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Edexcel IAL Chemistry Arithmetic and Weighted Means

Practise Edexcel IAL Chemistry arithmetic and weighted means through titration tables, concordant titres, outlier choices and mean-volume calculations.

Syllabus
Pearson Edexcel International Advanced Subsidiary/Advanced Level
Course
Chemistry XCH11/YCH11
Level
AS

Exam points

  • Select concordant titres within 0.2 cm3 and exclude rough or outlying titrations before averaging.
  • Complete burette-reading tables by subtracting initial from final volumes before calculating a mean titre.
  • Calculate arithmetic means from all valid results and report titre or volume values with suitable precision.

B.1.2—Arithmetic and weighted means question 1

[Maximum number: 1]

Washing soda is hydrated sodium carbonate ( Na2CO3nH2O\mathrm{Na}_{2} \mathrm{CO}_{3} \cdot \mathrm{nH}_{2} \mathrm{O} ). The value of n can be determined by titration.

A titration method was carried out using the following procedure.
Step 14.29 g of Na2CO3nH2O\mathrm{Na}_{2} \mathrm{CO}_{3} \cdot \mathrm{nH}_{2} \mathrm{O} was weighed into a beaker.
Step 2 The Na2CO3nH2O\mathrm{Na}_{2} \mathrm{CO}_{3} \cdot \mathrm{nH}_{2} \mathrm{O} was dissolved in 50 cm350 \mathrm{~cm}^{3} of deionised water.
Step 3 All of the solution was transferred to a 250 cm3250 \mathrm{~cm}^{3} volumetric flask. The beaker was rinsed with deionised water and these washings were added to the volumetric flask.

Step 4 The volumetric flask was made up to the mark with deionised water. The flask was stoppered and inverted several times.

Step 5 A burette, pipette and conical flask were all rinsed with deionised water.
Step 6 The burette was rinsed and then filled with 0.125 moldm30.125 \mathrm{~mol} \mathrm{dm}^{-3} hydrochloric acid solution. The pipette was rinsed with the sodium carbonate solution and then used to transfer 25.0 cm325.0 \mathrm{~cm}^{3} of the solution to the conical flask.

Step 7 A few drops of methyl orange were added to the conical flask. The sodium carbonate solution was titrated with the hydrochloric acid. This step was repeated until concordant titres were obtained.

The following results were obtained in the titration.

Table for Question B.1.2—Arithmetic and weighted means question 1 — Edexcel A-Level Chemistry AS

Complete the table and calculate the mean titre, using all concordant values.

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