the deformation axis indicates permanent change.

A graph becoming curved does not by itself prove that the elastic limit has been passed. Proportionality concerns the shape of the loading graph; elasticity concerns whether the original dimensions are recovered.

Stress-strain graphs compare materials independently of geometry

Plot tensile or compressive stress on the vertical axis against strain on the horizontal axis. Because both quantities account for sample dimensions, the graph describes material response more directly than a force-extension graph.

Graph feature Physical meaning
initial straight-line gradient Young modulus E=σ/εE=\sigma/\varepsilon
greater gradient stiffer material in the linear elastic region
strain at a stated stress fractional length change
breaking point fracture; its stress coordinate is the breaking stress

When comparing samples, use the same feature: gradient for stiffness, breaking stress for resistance to fracture by stress, and strain coordinate for deformation. Read values with axis multipliers and units before calculating.

The steepest graph is the stiffest, not automatically the one with the greatest breaking stress. Stiffness and the stress sustained before fracture describe different properties.

Core Practical 3: determine a material's Young modulus

Clamp a long, thin wire securely and measure its original test length LL. Measure diameter with a micrometer at several positions and in different orientations, then average and calculate A=πd2/4A=\pi d^2/4. A long, thin wire gives a larger measurable extension for a given load, reducing percentage uncertainty in extension.

Add known masses gradually, allow the wire to settle, and record extension ΔL\Delta L from a fiducial marker or pointer. Calculate tensile force F=mgF=mg. Repeat readings where practical and keep loads within the linear elastic region so the wire returns to its original length.

Plot stress F/AF/A against strain ΔL/L\Delta L/L; the best-fit gradient of the straight region is EE. Alternatively, plot FF against ΔL\Delta L: if its gradient is kk, then E=kL/AE=kL/A. Use a large gradient triangle and propagate the measured units consistently.

Check micrometer zero error, avoid parallax at the extension scale, and use a tray or shield beneath suspended masses. Do not exceed a safe load or stand below the load. Diameter uncertainty matters strongly because area depends on d2d^2.

Do not calculate Young modulus from one unverified loading point when a graph is available. The gradient must come from the proportional region; plastic deformation would invalidate the assumed constant ratio.

Area under a force-extension graph is elastic energy

A small increase in extension requires work FdxF\,d x. Therefore the elastic strain energy change is the area under the force-extension graph between the chosen extensions. Force in newtons multiplied by extension in metres gives joules.

For a linear graph starting at the origin, the area is a triangle: ΔEel=12FΔx\Delta E_{el}=\tfrac12F\Delta x. For example, reaching F=30NF=30\,\mathrm{N} at Δx=0.080m\Delta x=0.080\,\mathrm{m} stores 0.5(30)(0.080)=1.2J0.5(30)(0.080)=1.2\,\mathrm{J}.

For a non-linear graph, divide the region into narrow strips and add trapezium areas, or count grid squares with the axis scale applied. Narrower strips follow the curve more closely. State that the result is an estimate and retain sensible precision.

The expression 12FΔx\tfrac12F\Delta x is not valid for an arbitrary curved force-extension graph. It is the triangular area only when force rises linearly from zero; otherwise use the actual area under the curve.