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IGCSE Chemistry11.7 Carboxylic acidsQuestion Bank

Question 1

[Maximum number: 1]

Some symbol equations and word equations, A to J, are shown.

A Fe3++3OHFe(OH)3\mathrm{Fe}^{3+}+3 \mathrm{OH}^{-} \rightarrow \mathrm{Fe}(\mathrm{OH})_{3}

B H++OHH2O\mathrm{H}^{+}+\mathrm{OH}^{-} \rightarrow \mathrm{H}_{2} \mathrm{O}

C ethane + chlorine → chloroethane + hydrogen chloride

D C12H26C8H18+C4H8\mathrm{C}_{12} \mathrm{H}_{26} \rightarrow \mathrm{C}_{8} \mathrm{H}_{18}+\mathrm{C}_{4} \mathrm{H}_{8}

E ethene + steam → ethanol
F chlorine + aqueous potassium iodide → iodine + aqueous potassium chloride

G C6H12O62C2H5OH+2CO2\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6} \rightarrow 2 \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}+2 \mathrm{CO}_{2}

H ethanoic acid + ethanol → ethyl ethanoate + water
I calcium carbonate → calcium oxide + carbon dioxide

J 6CO2+6H2OC6H12O6+6O26 \mathrm{CO}_{2}+6 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}+6 \mathrm{O}_{2}

Use the equations to answer the questions that follow.
Each equation may be used once, more than once, or not at all.
Give the letter, A to J, for the equation that represents:

Question 1(c)

(a)

the formation of an ester [1]

[ 1 ]

Question 1

Question 1(a)

(a)

The structures of five organic compounds, A, B, C, D and E, are shown.
Answer the questions that follow.
Each letter may be used once, more than once or not at all.
A

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B

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c

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D

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E
E

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[ 1 ]

Question 1(a)(v)

(i)

Give the letters of two compounds that can react with each other to form an ester. and

[ 1 ]

Question 20

Which statements about aqueous ethanoic acid are correct?

1 It can be produced by oxidising ethanol with potassium iodide.
2 It reacts with magnesium to produce hydrogen gas.
3 It has an approximate pH value of 3 .
4 It produces esters called methanoates.
A 1 and 3
B 1 and 4
C 2 and 3
D 2 and 4

Question 4

Question 4(c)

(a)

Ethanol can be oxidised to form ethanoic acid.

[ 1 ]

Question 4(c)(i)

(i)

Name a suitable oxidising agent for this reaction.

[ 1 ]

Question 4(e)

(b)

Carboxylic acids react with alcohols to make esters.

The structure of an ester is shown.

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Draw the structures of the carboxylic acid and alcohol from which this ester can be made. Give the names of the carboxylic acid and alcohol.
structure of the carboxylic acid
name of the carboxylic acid
structure of the alcohol
name of the alcohol

[ 4 ]

Question 4

[Maximum number: 2]

Ethanol is made industrially by the reaction of ethene with steam. The reaction occurs at a temperature of 300C300^{\circ} \mathrm{C} and a pressure of 60 atmospheres.

C2H4( g)+H2O( g)C2H5OH( g)\mathrm{C}_{2} \mathrm{H}_{4}(\mathrm{~g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{~g}) \rightleftharpoons \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(\mathrm{~g})

A catalyst is used in this reaction.
The forward reaction is exothermic.

Question 4(d)

(a)

When alcohols react with carboxylic acids, esters are produced.

[ 2 ]

Question 4(d)(ii)

(i)

Give the name of the alcohol and the carboxylic acid that react together to produce ester X. alcohol
carboxylic acid

[ 2 ]

Question 4

[Maximum number: 2]

This question is about ethanoic acid, CH3COOH\mathrm{CH}_{3} \mathrm{COOH}.

Question 4(d)

(a)

Ethanoic acid reacts with methanol to form an ester.

[ 2 ]

Question 4(d)(i)

(i)

State two conditions required for this reaction.

1

2

[ 2 ]

Question 4

[Maximum number: 2]

Methanol is made industrially by reacting carbon monoxide with hydrogen. The gases react at a temperature of 250C250^{\circ} \mathrm{C} and a pressure of 75 atmospheres.

CO( g)+2H2( g)CH3OH( g)\mathrm{CO}(\mathrm{~g})+2 \mathrm{H}_{2}(\mathrm{~g}) \rightleftharpoons \mathrm{CH}_{3} \mathrm{OH}(\mathrm{~g})

The forward reaction is exothermic.

Question 4(d)

(a)

Alcohols react with carboxylic acids to produce esters.

[ 2 ]

Question 4(d)(ii)

(i)

Give the name of the carboxylic acid and the alcohol that react together to produce ester X. carboxylic acid alcohol

[ 2 ]

Question 33

The structure of an ester is shown.

Question image

What are the names of the carboxylic acid and the alcohol that react together to form this ester?

Table

Question 33

[Maximum number: 1]

What is the structure of the ester formed from ethanoic acid and propanol?

Question 34

Which statement about ethanol is not correct?
A Ethanol can be made by fermentation.
B Ethanol is oxidised to make ethanoic acid.
C Ethanol reacts with oxygen exothermically, making it a good fuel.
D Ethanol reacts with propanoic acid to make propyl ethanoate.

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