1.4 - Materials
- Syllabus
- 2021
- Topic
- 1.4
- Level
- AS
Density is mass per unit volume: ρ=m/V. In SI units, mass is in kilograms, volume in cubic metres and density in kgm−3. The relationship can be rearranged to m=ρV or V=m/ρ.
Identify the material volume represented by the data, convert each measurement before substitution, and check powers of ten carefully. For a regular solid, calculate volume from its dimensions; for an irregular solid, a measured displacement volume may be used.
A sample has mass 0.54kg and volume 2.0×10−4m3. Its density is 0.54/(2.0×10−4)=2.7×103kgm−3.
Density is not the same as mass: a small sample and a large sample of the same uniform material have different masses but the same density under the same conditions. Convert cm3 to m3 cubically, not linearly.
A body in a fluid experiences an upward force because fluid pressure is greater at greater depth. The resulting upthrust equals the weight of fluid displaced: U=mfluidg=ρfluidVdisplacedg.
| Situation | Displaced volume | Force conclusion |
|---|---|---|
| fully submerged | submerged object's external volume | compare U with weight and other forces |
| partly submerged | volume below the fluid surface | floating equilibrium gives U=W if no other vertical force |
| accelerating upward | — | resultant upward force is positive, so U exceeds downward forces |
A fully submerged object displaces 3.0×10−4m3 of water of density 1000kgm−3. Its upthrust is (1000)(3.0×10−4)(9.81)=2.9N.
Use the volume of fluid actually displaced, not automatically the object's total volume. Floating does not mean there is no weight; it normally means upthrust balances weight.
For a small sphere moving slowly through a fluid with laminar flow, Stokes' law gives viscous drag F=6πηrv. Here η is dynamic viscosity in Pas, r is sphere radius and v is speed relative to the fluid. Drag acts opposite to relative motion.
| Change while other terms stay fixed | Effect on Stokes drag |
|---|---|
| viscosity η increases | drag increases in direct proportion |
| radius r increases | drag increases in direct proportion at the same speed |
| speed v increases | drag increases in direct proportion |
At terminal speed for a falling sphere, W=U+Fdrag. Therefore Fdrag=W−U can be inserted into Stokes' law to find viscosity or speed. For the liquids considered here, increasing temperature reduces viscosity, so a given sphere reaches a greater terminal speed.
Do not use Stokes' law without checking its conditions: the object must be small and spherical, speed low, and flow laminar rather than turbulent. Temperature must be controlled because viscosity is temperature dependent.
Measure the sphere's diameter in several orientations with a micrometer and average it to obtain r. Obtain the sphere's weight and the liquid density, or measure the quantities needed to calculate them. Keep the transparent liquid column vertical and record its temperature.
Place at least three horizontal markers on the tube. Release the sphere centrally without pushing it. Put the first timing marker far enough below the surface for acceleration to have ended. Confirm terminal motion by showing that equal distances take equal times, or that speeds in consecutive marked regions agree.
Measure a marker separation s with a metre rule and time the same point on the sphere crossing the two markers. Repeat and average, then calculate v=s/t. Reduce reaction-time error with a longer timed distance or calibrated video, while keeping the sphere in the terminal-speed region.
At terminal speed, use W=U+6πηrv, with U=ρliquidVsphereg, and rearrange for η. Keep all quantities in SI units and compare repeats before quoting an appropriately precise result.
A constant speed must be demonstrated, not assumed immediately after release. Control temperature and avoid timing near the surface or bottom, where the motion may not represent the Stokes-law model.
Hooke's law is ΔF=kΔx: change in force is proportional to change in extension or compression while the response remains proportional. The stiffness k=ΔF/Δx is measured in Nm−1.
Measure extension from the unloaded length, not the total length. On a force-against-extension graph, k is the gradient of the straight proportional section. Rearrange to Δx=ΔF/k when stiffness and force change are known.
A spring length changes from 0.180m to 0.230m when force increases by 4.0N. Since Δx=0.050m, k=4.0/0.050=80Nm−1.
Hooke's law does not describe every load. Beyond the limit of proportionality the graph is no longer linear, so one constant value of k no longer predicts the whole response. Stiffness describes the object and depends on its dimensions as well as its material.
| Quantity | Relationship | Unit |
|---|---|---|
| stress σ | F/A, using cross-sectional area perpendicular to force | Pa=Nm−2 |
| strain ε | ΔL/L, using original length | no unit |
| Young modulus E | σ/ε | Pa |
Stress measures force intensity; strain measures fractional length change. Young modulus compares them in the linear elastic region and measures material stiffness: a larger E means more stress is required for the same strain.
Convert diameter to radius and calculate A=πr2 for a circular wire. Use extension rather than final length in strain. Equivalently, substituting the definitions gives E=FL/(AΔL).
Young modulus is a material property only when the response is in the appropriate linear elastic region. Strain is a ratio, so it has no unit; extension alone cannot compare differently sized samples fairly.
| Feature | Meaning on a force-extension or force-compression graph |
|---|---|
| limit of proportionality | end of the straight region where F∝Δx |
| elastic limit | greatest deformation from which the object returns to its original dimensions when unloaded |
| yield point | large additional deformation occurs for a small force increase |
| elastic deformation | removed when the force is removed |
| plastic deformation | permanent deformation remains after unloading |
In the initial straight region, gradient ΔF/Δx is stiffness. A curved graph beyond the proportional limit may still include some elastic behaviour, so the limit of proportionality and elastic limit are different ideas.
To decide whether deformation is elastic or plastic, consider what happens after the force is removed. Returning to zero deformation indicates elastic recovery; a non-zero intercept on the deformation axis indicates permanent change.
A graph becoming curved does not by itself prove that the elastic limit has been passed. Proportionality concerns the shape of the loading graph; elasticity concerns whether the original dimensions are recovered.
Plot tensile or compressive stress on the vertical axis against strain on the horizontal axis. Because both quantities account for sample dimensions, the graph describes material response more directly than a force-extension graph.
| Graph feature | Physical meaning |
|---|---|
| initial straight-line gradient | Young modulus E=σ/ε |
| greater gradient | stiffer material in the linear elastic region |
| strain at a stated stress | fractional length change |
| breaking point | fracture; its stress coordinate is the breaking stress |
When comparing samples, use the same feature: gradient for stiffness, breaking stress for resistance to fracture by stress, and strain coordinate for deformation. Read values with axis multipliers and units before calculating.
The steepest graph is the stiffest, not automatically the one with the greatest breaking stress. Stiffness and the stress sustained before fracture describe different properties.
Clamp a long, thin wire securely and measure its original test length L. Measure diameter with a micrometer at several positions and in different orientations, then average and calculate A=πd2/4. A long, thin wire gives a larger measurable extension for a given load, reducing percentage uncertainty in extension.
Add known masses gradually, allow the wire to settle, and record extension ΔL from a fiducial marker or pointer. Calculate tensile force F=mg. Repeat readings where practical and keep loads within the linear elastic region so the wire returns to its original length.
Plot stress F/A against strain ΔL/L; the best-fit gradient of the straight region is E. Alternatively, plot F against ΔL: if its gradient is k, then E=kL/A. Use a large gradient triangle and propagate the measured units consistently.
Check micrometer zero error, avoid parallax at the extension scale, and use a tray or shield beneath suspended masses. Do not exceed a safe load or stand below the load. Diameter uncertainty matters strongly because area depends on d2.
Do not calculate Young modulus from one unverified loading point when a graph is available. The gradient must come from the proportional region; plastic deformation would invalidate the assumed constant ratio.
A small increase in extension requires work Fdx. Therefore the elastic strain energy change is the area under the force-extension graph between the chosen extensions. Force in newtons multiplied by extension in metres gives joules.
For a linear graph starting at the origin, the area is a triangle: ΔEel=21FΔx. For example, reaching F=30N at Δx=0.080m stores 0.5(30)(0.080)=1.2J.
For a non-linear graph, divide the region into narrow strips and add trapezium areas, or count grid squares with the axis scale applied. Narrower strips follow the curve more closely. State that the result is an estimate and retain sensible precision.
The expression 21FΔx is not valid for an arbitrary curved force-extension graph. It is the triangular area only when force rises linearly from zero; otherwise use the actual area under the curve.