Course review

3.1 Proton transfer reactions

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Learning objective

3.1.1—Brønsted-Lowry theory

New

• Acid = proton donor • Base = proton acceptor • Deduce acid and base in a reaction; distinguish base and alkali

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Learning objective

3.1.2—Conjugate acid-base pairs

New

• Differ by one proton • Deduce conjugate acid/base formulas

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Learning objective

3.1.3—Amphiprotic species

New

• Can act as both acid and base • Write equations showing acid and base behaviour

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Learning objective

3.1.4—pH scale

New

• pH = −log₁₀[H⁺] • [H⁺] = 10⁻ᵖᴴ • Calculate pH and [H+]; include universal indicator and pH probe use

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Learning objective

3.1.5—Ion product of water (Kw)

New

• Kw = [H⁺][OH⁻] • Acidic: [H⁺] > [OH⁻] • Neutral: [H⁺] = [OH⁻] • Basic: [H⁺] < [OH⁻] • Recognize acidic, neutral, and basic solutions from [H+] and [OH-]

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Learning objective

3.1.6—Strong vs. weak acids/bases

New

• Differ in extent of ionization • Equilibrium favors weaker conjugate • Distinguish strong/weak from concentrated/dilute

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Learning objective

3.1.7—Neutralization reactions

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• Acid + metal oxide/hydroxide/carbonate/hydrogencarbonate • Formulate equations and identify parent acids/bases of salts

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Learning objective

3.1.8—pH curves

New

• Strong acid-strong base titrations • Characteristic shapes • Sketch and interpret intercept and equivalence point for monoprotic titrations

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Learning objective

3.1.9 (HL)—pOH scale

New

• pOH = −log₁₀[OH⁻] • [OH⁻] = 10⁻ᵖᴼᴴ • pH + pOH = 14 (at 25°C) • Interconvert [H+], [OH-], pH, and pOH

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Learning objective

3.1.10 (HL)—Acid/base strength constants

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• Ka, Kb, pKa, pKb • Interpret relative acid/base strength from Ka, Kb, pKa, and pKb

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Learning objective

3.1.11 (HL)—Conjugate pair relationship

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• Ka × Kb = Kw • Solve problems involving Ka, Kb, and Kw

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Learning objective

3.1.12 (HL)—Salt hydrolysis

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• pH depends on parent acid/base strength • Write ion hydrolysis equations and predict salt solution pH

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Learning objective

3.1.13 (HL)—pH curves for weak acids/bases

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• Four combinations: strong-strong, strong-weak, weak-strong, weak-weak • Interpret buffer region and points where pH = pKa or pOH = pKb

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Learning objective

3.1.14 (HL)—Acid-base indicators

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• Weak acids with colored conjugate pairs • Color change at pH ≈ pKa • Write indicator equilibria and include universal indicator as a mixture

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Learning objective

3.1.15 (HL)—Indicator selection

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• End point coincides with equivalence point • Choose indicators from salt identity and indicator pH range; distinguish end point and equivalence point

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Learning objective

3.1.16 (HL)—Buffer solutions

New

• Resist pH change • Acidic buffers: weak acid + conjugate base • Basic buffers: weak base + conjugate acid • Explain buffer action using weak acid/base conjugate systems

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Learning objective

3.1.17 (HL)—Buffer pH and composition

New

• Buffer pH depends on pKa/pKb and acid/base to conjugate ratio • Solve buffer composition and pH problems using equilibrium constants • Explain the effect of dilution on buffer pH

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