Washing soda is hydrated sodium carbonate ( Na2CO3⋅nH2O ). The value of n can be determined by titration.
A titration method was carried out using the following procedure.
Step 14.29 g of Na2CO3⋅nH2O was weighed into a beaker.
Step 2 The Na2CO3⋅nH2O was dissolved in 50 cm3 of deionised water.
Step 3 All of the solution was transferred to a 250 cm3 volumetric flask. The beaker was rinsed with deionised water and these washings were added to the volumetric flask.
Step 4 The volumetric flask was made up to the mark with deionised water. The flask was stoppered and inverted several times.
Step 5 A burette, pipette and conical flask were all rinsed with deionised water.
Step 6 The burette was rinsed and then filled with 0.125 moldm−3 hydrochloric acid solution. The pipette was rinsed with the sodium carbonate solution and then used to transfer 25.0 cm3 of the solution to the conical flask.
Step 7 A few drops of methyl orange were added to the conical flask. The sodium carbonate solution was titrated with the hydrochloric acid. This step was repeated until concordant titres were obtained.