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IGCSE Chemistry11.1 Formulae, functional groups and terminologyQuestion Bank

Question 1

Question 1(a)

(a)

Five organic compounds have the following structures.
A
C
C
A
,

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B
B

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D

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E

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[ 1 ]

Question 1(a)(ii)

(i)

Which two compounds are structural isomers of each other?

[ 1 ]

Question 1

Question 1(a)

(a)

The structures of five organic compounds, A, B, C, D and E, are shown.
Answer the questions that follow.
Each letter may be used once, more than once or not at all.
A

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B

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c

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D

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E
E

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[ 2 ]

Question 1(a)(vi)

(i)

Give the letter of the compound that is in the same homologous series as hex-1-ene.

[ 1 ]

Question 1(a)(viii)

(ii)

Draw a structural isomer of compound D.

Show all of the atoms and all of the bonds.

[ 1 ]

Question 7

[Maximum number: 1]

The structure of glycine is shown.

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Which row is correct?

formula of glycine

number of different

elements in glycine

CH5O2 N\mathrm{CH}_{5} \mathrm{O}_{2} \mathrm{~N}

10

C2H5O2 N\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}_{2} \mathrm{~N}

4

C2H5O2 N\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}_{2} \mathrm{~N}

10

H2NCHCOOH\mathrm{H}_{2} \mathrm{NCHCOOH}

4

Question 2

[Maximum number: 1]

Silver has an atomic number of 47.

Question 2(f)

(a)

Members of one homologous series only react with chlorine in the presence of sunlight.

[ 1 ]

Question 2(f)(i)

(i)

Name a member of this homologous series.

[ 1 ]

Question 3

[Maximum number: 2]

Fluorine is a Group VII element. Fluorine forms compounds with metals and non-metals.

Question 3(f)

(a)

Tetrafluoroethene is an unsaturated compound with the formula C2 F4\mathrm{C}_{2} \mathrm{~F}_{4}. Tetrafluoroethene is the monomer used to make the polymer poly(tetrafluoroethene).

[ 2 ]

Question 3(f)(i)

(i)

What is meant by the term unsaturated?

[ 1 ]

Question 3(f)(iii)

(ii)

Draw the structure of a molecule of tetrafluoroethene. Show all of the atoms and all of the bonds.

[ 1 ]

Question 2

[Maximum number: 5]

The structures of six organic compounds are shown.
A

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B

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C

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D

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E

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F

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Question 2(b)

(a)

Identify two of the compounds that are members of the same homologous series.

Give the general formula of this homologous series.
compounds
general formula

[ 2 ]

Question 2(c)

(b)

Which two compounds are isomers of each other?

Explain why they are isomers.
compounds
explanation

[ 3 ]

Question 5

[Maximum number: 2]

Chlorine, bromine and iodine are halogens.

Question 5(d)

(a)

When one mole of chlorine, Cl2\mathrm{Cl}_{2}, reacts with one mole of propane, a mixture of two structural isomers is formed.

[ 2 ]

Question 5(d)(ii)

(i)

Explain what is meant by the term structural isomers.

[ 2 ]

Question 3

[Maximum number: 1]

Sulfur dioxide, SO2\mathrm{SO}_{2}, is used in the manufacture of sulfuric acid.

Question 3(d)

(a)

When propan-1-ol is heated with concentrated sulfuric acid as a catalyst an unsaturated hydrocarbon of relative molecular mass 42 is formed and one other product.

[ 1 ]

Question 3(d)(i)

(i)

What is meant by the term unsaturated?

[ 1 ]

Question 4

[Maximum number: 4]

Gasoline is used as a fuel for cars. It is a mixture of hydrocarbons.

Question 4(b)

(a)

One of the compounds in gasoline is heptane, C7H16\mathrm{C}_{7} \mathrm{H}_{16}. Heptane is a saturated hydrocarbon.

[ 2 ]

Question 4(b)(iii)

(i)

Give two characteristics of an homologous series.

1
2

[ 2 ]

Question 4(d)

(b)

The formula C4H10\mathrm{C}_{4} \mathrm{H}_{10} represents two structural isomers, A and B.

A

A

B

B

[ 2 ]

Question 4(d)(ii)

(i)

What is meant by the term structural isomers?

[ 2 ]

Question 4

[Maximum number: 3]

Ethanol is made industrially by the reaction of ethene with steam. The reaction occurs at a temperature of 300C300^{\circ} \mathrm{C} and a pressure of 60 atmospheres.

C2H4( g)+H2O( g)C2H5OH( g)\mathrm{C}_{2} \mathrm{H}_{4}(\mathrm{~g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{~g}) \rightleftharpoons \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(\mathrm{~g})

A catalyst is used in this reaction.
The forward reaction is exothermic.

Question 4(c)

(a)

Ethanol is a member of the alcohol homologous series.

Members of the same homologous series have the same general formula.

[ 3 ]

Question 4(c)(i)

(i)

State the general formula of alcohols.

[ 1 ]

Question 4(c)(ii)

(ii)

State two general characteristics, other than the same general formula, of all homologous series.

1

2

[ 2 ]
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